83

78

73
T (C)

punto de burbuja
punto de roco
68

63

58
0.000

0.200

0.400

0.600
x,y

0.800

1.000

1.000

0.800

0.600

Y n-hexano

curva de equilibrio
curva de 45

0.400

0.200

0.000
0.000

0.200

0.400
X n-hexano

0.600

0.800

1.000

60000

50000

40000

ENTALPIA(J/mol)

30000

20000

10000

0
0.000

0.100

0.200

0.300

0.400

0.500

fraccion molar

0.600

0.700

0.800

0.900

1.000

MEZCLA IDEAL:
Etanol(A) Agua(B)

ECUACIN DE ANTOINE:

LogPvap(mmHg)=A-(B/(T(C)+C))

Pvap en Kpa
cp(J/mol.K)
cp=a + bT + CT^2 + dT^3 +eT^4

constantes cp de vapor
Acetona(A)
Acetonitrilo(B)
constantes cp del lquido
Acetona
Acetonitrilo

a
23.1317
24.4795
a
16.8022
18.6216

b
0.162824
0.0891399
b
0.848409
0.73015

c
8.01548E-005
3.50089E-005
c
-0.00264114
-0.00233009

Temp.sat a
101KPa

Constantes de la ecuacin de
Antoine
Etanol(A)
Agua(B)

A
8.11220
7.96681

d
-1.60497E-007
-3.43081E-008

e
5.91406E-011
3.40092E-011

Pacetona

58.96
69
70
71
72
73
74
75
76
77
78
79
80
81

13
15
15
16
16
16
17
17
17
17
18
18
18
19

(KPa)

(C)
78.2981918812
100.000624906

en K
351.2981918812
373.0006249057

d
3.39139E-006
2.7825E-006
calor latente de acetona a Teb normal de 331 k
calor latente de acetonitrilo a a Teb normal de 354 k

Presin constante=101325Pa
T(C)

B
C
1592.86
226.18
1668.21000 228.00000

Pacetonitrilo (KPa)
9
10
11
11
11
11
12
12
12
12
12
13
13
13

Ptotal
(Kpa)
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325
101.325

Xacetona

Yacetona

entalpia del liquido (J/mol)

23.837
19.598
19.229
18.869
18.517
18.174
17.838
17.509
17.188
16.875
16.568
16.268
15.975
15.688

2.941
2.924
2.922
2.920
2.917
2.915
2.912
2.909
2.906
2.903
2.900
2.897
2.894
2.890

-88375
-94857
-95241
-95583
-95887
-96152
-96380
-96572
-96730
-96854
-96946
-97006
-97036
-97037

entalpia del vapor

(J/mol)
32185.329401111
36489.2922007029
36792.6888481213
37098.6324155255
37407.1052889191
37718.0893193864
38031.5658218293
38347.515573793
38665.9188143794
38986.7552432502
39310.0040197172
39635.6437619226
39963.6525461063
40294.0079059629

=
=

29087.2
31510.7

L0

F=500
Zf=0.42
p=1 atm

presion del vapor de agua=

4.5Psia

caudal=25L/min

DATOS:
*18L H2O y 1.92L ETANOL
*Destilacin Batch
*Reflujo Total
*regla de fases: F=C-P+2
==>

D=
ZD=0.9
R=Lo/D

presion del vapor de agua=

4.5Psia

W=
Xw=0.4

tiempo(min) T1(C)
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85

25.8
25.8
26.3
26.5
78.3
78.1
78.1
78.1
78.1
78.1
78.1
78.1
78.1
78.1
78.1
78.1
78.1
78.1

F=2-2+2=

1.92L

ETANOL

F=C-P+2

==>

F=2-2+2=2 (presin total y.. )

T2(C)

T3(C)
47.3
48.1
71.7
88.8
91.6
91.7
91.8
91.8
91.9
91.9
92
92
92.1
92.1
92.2
92.2
92.2
92.2

45
56
78
84
88
88
88.5
88.5
88.5
88.5
88.5
88.5
88.5
88.5
88.5
88.5
88.5
88.5