Professional Documents
Culture Documents
Research sponsored
by the UC WISE
program and the U.S.
National Science
Foundation (CBET1263860)
Abstract
Methods
Results
Morphology
Shown below are images of two of the
membrane samples, taken using a Scanning
Electron Microscope. The pre-settling delay
period in drying consistently resulted in a
thinner, more compact zeolite layer, but it also
had unexpected effects on the other
characteristics of the membrane.
Introduction
The widespread implementation of renewable
energy sources depends on developing more
efficient electrical storage technology.
Vanadium redox flow batteries (VRFBs) are
very promising in this field, but they suffer
from self-discharge due to metal ion
crossover. RFBs consist of an anode and
cathode, both filled with electrolyte solution
and separated by a semi-permeable
membrane. The job of the membrane is to
allow for the flow of protons from one side to
another to complete the reaction that powers
the battery while effectively containing the
metal ion solution. New membrane
technology has led to a polymer-zeolite
composite that has increased performance
within the VRFB. To further improve proton
selectivity of the membranes, we hope to
determine whether the drying conditions of
the composite affect morphology or
performance within the cell.
Ion Permeation
While the more compact zeolite layer reduced
vanadyl ion flow and so minimized electrolyte
solution crossover, it also decreased proton flow.
As the main purpose of the membrane is to allow
for the flow of protons, the decrease in proton
conductivity is something that could seriously
impact the battery performance.
Resistance
Below is a table of resistance measurements for
the six samples tested. It was found that the
drying temperature was more of a factor in the
resistance than the delay period.
Membrane
Resistance (Ohms)
F1 - 25C, No pre-settling
0.19
0.19
F3 - 80C, No pre-settling
0.24
0.27
F5 - 40C, No pre-settling
0.27
0.30
Conclusion
While it was determined that a delay in the
drying procedure produced a thinner, more
compact zeolite layer, this alteration also
affected the resistance and overall proton
selectivity negatively. It was also determined
that the 80 drying temperature had the most
favorable ratio of proton to vanadyl ion flow.
References
Zhi Xu, I. Michos, X. Wang, R. Yang, X. Gu, J. Dong,
Zeolite Ion Exchange Membrane for Redox Flow Battery.
Chem. Commun. 50 (2014) 2416-2419.
R. Yang, Z. Xu, S. Yang, L. Li, A. Angelopoulos, J. Dong,
Nonionic Zeolite Membrane as Potential Ion Separator in
Redox-Flow Battery. J. Membr. Sci. 450 (2014) 12-17.