1

Formulrio:
dW = -p
ext
dV
AU = q + W
AH = AU + A(pV)
H (T
2
) = H (T
1
) + C
p
AT
C
p
= a + bT + c/T
2

C
p
= Cv + d(pV)/dT
q = mcAT
AH
0
=
q
p
/
n

AS = AH/T
AS = C
v
ln (T
2
/T
1
) + nRln (V
2
/V
1
)
AS = C
p
ln (T
2
/T
1
)
dG = SdT + Vdp + dn
n
1
d
1
+ n
2
d
2
= 0
AG = AH TAS
[(c(G/T)/cT]
p
= H/T
2

=
o
+ RTln (p/p
o
)
A
r
G = A
r
Go + RT ln (p
B
/p
A
)
A
r
G
o
= RT lnK
p
ln K = (AH
o
/RT) + (AS
o
/R)
p + f = c + 2
dp/dT = AH/TAV
ln p = (AH
vap
/R)(1/T) +(AH
vap
/RT
b
)
ln (p
T2
/p
T1
) ~ (AH/R)(1/T
2
1/T
1
)
T
b
~ (2/3)T
c

p = A + B ln T
V
2
= |
2
+ n
2
(c|
2
/cn
2
)
|
2
= (1000/mdd
o
)(d
o
d) + M
2
/d
A
mis
G = nRT(x
1
ln x
1
+ x
2
ln x
2
)

A
= *
A
+ RT ln x
A

p
A
= p*
A
x
A

p
B
= K
B
x
B

a
A
= p
A
/p*
A

A
= *
A
+ RT ln a
A

ln x
2
= (AH
fus
/R) (1/T 1/T
o
)
ln x
2
= (AH
fus
/R) (1/T 1/T
o
) [(o
1

o
2
)
2
(V
m
|
2
|
1
)/RT]
AH
dissol
= (V
m
|
1
|
2
) (o
1
o
2
)
2

1/A = 1/A + (Ac)/(K
a
A
2
)
I = (1/2) c
i
z
i
2

log

= 0,509 z
+
z

I
1/2

= a

/[m (v
v+
+
v
v

)
1/v
]
AT
e
= (RT
e
2
/A
vap
H)x
B

AT
e
= K
e
m
B
AT
c
= K
c
m
B
M
B
= (1000w
B
K
e
)/(w
A
AT
e
)
tV = n
B
RT
t = i t
o = (i 1)/(v 1)
p
T
= x
A
p*
A
+ x
B
p*
B

G
e
= A
mis
G RT x
i
ln x
i
= RT x
i
ln
i

c/(x/m) = 1/ab + c/a
log (x/m) = log a + (1/n)log c
a
w
/[(1 a
w
)m] = 1/(m
o
c) + [(c
1)/(m
o
c)]a
w

AG = AA
d = I d
I = n/A
I = (c/RT) (d/dc)
ln c = ln c
0
kt
1/c 1/c
0
= kt
t
1/2
= ln 2/k
t
1/2
= 1/kc
0

(x
eq
/a)ln [x
eq
/(x
eq
x)] = k
1
t
ln k = ln A E
A
/RT
A

H
o
= E
a
RT
A

S
o
= R[ln(h/k
B
) + ln A 1 lnT]
v = V[S]/{K
M
+ [S]}
1/v = (K
M
/V)(1/[S]) + (1/V)

in
=
o
+ RT ln (c
in
/c
o
) + zF|
in

dn/dt = DA(cc/cx)
dn/dt = DAK
p
(cc/cx)
(cc/ct) = D(c
2
c/cx
2
)
x
2
= 2Dt; x
2
= 4Dt; x
2
= 6Dt
D = k
B
T/f
D = (RT/F
2
,z
i
,)
f = 6trq
r/[D] = nK
a
rK
a

P = D/l
P = DK
p
/l
, = (od)/(c
0
c)
u = v/E
u = (,c
0
c)/q
u = ze/6qtr
log M = a bx

2