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INTRODUCTION
1.1
Background of experiment
With the increasing price of petroleum, the limited of its resources, and the
environmental concerns, renewable and more environmentally benign energy sources
have been developed. Biodiesel is one of the most promising substitutes.
Biodiesel is a nonpetroleum-based fuel that generally consists of fatty acid
methyl esters or fatty acid ethyl esters, respectively derived from the
transesterification of oil, whose main components are triglycerides, with methanol or
ethanol. The transesterification process can be catalysed by bases, acids, and enzymes.
Base catalysts are more attractive by their faster speed than acids and lower price than
enzymes in this reaction. The homogeneous alkaline catalysts, usually potassium
hydroxide(KOH) or sodium hydroxide(NaOH), now widely used in industrial
production, have disadvantages, including a separating problem of its catalyst and
product as well as a huge amount of wastewater. Moreover, the homogeneous base
catalysts are sensitive to water and acid. Thus, the vegetable oil has the requirement of
its water and fatty acid content, which limits the source of the raw materials. Palm oil,
which will be used in this experiment, is one of the four leading vegetable oils traded
on the world market. Because it is cheaper than canola, rapeseed, or soybean oil, the
use of palm oil would reduce the overhead cost of biodiesel production and generate a
ready supply of diesel fuel substitute.
For our experiment, biodiesel will be synthesis from palm oil, methanol and
sodium hydroxide with effect factor of methanol/oil molar ratio in the reaction. This
reaction is known as a transesterification reaction. Transesterification is the process of
transforming one type of ester into another type of ester. The overall mechanism is
catalyzed by the presence of NaOH. In the first step of the reaction, NaOH reacts with
methanol in an acid-base reaction. The product of this reaction is the very strong base
sodium methoxide and water. In the second step, the sodium methoxide acts as a
nucleophile and attacks the three carbonyl carbons of the vegetable oil. This produces
a tetrahedral intermediate that is highly unstable. The overall result is the "cracking"
of the triglyceride. The elimination of the glycerol backbone leads to the formation of
the three methyl esters (biodiesel) and glycerol. The glycerol will fall to the bottom,
and the methyl ester (biodiesel) will float to the top.
1.2
Objective of experiment
To synthesis biodiesel from palm oil, methanol and sodium hydroxide with effect
factor of methanol/oil molar ratio in the transesterification reaction.
1.3
Scope of Experiment
The scope of experiment will only include the study the lab-scale production of
biodiesel from palm oil, methanol and sodium hydroxide.
2.0
LITERATURE REVIEW
The United States is the largest single consumer of fossil fuels in the world. Each
year, the U.S. consumes 125 billion gallons of gasoline and 60 billion gallons of
diesel fuel. It is desired to find alternative feedstock due to high current energy
consumption. One such alternative feedstock is vegetable oil. Vegetable oil offers the
benefits of a greener synthetic route for obtaining diesel fuel. This fuel source is
known as biodiesel, and can be synthesized on an individual level or on an industrial
scale.
Transesterification is the process of exchanging the organic group R of an
ester with the organic group R of an alcohol and possibly with the aid of catalyst
(Wikipedia).
ethanol which is less toxic. As raw materials, the oils used could come from any
vegetable, e.g., corn, canola, peanut, sunower, soybean, olive, palm, or palm kernel.
The optimum amount of catalyst that should be added is 1% of the weight of palm oil
used. More than 1% will result in lower percentage yield as too much catalyst used
may initiate a saponification reaction as stated before. Less than 1% will also bring
about lower yield because palm oil may contain trace free fatty acids which is also
referred as FFA. Some NaOH catalyst may be neutralised during the
transesterification process by those FFA thus resulting in lesser catalyst in reaction.
(Lin and Hsiao, 2012)
These biofuel is a renewable resource causes less air pollutants except NO 2 emission,
biodegradable which is make from non-petroleum or plastic component, nontoxic,
safer to handle and less greenhouse gas emissions (B20 can reduce 15% of CO 2
emission). Engines running on biodiesel do not emit black smoke can help to improve
current environmental pollution problems.
Besides its advantages, it also has weakness or disadvantages. One of them is this fuel
is only available for diesel engine only. The price is more expensive while decreasing
the engine power respect to the per cent blended. It also increases the emission of
nitrogen oxide. Lastly, it not suitable for use in low temperatures because of the
blended properties itself.
3.0
METHODOLOGY
3.1
Materials
Palm oil, sodium hyroxide, NaOH (99% pure), methanol (99% pure), distilled water
3.2
Apparatus
500mL conical flasks, 500 mL beakers, hot plate, magnetic stirrer, measuring
cylinder, aluminium foil, electronic balance, 1L separatory funnel, thermometer
3.3
Experimental Procedure
1.
2.
3.
4.0
4.
The mixture is added into the 50-55oC palm oil and stirring speed of palm oil is
5.
maintained.
The beaker is covered with aluminium foil and is stirred continuously for 30
6.
minutes.
After 30 minutes, the content is transferred into a separating funnel and is left to
7.
8.
9.
bottom.
The upper layer of crude biodiesel is washed with distilled water and drained off.
The content left in the separating funnel is drained into another beaker and
10.
In order to study the effect of different molar ratio of methanol to palm oil on the
conversion to the products, two different molar ratio of methanol to palm oil were
used to produce two samples of biodiesel.
300 0.8875
846.1
0.3147 mol
6 0.3147 32.04
0.7918
76.4 ml
12 0.3147 32.04
=152.8 ml
0.7918
2.66 g
5.0
Anticipate Results
6:1 has a higher percentage yield
6.0
Percentage Yield=
7.0
6:1
12:1
Reference
Azcan, N. and A. Danisman. (2007). Alkali catalyzed transesterification of cottonseed
oil by microwave irradiation. Fuel 86:2639-2644.
Wikipedia. (2014). Transesterification. Retrieved November 16, 2014, from
http://en.wikipedia.org/wiki/Transesterification
Lin, C.C and Hsiao, M.C. (October, 2012). Effects of Catalyst Amount, Reaction
Temperature and Methanol/Oil Molar Ratio on Conversion Rate of Soybean Oil