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We say a process is exothermic when heat is

released and endothermic when heat is


absorbed.
Is the follow A) exothermic or B) endothermic?
Im melting!
(My world, my
world)

Today you need:


Clickers
Scrap Paper
Notes
CRT

Unit 9:
Thermochemistry
9.1 Kinetic Energy
9.2 Cooling Curves
9.3 Heat Calculations

Clicker Quiz 9.3


9.1 Kinetic Energy
9.2 Cooling Curves

9.1 Kinetic Energy

Resource: Notes

hich equation represents solidification?

9.2 Cooling Curve

Resource: Notes

Which particle diagram


below represents
segment BC on the
cooling curve?

9.2 Cooling Curve

Resource: Notes

What is the boiling point of this


substance?

Numerical Answer

9.2 Cooling Curve

Resource: Notes

Which process increases the


average kinetic energy of the
particles of a sample?
A) Condensation
B) Deposition
C) Solidification
D) Vaporization
E) None of the above

9.3 Heat Calculations

9.3 Heat Calculations


Essential Question: How
does energy flow through a
system?
9.3 Mastery Skill: I can
quantify the heat for a
temperature change or phase
change.

9.3 Heat Calculations

Cold! -20oC

Hot! 40oC

Heat(q)

Heat (q)
I am hot.

System = Hot Cocao


Surroundings = Winter Wonderland
Equator

Chillllll
.

System = Lemonade
Surroundings = The

9.3 Heat Calculations

Law of Conservation of
Energy
The total amount of energy in an isolated system
remains constant over time.

9.3 Heat Calculations

calorie and Calorie


The calorie (cal) is a unit of heat.(1 Cal = 1000 cal)
the energy required to increase 1 gram of water by 1oC.
Food

Calories

Orange

65

Apple

110

McDonalds Med. French


Fry

450

9.3 Heat Calculations

Joules

e joule (J) is also unit of heat.


1 calorie = 4.18 joules

w many calories are in 1 joule?


1 J = 0.239 cal

9.3 Heat Calculations

Specific heat
Specific heat (C) is the amount of
heat required to raise the
temperature of 1 g of substance by
1oC.

9.3 Heat Calculations

Resource: Notes

Which animal will cook


faster?

2.81 J/goC
2.64 J/goC
3.06 J/goC

3.35 J/goC

9.3 Heat Calculations

Measuring Heat Single


phase

q= mCT
Heat (J)
mass (g)

Temperature Change (oC)


Specific heat (J/goC)

9.3 Heat Calculations

Resources: Table T

Example
A bike with an aluminum frame is left outside
in the sun. Over the course of 2 hours, the
sun hits the bike with 40,000 Joules of heat. If
the bike has a mass of 4,500g and aluminum
has a specific heat of 0.90 J/goC, how much
has the temperature changed?
q=mCT
q= 40,000J
m= 4,500g
C= 0.90 J/(1goC)
T= ?

40,000J = (4,500g)(0.90J/goC) T
40,000J = (4,050J/oC) T
9.9oC = T

9.3 Heat Calculations

Resources: Table T

Your turn.
The bleachers at Yankee Stadium have been
sitting in the sun for 5 hours. By this time it
has been struck by 3,630,000 Joules of heat.
If the bench has a mass of 220,000g and has
a specific heat of 1.10 J/goC, how much has
the temperature changed?
q=mCT
q= 3,630,000J
m= 220,000g
C= 1.10 J/goC
T= ?

3,630,000J = (220,000g)(1.10J/goC) T
3,630,000J = (242,000J/oC) T
15.0oC = T

9.3 Heat Calculations

Your turn.

Resources: Tables B and T

9.3 Heat Calculations

Measuring Heat- Phase


Change
Enthalpy is the measure of energy for a system.
We can use it to quantify the heat (q) associated
with a phase change.

9.3 Heat Calculations

Heat of Fusion (s) (l)


Heat required to change a solid
to a liquid (or vice versa) for a
given amount of substance.

q=m

9.3 Heat Calculations

Heat of Vaporizatio
(g)

(l)

Heat required to change a


liquid to a gas (or vice versa)
for a given about of substance.

q=m
H

9.3 Heat Calculations

Resources: Tables B and T

Heat of Fusion Practice


How much heat is required to
melt 12 g of ice?
q=mHf
q= ?
m = 12 g
Hf= 334 J/g

q = (12g) (334 J/g)


q = 4008 J

9.3 Heat Calculations

Resources: Tables B and T

Your Turn.
How many grams of water can
you boil with 6500J of heat?
q=mHf
q= 6500J
m=?
Hv= 2260J/g

6500J = m (2260 J/g)


2.9 g = m

9.3 Heat Calculations

Resources: Tables B and T

Your Turn.
How many grams of water can
you boil with 6500J of heat?

How do you know which to


use?
Think-Pair-Share

9.3 Heat Calculations

Resources: Tables B and T

q= mCT

q=m
Hf
q=m

9.3 Heat Calculations

Summary

9.3 Heat Calculations

What are the steps for


quantifying heat?
STEP
STEP
STEP
STEP
STEP

1:
2:
3:
4:
5:

Identify needed equation


Make a list
Plug in values
Solve for unknown
Check

9.3 Heat Calculations

Resources: Tables B and T

Which equation can be used


for solving this problem?

How much heat is absorbed by 10 g


of water at when temperature
increases from 15C to 40C?
A) q=mCT
B) q=mHf
Justify your answer.
C) q=mHv

9.3 Heat Calculations

Resources: Tables B and T

Solve this problem.


How much heat is absorbed by 10 g
of water at when temperature
increases from 15C to 40C?
Numerical Answer

9.3 Heat Calculations

Resources: Tables B and T

Which equation can be used


for solving this problem?
How many grams of water can be
boiled with 15,000J of heat?
A) q=mCT
B) q=mHf
Justify your answer.
C) q=mHv

9.3 Heat Calculations

Resources: Tables B and T

Solve this problem.


How many grams of water can be
boiled with 15,000J of heat?
Numerical Answer

9.3 Heat Calculations

Resources: Tables B and T

Which equation can be used


for solving this problem?

Find the specific heat of an unknown


if 80 g loses 6512 J as temperature
drops from 68C to 46C.
A) q=mCT
B) q=mHf
Justify your answer.
C) q=mHv

9.3 Heat Calculations

Resources: Tables B and T

Solve this problem.


Find the specific heat of an unknown
if 80 g loses 6512 J as temperature
drops from 68C to 46C.
Numerical Answer

9.3 Heat Calculations

With respect to 9.3 Kinetic Energy


Professio
nal-4

Practition Apprentic
er-3
e-2

Novice-1

Quantity

Most-All
questions
answered
correctly

Most-All
questions
answered
correctly

Some-Most
questions
answered
correctly

Few-No
questions
answered
correctly

Descript
ion

Effective
strategies
employed for
all questions.

Some
strategies are
used, but not
for everything.

Little strategy
is used. Mostly
using intuition
instead of
problem
solving.

Strategies are
missing
completely.

9.3 Mastery Skill: I can quantify the heat for a


temperature change or phase change.

Complete Melting Point of


a Solid Lab
Look at comments from the previous lab
so you can make improvements.
Understand the criteria for a professional
level report.
Ask group-mates for their critique!

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