TABLE 1 Composition of Reaction Mixture 1

Sample 1
Temperature
0.10 M Na4P2O7 (mL)
H2O (mL)
5 x 10^-4 M Ferroin (mL)

Time (s)
0
180
360
540
720
900
1080
1260
1440
1620
1800
1980
2160
2340
2520
2700
2880
3060
3240
3420
3600
3780
3960
4140
4320
4500
4680
4860
5040

40
1.0
3.5
0.5

Absorbance
0.4
0.388
0.373
0.361
0.351
0.341
0.333
0.325
0.318
0.311
0.305
0.298
0.291
0.285
0.278
0.273
0.267
0.261
0.256
0.25
0.245
0.239
0.234
0.229
0.224
0.219
0.214
0.21
0.204

313.15

Kelvin

Time

ln(absorbance)
0
180
360
540
720
900
1080
1260
1440
1620
1800
1980
2160
2340
2520
2700
2880
3060
3240
3420
3600
3780
3960
4140
4320
4500
4680
4860
5040

-0.9162907319
-0.9467499394
-0.9861768593
-1.0188773206
-1.0469690555
-1.0758728017
-1.099612789
-1.1239300967
-1.1457038962
-1.1679623668
-1.1874435024
-1.2106617925
-1.2344320118
-1.2552660987
-1.2801341653
-1.2982834838
-1.3205066206
-1.3432348717
-1.3625778345
-1.3862943611
-1.4064970684
-1.4312917271
-1.4524341636
-1.4740332754
-1.4961092271
-1.5186835492
-1.541779264
-1.5606477483
-1.5896352851

Slope
Time
-0.00012751

0
180
360
540
720
900
1080
1260
1440
1620
1800
1980
2160
2340
2520
2700
2880
3060
3240
3420
3600
3780
3960
4140
4320
4500
4680
4860
5040

Absorbance vs. Time

5.0E-01
4.0E-01

f(x) = - 3.64258347016968E-005x + 0.3774137931

R = 0.9802772681

3.0E-01
Absorbance

2.0E-01
1.0E-01
0.0E+00
0

1/(absorbance)
2.5
2.5773195876
2.6809651475
2.7700831025
2.849002849
2.9325513196
3.003003003
3.0769230769
3.1446540881
3.2154340836
3.2786885246
3.355704698
3.4364261168
3.5087719298
3.5971223022
3.663003663
3.7453183521
3.8314176245
3.90625
4
4.0816326531
4.1841004184
4.2735042735
4.3668122271
4.4642857143
4.5662100457
4.6728971963
4.7619047619
4.9019607843

1000

2000

3000

4000

5000

Time (seconds)

ln(absorbance) vs. Time

0.0E+00
0

1000

2000

3000

4000

500

-5.0E-01
ln(absorbance)

-1.0E+00

f(x) = - 0.0001275079x - 0.9503384575

R = 0.9969949266

-1.5E+00
-2.0E+00

Time (seconds)

1/(absorbance) vs. Time

6.0E+00
5.0E+00
f(x) = 0.0004568067x + 2.4814659881
R = 0.9963475052

4.0E+00
1/(absorbance)

3.0E+00
2.0E+00
1.0E+00
0.0E+00
0

1000

2000

3000

4000

Time (seconds)

50

1/(absorbance)

R = 0.9963475052

3.0E+00
2.0E+00
1.0E+00
0.0E+00
0

1000

2000

3000

4000

Time (seconds)

50

nce vs. Time

4258347016968E-005x + 0.3774137931
2772681

2000

3000

4000

5000

6000

Time (seconds)

ance) vs. Time

1000

2000

3000

4000

5000

6000

5000

6000

- 0.0001275079x - 0.9503384575
.9969949266

Time (seconds)

bance) vs. Time

0.0004568067x + 2.4814659881
9963475052

000

2000

3000

4000

Time (seconds)

9963475052

000

2000

3000

4000

Time (seconds)

5000

6000

Sample 2
Temperature
0.10 M Na4P2O7 (mL)
H2O (mL)
5 x 10^-4 M Ferroin (mL)

Time (s)
0
120
240
480
600
720
840
960
1080
1200
1320
1440
1560
1680
1800
1920
2040
2160
2280
2400
2520
2640
2760
2880
3000
3120
3240
3360
3480
3600
3720

45
1.0
3.5
0.5

Absorbance
0.321
0.321
0.318
0.308
0.304
0.3
0.296
0.292
0.288
0.283
0.279
0.275
0.27
0.266
0.262
0.257
0.253
0.249
0.244
0.24
0.236
0.232
0.228
0.223
0.219
0.216
0.211
0.207
0.203
0.199
0.195

318.15 Kelvin

Time
0
120
240
480
600
720
840
960
1080
1200
1320
1440
1560
1680
1800
1920
2040
2160
2280
2400
2520
2640
2760
2880
3000
3120
3240
3360
3480
3600
3720

3840
3960
4080
4200
4320
4440
4560
4680
4800
4920

0.191
0.187
0.184
0.18
0.176
0.173
0.169
0.166
0.163
0.16

3840
3960
4080
4200
4320
4440
4560
4680
4800
4920

Abs
4.0E-01
3.0E-01

f(x
R

2.0E-01

Absorbance

1.0E-01

ln(absorbance) Slope
Time
-1.1363141559 -0.00014646
-1.1363141559
-1.1457038962
-1.177655496
-1.1907275776
-1.2039728043
-1.2173958247
-1.2310014767
-1.2447947988
-1.2623083813
-1.2765434972
-1.2909841813
-1.30933332
-1.3242589702
-1.3394107752
-1.3586791941
-1.3743657903
-1.3903023825
-1.4105870537
-1.4271163556
-1.443923474
-1.4610179073
-1.47840965
-1.5005835075
-1.5186835492
-1.5324768713
-1.5558971455
-1.5750364857
-1.5945492999
-1.6144504543
-1.6347557204

1/(absorbance)
0
120
240
480
600
720
840
960
1080
1200
1320
1440
1560
1680
1800
1920
2040
2160
2280
2400
2520
2640
2760
2880
3000
3120
3240
3360
3480
3600
3720

3.1152647975
3.1152647975
3.1446540881
3.2467532468
3.2894736842
3.3333333333
3.3783783784
3.4246575342
3.4722222222
3.5335689046
3.5842293907
3.6363636364
3.7037037037
3.7593984962
3.8167938931
3.8910505837
3.95256917
4.016064257
4.0983606557
4.1666666667
4.2372881356
4.3103448276
4.3859649123
4.4843049327
4.5662100457
4.6296296296
4.7393364929
4.8309178744
4.9261083744
5.0251256281
5.1282051282

0.0E+00
0

ln(abs

0.0E+00

-5.0E-01
ln(absorbance)

-1.0E+00

-1.5E+00

-2.0E+00

1/(ab

8.00E+00

6.00E+00
1/(absorbance)

4.00E+00

2.00E+00

0.00E+00

6.00E+00
1/(absorbance)

4.00E+00

2.00E+00
-1.6554818509
-1.6766466621
-1.6928195214
-1.7147984281
-1.7372712839
-1.7544636845
-1.7778565641
-1.7957674906
-1.8140050782
-1.8325814637

3840
3960
4080
4200
4320
4440
4560
4680
4800
4920

5.2356020942
5.3475935829
5.4347826087
5.5555555556
5.6818181818
5.7803468208
5.9171597633
6.0240963855
6.1349693252
6.25

0.00E+00

Absorbance vs. Time

4.0E-01
3.0E-01

f(x) = - 3.41684087930881E-005x + 0.3234629114

R = 0.9989377883

2.0E-01

Absorbance

1.0E-01
0.0E+00
0

1000

2000

3000

4000

5000

6000

Time (seconds)

ln(absorbance) vs. Time

0.0E+00
0

1000

2000

3000

4000

5000

6000

5000

6000

-5.0E-01
ln(absorbance)

-1.0E+00
-1.5E+00

f(x) = - 0.0001464595x - 1.0909702658

R = 0.9949553108

-2.0E+00

Time (seconds)

1/(absorbance) vs. Time

8.00E+00
6.00E+00
1/(absorbance)

f(x) = 0.0006446357x + 2.7788401047

R = 0.9745037056

4.00E+00
2.00E+00
0.00E+00
0

1000

2000

3000

4000

Time (seconds)

6.00E+00
1/(absorbance)

f(x) = 0.0006446357x + 2.7788401047

R = 0.9745037056

4.00E+00
2.00E+00
0.00E+00
0

1000

2000

3000

4000

Time (seconds)

5000

6000

Sample 3
Temperature
0.10 M Na4P2O7 (mL)
H2O (mL)
5 x 10^-4 M Ferroin (mL)

Time (s)
0
120
240
380
500
620
740
860
980
1100
1220
1340
1460
1580
1700
1820
1940
2060
2180
2300
2420
2540
2660
2780
2900
3020
3140
3260
3380

50
1.0
3.5
0.5

Absorbance
0.645
0.599
0.567
0.543
0.525
0.505
0.491
0.477
0.466
0.456
0.446
0.456
0.446
0.435
0.427
0.417
0.41
0.4
0.392
0.385
0.378
0.369
0.362
0.355
0.349
0.343
0.335
0.329
0.323

323.15 Kelvin

Time
0
120
240
380
500
620
740
860
980
1100
1220
1340
1460
1580
1700
1820
1940
2060
2180
2300
2420
2540
2660
2780
2900
3020
3140
3260
3380

1.44846416
0.3705038
0.69314718
0.53452399

ln(absorbance) Slope
Time
-0.4385049622 -0.00017834
-0.5124936809
-0.5673959753
-0.610645959
-0.6443570164
-0.6831968497
-0.7113111512
-0.7402387881
-0.7635696449
-0.7852624695
-0.807436327
-0.7852624695
-0.807436327
-0.8324092479
-0.8509712658
-0.8746690572
-0.8915981193
-0.9162907319
-0.9364934392
-0.9545119447
-0.9728610834
-0.9969586349
-1.0161110672
-1.0356374895
-1.0526833568
-1.0700248318
-1.0936247472
-1.1116975282
-1.1301029558

1/(absorbance)
0
120
240
380
500
620
740
860
980
1100
1220
1340
1460
1580
1700
1820
1940
2060
2180
2300
2420
2540
2660
2780
2900
3020
3140
3260
3380

1.5503875969
1.6694490818
1.7636684303
1.8416206262
1.9047619048
1.9801980198
2.0366598778
2.0964360587
2.1459227468
2.1929824561
2.2421524664
2.1929824561
2.2421524664
2.2988505747
2.3419203747
2.3980815348
2.4390243902
2.5
2.5510204082
2.5974025974
2.6455026455
2.7100271003
2.7624309392
2.8169014085
2.8653295129
2.915451895
2.9850746269
3.0395136778
3.0959752322

Absorbance vs. Time

8.0E-01
6.0E-01
f(x) = - 7.88886857292883E-005x + 0.5694992719
R = 0.9359665433

4.0E-01

Absorbance

2.0E-01
0.0E+00
0

500

1000 1500 2000 2500 3000 3500 4000

Time (seconds)

ln(absorbance) vs. Time

0.0E+00
-2.0E-01

500

1000

1500

2000

2500

3000

3500

4000

-4.0E-01
ln(absorbance)
-6.0E-01
-8.0E-01

f(x) = - 0.0001783401x - 0.5452513892

R = 0.9735536143

-1.0E+00
-1.2E+00

Time (seconds)
1/(absorbance) vs. Time
4.00E+00
3.00E+00
1/(absorbance)

f(x) = 0.0004126969x + 1.6724374081

R = 0.9895999158

2.00E+00
1.00E+00
0.00E+00
0

500 1000 1500 2000 2500 3000 3500 4000

1/(absorbance) vs. Time

4.00E+00
3.00E+00
1/(absorbance)

f(x) = 0.0004126969x + 1.6724374081

R = 0.9895999158

2.00E+00
1.00E+00
0.00E+00
0

500 1000 1500 2000 2500 3000 3500 4000

Time (seconds)

Determining Ea
1/temperature versus ln(k)

1/Temperature

ln(k)
0.0031933578 -8.967394193
0.0031431715 -8.82848513
0.0030945381 -8.631818717

0.1389090639
5.01864E-005
2767.8651261
23012.030658
56632.6907
28316.3453

R/Ea (lnA - lnk) = 1/T

ln(k)
-8.96739419
-8.82848513
-8.63181872

ln(k) ver
-8.4
0.00308

0.0031

0.0031

-8.5
-8.6
ln(k)

-8.7
-8.8
-8.9
-9

f(x) = - 3392.4955219295
R = 0.9883558875

4
00308

1/Temperature
0.0031933578
0.0031431715
0.0030945381

ln(k) versus 1/Temperature

0.0031

0.00312

0.00314

f(x) = - 3392.4955219295x + 1.8557186451

R = 0.9883558875

9
1/Temperature (1/Kelvin)

ln(k) = -Ea/R (1/T) + ln A

0.00316

0.00318

0.0032

18

0.0032