Material Safety Data Sheet ARKeEMA HYDRAZINE HYDRATE 55% (1. PRODUCT AND COMPANY IDENTIFICATION ‘Company Arkoma Ine. 800 First Avenue King of Prussia, Pennsylvania 18408 Thio and Fine Chemicals, Customer Service Telephone Number: (800) 828.4453 (Monday through Friday, 8:30 AM to 6:20 PLA EST) Emergency Information Transportation: CHEMTREO: (00) 424-9300 (2a, 7 days a week) Medica: Rocky Nourain Poison Centr (866) 77-8080 (2410, 7 gays a week) Product 2 Product name: HYDRAZINE HYDRATE 55% Synonyms: Hyseaane Molec formula: HANNH2"#20 Chemical fray Diamines Product use: aw materal fr orgaic synthase [Z.HAZARDS IDENTIFICATION ] Emergency Overview Color: colouress Physical state: quia Odor: ‘amrnoniacal DANGER! MAY BE FATAL IF ABSORBED THROUGH SKIN. ‘CAUSES EYE AND SKIN BURNS. ‘MAY CAUSE BLINDNESS. HARMFUL IF SWALLOWED. HARMFUL IF INHALED, MAY CAUSE ALLERGIC SKIN REACTION. (CAUSES RESPIRATORY TRACT IRRITATION, MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. ‘SUSPECT CANCER HAZARD - MAY CAUSE CANCER. PROLONGED OR REPEATED EXPOSURE CAN CAUSE EFFECTS ON: LUNGS, UPPER RESPIRATORY ‘TRACT, LIVER, KIDNEY. Potential Health Effects Primary routes of exposure: inhalation and skin contact Signs and symptoms of acute exposure: Product code: 330185 Version 1.2 Issued on: 01/08/2012 Page: 1112Material Safety Data Shoot ARKeEMA HYDRAZINE HYDRATE 55% Corrosive to skin and eyes. Causes burn. Ite the respiratory oxgars. Prolonged or repeated exposure may use lorie skin reaction: edness, rash. ewalowed, may cause gastrointestinal tation including nausea ard Vomiting. May aso cause Cental Newvous System eects: drowsiness. fatigue, tremors (seventy of effects depends ‘on extent of exposure) Skin ‘Moderately to highly toxic Corrosive, (based on animal stusis) Inhalation: Slight toxic to mederate'y toxic, (based on enim studies) Byes: Corrosive. (based on anal studies) Ingestion: Moderately toxic. (based on animal stuces) Ropested exposure: Dala forthe main component: Listed by the National Tscology Program as: Reasonably anticipated tobe a human carcinogen, Classified bythe Intemational Agency for Research on Cancer as: Group 28: Possibly carcinogenic to humans: Repeated exposures may produce. upper respiratory vact effects, lung effec, kidnoy fects ver eects ‘3, COMPOSITIONINFORMATION ON INGREDIENTS Chemical Name CAS-No. wow ‘OSHA Hazardous, Hyseazine, manohysrate 7803-57.8 55% v Water 772185 45% N ‘Tha substanco(e) marked with @"Y" in the Hazard column above, are those identified as hazardous chemicals under the crtenia ofthe OSHA Hazard Communication Standard (20 CER 1910 1200) Ths mater is classified as hazardous under Federal OSHA regulaton. 4 FIRST AID MEASURES General advice: POISON! Get mecicalatenton immediatly. Call a Poison Contol Center immeditaly Inhalation: inhaled, ramave victim to fresh ai. not breathing, give arial respiration, I breathing s ficut, give oxygen, Skin Incase of contac, immediately fush skin with plonty of water frat last 15 minutes while removing contaminated clothing and shoes. Wash cothing befere reuse, Thoroughly clean shoes before reuse. Eyes: Incase of contac, mediately fush eyes with plenty of water or at least 15 minutes, Ingestion: Product code: 330185 Version 1.2 Issued on: 01/03/2012 Page: 2/12‘Material Safety Data Sheet Sees HYDRAZINE HYDRATE 55% I swallowed, OO NOT induce vomiting, It vtim is fly conscious, give a cupful of water. Never ge anythhg by ‘mouth o an uncaneesous person 5. FIREFIGHTING MEASURES Flash point Has ro measurable flashpoint up to the boing pont ‘Auto-ignition temperature: Net determined Lower flammable tit (LF a7 mM Upper flammable limit (UF 100 mV) Extinguishing media (suitable): water spray, Foam, ponder Protective equipment: Fire fighters and ethers who may be exposed to products of combustion should wear ul fe fighting tun out gear (ul Bunker Geas) and self-contained breathng apparatus (pressure demand / NIOSH approved or equivalenb, Eurther firefighting advice: Use fooging amourts of water from a protected locaton, Firefighting equipment shoulé be thoroughly decontaminated ater use Fire and explosion hazards: Explosion hazard CCordact with metas toerates hydrogen gas. When in aqueous solution, hydrazine forms a monchydrate form, also called hydrazine hydrate, which contains 64% hydrazine and 3656 water The conversion factor batweon percent hysrazine anc percent hydrazine hydrate 064 For example, a §6% hydrazine hydrate soliton contains 35% hydrazine (55% x 0.84) and 65% water. 6. ACCIDENTAL RELEASE MEASURES: ‘Slop th leak ¢ you can do so without rik. Evacuat area ofall unnecessary personnel. Keep people avray and stay on the upwind side. Extnguish sources of ignition nearby end downwind, Vertlae he area, See sacton & Exposure conto and personal protection. Dike splage.Contan splage, scak up with nor-combustble absorbent material, (2.9. sand, earth, diatomaceous earth, vermiculte) ard transfe to a contain: for disposal according to local national regutatons (see section 13), Avold generation of vapors. Do not allot enter Grine or waterways, Notify the responsible authors ofrepertable releases fo the ar, int waterways, sol or sewers. Collect wash wate for approved disposal. Consur a regulatory specialist determine appropriate stata or local reporting Fequiements for assistance in waste characterization andicr hazardous waste disposal and other requirements listed in pertinent erveonmental permits Product code: 330155 Version 1.2 tseued on: o1/oaiz012 3112Material Safely Data Shoot ARKeEMA HYDRAZINE HYDRATE 55% ([7-HANDLING AND STORAGE Handling General information on handling: Do not taste or swallow, Do not get in eyes, on skin, or on ching ‘Avoid breating vapor of mis Keep container tightly closed Use only wit adequate venation \Wash thoroughly after handing. (Opserve al absted safeguards until container is cleaned, recansiioned of destroyed. EEmpted container retains vapor and product residus ‘tote away tom combustibles and materials to avo, Storage General information on storage conditions: Stote out of ditect sunlight in 8 cool well-ventilated place. Store away from combustibles and materia to avoid, Storage stability ~ Remarks: Stable under racommendes storage conaitons. Storage incompatibility ~ General: Koop away ftom combustible materias. Store separate from otal oxides Strong oxdzing sgonts Motalic sats Strong acids Nios Akal metals Do not store this material in containers made of Ordinary metals Ordinary toe 8.EXPOSURECONTROLSIPERSONAL PROTECTION sd Alrborne Exposure Guidelines: Hydrazine (302-01-2) US, ACGIH Threshold Limi Values “Time Weighted Averago (TWA) 0.01 ppm ‘Skin designation Remarks Can be absotved through the skin Product code: 330155 Version 1.2 Issued on: 01/03/2012 Page: 4112Material Safoty Data Sheet ARKEMA HYDRAZINE HYDRATE 55% US, OSHA Table Z-1 Lime for A Contaminants (29 CFR 191.1000) PEL: 1 ppm (1.3. gin ‘Skin designation Remarks Can be absorbed through the skin. Hydrazine, monohydrate (7803-57-8) US. ACGIH Threshold Limit Values Skin designation Remarks. Can be absorbed through the skin. Time Weighted Average (TWA) ©. por US. OSHA Table 2-1 Limits for A Contaminants (29 CFR 1810:1000) ‘Skin designation Remarks CCan be absorbed through the stn PEL; 1 ppm (1.3.mg/ms} ‘ony toss components wit» exposure inte sre rine int secton. Lite win akin conse desgnaton above nave sn corte ‘fect Ar eamcing alone le insur 0 accwaayquantate expooure Measures fo grovel spficartcuanoous seeorston ‘ry So requred Lint sh erate Ssignaton above san hat exconre to ts nial ey cues ale reasons, Engineering controls Investigate engineering techniques to reduce exposures below sirbome exposure lms oF to otherwise reduce ‘exposures. Provide ventiation if necessary fo minimize exposures oft control exposure levels to below airborne exposure limts {if appicable see above). practical, use local mechanical exhaust ventlation at ‘ouroas of alr contamination such a8 apen process equipment. Respiratory protectin: ‘Avoid breathing vapor or mist: Where airborne exposure i kely or sitborne exposure limits are exceeded (i ‘applicable, sae above) use NIOSH approved reepalory protection equipment aporoprate to ths material {andlor ts components. Ful facepiece equipment recommended and, iFused, replaces need for face shield Aanalorenomieal goggles. Consult espirator manufacurer ta determine sppropriate ype equipment fora gven “pplication, Observe respirator use limitations speciied by NIOSH or the manviactuer. For emergency and ‘other conditions where there may be a potenti fr signticant expasure or where exposure lim may be Signfcanty exceeded, use an approved fl face poslive-pressure,selt-conained breathing apparatus or postve-prossure aiine with aunary eer-containad at supply. Respiratory protection pragrame must comply vith 28 CFR § 1910.194 Product code: 330155, Version 1.2 Issued on: 01/09/2012 Page: 6/12Material Safety Data Shoot ) ARKeEMA HYDRAZINE HYDRATE 55% ‘Skin protection: ‘Weer appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropiate type glove material fr ven application, Wear chemical oogles, a face shield, and cherrical resistant cating such as 2 rubber apron wien splashing may occu Flnse immediately skins contaminated. Remove coniaminatad cothing immediately anc wash before reves. (Clean protective equipment before reuse. Provide a safety shower at any location where skin contact can Ceeur. Wash thoroughly afer hanting Eye protection: ‘Whefe there is potential for eye contact wear a face shield, chemical goggles, and have eye fusing fulbment immediately avalable, (S.PHYSICAL AND CHEMICAL PROPERTIES Color: cooutess Physical state: sid or ‘ammonacat ar 107 (4 S6In soliton in water) Density swt determined Specific Gravity Relative 1.02 (68°F(20°C)) density): Vapor pressure: 11-15mmHg (68°F (20°C), Vapor density: 0.84 kging Boling pointiboling 228 °F (109°C) range Freezing point “80°F (62°C) Melting pointrange: not determined Evaporation rate: 10 data avaiable Solubility in water: 68°F (20°C) completely soluble Solubility in other Solubi in: Ethane! solvents: [qualitative and ‘quantative) Thermal decomposition > 482°F + 260°C) Product code: 330165 Version 1.2 Iseued on: 01/09/2012 Page: 6/12La Matorial Safety Data Sheet ARKeEMA HYDRAZINE HYDRATE 55% (fo: STABILITY AND REACTIVITY Stability ‘This materials chemically stable under normal ane anticipated storage, handling and processing condtons Powerful reducer Materials to avoid: ‘Strong ackis and ovcizng agents Nertes Alka metals Metalic sats Metalic oxides Combustle material Corrosion wi: ight metals and alloys Conditions / hazards to avold: ‘void lames, welding ars, potential ignition sources, or other high temperature sources which induce thermal ‘secompositon Hazardous decomposition products: ‘Thermal decompostion ghvng flammable and toxic preducts| Nivogenous dervatives Hysrogen [41. TOXICOLOGICAL INFORMATION J Dala on this material andlor a similar material are summarized below, Data for Hydrazine (302-01-2) Acute tox rat: Moderately toxc. (rat) LD50 between 80 - 129 mak. Dermal: Moderately toxic to highly toxic. (rabbit LOSO between 91 - 238 mg/kg ‘Moderately toxic. (rabbit) LDS > 200 mg/kg. (48%) ‘Moderately toxic. (rabbit) LDS0 950 mg, (75.5%) Inhalation: “Tower 4h LOK 75 moh ‘Sighty toxic. (rt) 1 hLO5O 6.5 mal. (64 4) sign: ifcuty in breathing (Aeroso}) ‘Skin Iitation: Cortesve. (2bb (48 - 100%) ‘Sight itating. (rabbit Intaton Index: 2 /8. (35 %) ‘Sighty to moderately rising. (rabb)Intation Index: 1.8 /8. (16.5%) Product code: 330155 Version 1.2 Issued on: 01/05/2012 Page: 7142Material Safoty Data Sheet ARKeEMA HYDRAZINE HYDRATE 55% Eye lertation: Corrosive. rabbit (100%) Slightly tating. rebbit Itation Index: 5 110. (15.556) Repeated dose toxicity Repeated ofl, inhalation administration fo various animal species / affected organ): Livor, Key, Nervous system | Carcinogenicity ‘Chronic oral administration to varlous animal species ttectad organ(s): lung, liver, kidney J Increased Incidonce of tumors was reported (Chronic inhalation administration to rat and hamster affected organ(s): upper respiratory tact / Increased incidence of tumars was reported CCassifed by the Intemational Agency for Research on Cancer as: Group 20: Possibly carcinageni to humans. Listed by tne National Toxicology Program ae: Reasonably anepated to be a human carcinogen, Genotoniciy Assessment in Vitro: Gonetic changes were observed in laboratory ests using: bacterla, yeast, animal cells notoxic Assessment in Vivo: CGanotic changes were observed in a laboratory test using: fa es No genetic changes were observed in a labaralory tet using: redent Developmental toxicity Exposure during pregnancy. dermal application (rodent) / No bith defects were observed, (levels produced toxic effocs in the methers and offspzng) Human experience General Epidemiology studles have not shown an nerease ln cancer ritating ta eyas, respiatory system and skin Human experience Skin contact: Skin: Inéation. Skin allergy was observed Human experience Ingestion: Gastrocntestina tact ato, vomiting, nausea, Liver kidney, cardiovascular system: changes in organ structure or funtion. Nervous system: Drowsiness, lethargy, tremors Product code: 330165 Version 1.2 Jssued on: 01/09/2012 Page: 8/12Material Safety Data Sheet aecemna HYDRAZINE HYDRATE 55% (42. ECOLOGICAL INFORMATION Chemical Data on tis material andor a Sitar material are summarized below. Data for Hyarazine (302-01-2) ‘Octanol Wator Parition Coofficient: log Pow -0.16 (OECD Test Guideine 107) Ecotoxicology Data on tis material andlor a sirilar material ere surmarized below. Data for Hydrazine (302-01-2) ‘Aquatic toxicity data: Moderately toxe. Lepomis macrochrus (Bluegil sunfish) 95 h LCBO Moderateytoxc. Pimephals promelas (fated minnow) $6 h LC50 Moderately toxe. Poecla reticulata (guppy) 95 LCSO = 3.85 mg 2 mgi 5.98 mg ‘Aquatic invertebrates: Highly toxic Daphnia pulex (Water fles) 48 ECO = 0.18 mg Highly toxic. Daphnia magna (Miata fea) 96 h ECSO = 0.88 mgt Algae: Highly toxic. Algae 96 h E50 = 0.075 met (73. DISPOSAL CONSIDERATIONS: ] Waste cispos Destroy the product by oxdation witha dt solution of hypochlorts (sodium - calcium). Hypochlorite (aodium calcium) Clean container with water, Recover waste wate for processing later Dispose of acsorance with federal, state and local regulations. Consult a regulatory speci le detocmine appropriate site or local reporting requirements, for assistance in waste characterization andlor hazardous waste dsposal and othe requirements lsted in pertinent envronmental permits, Note: Cnercal adeltons to, processing of or otherwise aterng ts ‘material may make this waste management informaton incomplete, inaccurate, of otherise naporontal Furthermore state and local waste disposal requirements may be more resticve or otherwise diferent fom federal laws and regulations, (TRANSPORT INFORMATION } US Department of Transportation (007) UN Number 2293 Proper shiping name Hydrazine, aqueous solution Chass er Pckaging group Wi Marie pollutant yes Reportabie quantity ibs (Hydrazine hyerate) International Maritime Dangerous Goods Code (IMDG) Product code: 330155 Version 1.2 lssued on: 01/03/2012 Page: 9112Material Safety Data Sheet ARKeEMA HYDRAZINE HYDRATE 55% LUN Number 3293 Proper shipping name HYDRAZINE, AQUEOUS SOLUTION Class 84 Packaging group ui Marine potutant yes 45. REGULATORY INFORMATION i ial Inventory Statue EU. EINECS EINECS. Conforms to US. Tonic Substances Control Act TSCA ‘This product complies with TSCA, Inventry cequirements, For tha TSCA Inventory, hydrates of@ chemical ‘substance are considereato be mxtues ‘ofthe anhydrous form ofthe chemical ‘substance ana wator ‘Australia Industial Chemical (Notifcation and acs Conforms to ‘Assessment) Act ‘Canada. Canadian Environmental Protection Act OSL ‘Allcomponents of his product are on the (CEPA), Domestic Substances List (OSL). (Can. Gaz ‘Cenadian DSL ist Pert I, Vol 144) Japan. Kashir-Hou Law Uist ENCS (JP) Conforms to Korea, Existing Chemicals Inventory (KECI) KECI(KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) __Conformsto ‘and Nuclear asta Contal Act China. Inventory of Exsting Chemical Substances IECSC (CN) Conforms to ‘New Zealane. Invantoy of Chemicals (NZIOC), a8 NZIOC. ‘Conforms to published by ERMA New Zealand United States ~ Federal Requlations ‘SARA Tile I~ Section 302 Extremely Hazardous Chamicals: ‘Shomical Name ASNo, ‘SARA SABA ble —_‘Thveshold Quanilies Planning ‘Quantity Hysrazine, monohydrate 7803-878 1 Ibs ‘ooo bs ‘SARA Tite ll - Section 3117312 Hazard Catogoris: ‘Acute Heath Hazard, Chronic Health Hazara Product code: 330155 Version 1.2 Page: 10/12Material Safety Data Sheet ARKeEMA HYDRAZINE HYDRATE 55% ‘SARA Tite ll~ Section 313 Toxie Chemicale: Shemea! Name os Deminmis Reportable songeniaton thasbolt Hysrazine so2012 Crs 10000 bs (Otnemise used (or. ‘manufacturing processing) 25000 fs (Manufacturing and processing} Comprehensive Environmental Response, Compensation, and Liabilly Act (CERCLA) - Reportatt Quantity (RO): (Chemical Name CASNo, Reportable quanity Hycrazine, monohydrate e057 Ties (OSHA Regulated Carcinagons (NTP, IARC, OSHA Listed NTP: (Chemical Name AS-No, Alte Hysrazine, monohydrate 7803578 ‘Antinsted carcinogen. tare: Chemical Name ASNo, Attbute Hygrazne, monohydrate [p28 (Possible carcinogen) sna: No component of his product present at levels greater than or equalto 0.1% is kentiied as a carcinogen or potent earepogen by OSHA, United States ~ Stato Regulations, New Jersey Right to Know 7 cAS.No Hysrazine 302012 New Jersey Right to Know ~ Special Health Hazard Substance(s) ‘Chemical Name Hysrazne Pennsylvania Right to Know ‘Shamical Name ASNo, Kygrazne S020 Wetor 732186 Produet code: 330185 Version 1.2 ‘Issued on: 01/02/2012 Page: 11/42Matorial Safety Data Sheet ARKEMA HYDRAZINE HYDRATE 55% Pennsyvania Right Know ~ Environmentally Hazardous Substancels) Chemical Name cAs.Ne Hvdranno aaa012 Pennsylvania Right to Know ~ Special Hazardous Substance(s) Chemical Name CAS.No. Hysrazine S02-01-3 California Prop. 65 WARNING! This product contein a chemical known othe State of Caifrna to cause cancer, (Chemical Name Hysrazine WARNING! This product contains a chemical know tothe State of California to cause cance ‘Chemical Names CAS-No. ydrazina, monohydrate 7203-57-8 (6: OTHER INFORMATION Miscellaneous! Grades HYDRAZINE HYDRATE 40%, HYDRAZINE HYDRATE 55% Use restretions Reserved for industrial and professional use Latest Revision(s): Revsed Sections) Revised Division and haz mat Reference number ‘onoa002s656 Date of Ravion ‘ovoaror2 Date Printes owoaz12 ‘rkema Inc. boleves thatthe informston and recommendations contained herein inelucing data and ‘Salemenis) are accurte as ofthe dete hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR, PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provised herein relatos ony tothe spect product designated and may not be valid where euch products used in ccambinaion wih any cther materials erin any process. Further, since the coniions and methods of use {are beyond the contal of Arkema Inc, Arkem Inc. expressly disclams any and al ally ae to any results ‘blained or aising from any use ofthe produet or ellance on such information| Produet code: 330155 Version 1.2 {Issued on: 01/09/2012 Page: 12/12