ethane / propane mixture

82.06
1.9872

MW Ethane
Tc
Pc

30.07
305.5
48.2

K
atm

a=
b=

97495552
45.0936

MW Propane
Tc
Pc

44.09
370
42

K
atm

a=
b=

180617084
62.6763

T
P
342.2611 27.21661799

ethane
T0
propane
T0
Mixture V
T0

T ( R)
P (bar)
T (K)
P (atm)

R
Rgas

cm3atm/(mol-K)

h cal/g-mol
-42.2431

150

Cv

200

Cv

344.63
ethane
propane
sum

yi/xi
0.0292
0.9738
1.002975

Cv

h cal/g-mol
-109.8100

h total
-152.0531
-6.2469
-273.6934

Cv_a_E

Cv_b_E

Cv_c_E

Cv_d_E

-0.3392

0.04124

-0.0000153

1.74E-009

Cv_a_P

Cv_b_P

Cv_c_P

Cv_d_P

-2.9532

0.07279

-0.00003755

7.58E-009

Cv_a
Cv_b
Cv_c
Cv_d
-2.8857759 0.072086737 -0.000037013 7.432E-009

iterations here

Mixture L
ethane
propane
sum

0.0170
0.9830
1.0000

composition fixed

Cv

Cv_a
Cv_b
Cv_c
Cv_d
-2.9086888 0.072252767 -3.71711E-005 7.481E-009

616.07
27.579
342.2611
27.21662

RK-EOS

iterate to find v
v (cm3/gmol) 634.549827

4.310 lb/ft3

eq (8-11)
-6.042E-007
Fugacity coefficient term by term

Fugacity coefficient calculations

cal/g-mol
Btu/lb
Btu/lb-mol

Ethane
Propane

Bubble-point calculations

0.5897087994
0.5897087994

-0.27851
-0.387105

Ethane
Propane

ethane
a_E
RK-EOS

97495552
a_P

RK-EOS

RK-EOS

180617084

h0

b_E
45.0936

4067.66881 5.5412019
h0

b_P
62.6763

a
178901943

b
62.3501

MW
43.8124

a
178988914

b
62.3769

MW
43.8513

RK-EOS

eq (8-11)
1.2940E-007

s0

4576.62465 2.9448348

iterations here

RK-EOS

s0

iterate to find v
v (cm3/gmol) 131.133071

20.858 lb/ft3

propane
Sum 2

Fugacity coefficient term by term

Fugacity coefficient calculations

Bubble-point calculations

Ethane
Propane

2.7086297709
2.7086297709

-0.631057
-0.877116

Ethane
Propane

Fugacity Coefficient
Sum
-0.389837 -0.078639 0.924374
-0.519814 -0.317211 0.728177

Fugacity Vapor
0.733487 atm
19.29968 atm
New yi
0.029155
0.97382
1.002975

Fugacity Coefficient

Sum
-1.61845 0.459123 1.582685
-2.158078 -0.326564 0.721398

Fugacity Liquid
0.733487 atm
19.29968 atm