UNIVERSIDAD NACIONAL DE ANCASH

SANTIAGO ANTUNEZ DE MAYOLO

FACULTAD DE INGENIERA DE MINAS, GEOLOGIA Y
METALURGIA
FISICO - QUIMICA
TEMA:
DETERMINACION DEL CALOR DE SOLUCIN
POR EL MTODO DE SOLUBILIDAD
DOCENTE:
Ing. Edson YUPANQUI TORRES
ALUMNA:
LAZARO MACEDO E. Manu!a"""" #$.#%$&.%.AM
HUARAZ - 2006
HOJA DE RESULTADOS
APELLIDOS Y NOMBRES' LAZARO MACEDO E. Manuela
NOMBRE DE LA PR(CTICA' Determinacin del Calor de Solucin por el Mtodo de Solubilidad
CONCENTRACION DEL NaO)' 0.5 N
INDICADOR' enotaleina
DATOS OBTENIDOS EN LA PR(CTICA'
Vaso T (
0
C) Peso del Vaso
Seco (gr)
Solucin Acido
Oxlico
Peso del Vaso con
Solucin Acido
Oxlico (gr)
NaOH (ml)
! "5 #$. %&'' 5 5". !&'# ""
( "5 #$. 00#& 5 5(. (($0 "".5
! "0 #$. %&'' 5 5". (0$& "!.'
( "0 #$. 00#& 5 5(. (("$ "!.5
! (5 #$. %&'' 5 5". !$%# ('.0
( (5 #$. 00#& 5 5(. ((0( ($.5
CUADRO I'
T (
0
C) Sol. Aci. Oxalico (ml) Peso Aci. Oxalico (gr) Na OH (ml) S (gr / 00gr
Sol.)
! ( ! ( ! (
"5 5 5 5. !%%& 5. (((# "" "".5 !#. "5$
"0 5 5 5. ("'' 5. (!%! "!.' "!.5 !". &(!
(0 5 5 5. (!0& 5. (!5& ('.0 ($.5 !!. %$$
Ra**+,n -u./+*a n !a 0+0u!a*+on'
! Na OH " H
!
C
!
O
#
$ Na
!
C
!
O
#
" ! H
!
O
T 1 $2
#
C
% &e' de Pun(o de )*ui+alencia,
) ml e* + ,r Na O- . ) ml* + , -
(
C
(
O
#
Dato/ Na O-0
1 Na O- 2 . 0.5 N
3! . "" ml
3( . "".5 ml
3Na O- prom. . "".(5 ml
Dato/ -(C(O#0
3m! . 5 ml 4 m! . 5. !%%& ,r
3m( . 5 ml m( . 5. (((# ,r
m prom. . 5. (!! ,r
!N . ! e* + ,r . ! ml e* + ,r
L mL
N . ) e* + ,r . ) ml e* + ,r
3 5L6 3 5ml6
) ml e* + ,r Na O- . N 7 3 . 0.5 ml e* + ,r 7 "".(5 ml
ml
) ml e* + ,r Na O- . !&. &(5 ml e* + ,r
% )n el Pun(o de )*ui+alencia,
) ml e* + ,r Na O- . ) ml e* + ,r -(C(O#
) ml e* + ,r Na(C(O# . !&. &(5 ml e* + ,r
) ml e* + ,r -(C(O# . m 5ml ,r6
8e/o ml e* + ,r
8or lo tanto0 m 5ml ,r6 . ) ml e* + ,r -(C(O# 7 8e/o ml e* + ,r
8e/o ml e* + ,r -(C(O# . M . %0 m ,r . #5 m ,r
( ( ml e* + ,r ml e* + ,r
Entonce/0
m . !&. &(5 ml e* + ,r 7 #5 m ,r
ml e* + ,r
m . $#'. !(5 m ,r
m . 0. $#' !(5 ,r -(C(O#
Solu-ilidad en g/00 gr de solucin,

5. (!! ,r -(C(O# 0. $#' !(5 ,r -(C(O#
!00 ,r -(C(O# 9
9 . S . !#. "5$ ,r -(C(O# : !00 ,r de Solucin
T 1 $#
#
C
%% &e' de Pun(o de )*ui+alencia,
) ml e* + ,r Na O- . ) ml* + , -
(
C
(
O
#
Dato/ Na O-0
1 Na O- 2 . 0.5 N
3! . "!.' ml
3( . "!.5 ml
3Na O- prom. . "!. &5 ml
Dato/ -(C(O#0
3m! . 5 ml 4 m! . 5. ("'' ,r
3m( . 5 ml m( . 5. (!%! ,r
m prom. . 5. ((' ,r
!N . ! e* + ,r . ! ml e* + ,r
L mL
N . ) e* + ,r . ) ml e* + ,r
3 5L6 3 5ml6
) ml e* + ,r Na O- . N 7 3 . 0.5 ml e* + ,r 7 "!. &5 ml
ml
) ml e* + ,r Na O- . !5. '(5 ml e* + ,r
%% )n el Pun(o de )*ui+alencia,
) ml e* + ,r Na O- . ) ml e* + ,r -(C(O#
) ml e* + ,r Na(C(O# . !5. '(5 ml e* + ,r
) ml e* + ,r -(C(O# . m 5ml ,r6
8e/o ml e* + ,r
8or lo tanto0 m . ) ml e* + ,r -(C(O# 7 8e/o ml e* + ,r
8e/o ml e* + ,r -(C(O# . M . %0 m ,r . #5 m ,r
( ( ml e* + ,r ml e* + ,r
Entonce/0
m . !5. '(5 ml e* + ,r 7 #5 m ,r
ml e* + ,r
m . $!(. !(5 m ,r
m . 0. $!( !(5 ,r -(C(O#
Solubilidad en ,:!00 ,r de /olucin0
5. ((' ,r -(C(O# 0. $!( !(5 ,r -(C(O#
!00 ,r -(C(O# 9
9 . S . !". &(! ,r -(C(O# : !00 ,r de Solucin
T 1 &2
#
C
%%% &e' de Pun(o de )*ui+alencia,
) ml e* + ,r Na O- . ) ml* + , -
(
C
(
O
#
Dato/ Na O-0
1 Na O- 2 . 0.5 N
3! . (' ml
3( . ($. 5 ml
3Na O- prom. . ($. $5 ml
Dato/ -(C(O#0
3m! . 5 ml 4 m! . 5. (!0& ,r
3m( . 5 ml m( . 5. (!5& ,r
m prom. . 5. (!"! ,r
!N . ! e* + ,r . ! ml e* + ,r
L mL
N . ) e* + ,r . ) ml e* + ,r
3 5L6 3 5ml6
) ml e* + ,r Na O- . N 7 3 . 0.5 ml e* + ,r 7 ($. $5 ml
ml
) ml e* + ,r Na O- . !". '$5 ml e* + ,r
%%% )n el Pun(o de )*ui+alencia,
) ml e* + ,r Na O- . ) ml e* + ,r -(C(O#
) ml e* + ,r Na(C(O# . !". '$5 ml e* + ,r
) ml e* + ,r -(C(O# . m 5ml ,r6
8e/o ml e* + ,r
8or lo tanto0 m . ) ml e* + ,r -(C(O# 7 8e/o ml e* + ,r
8e/o ml e* + ,r -(C(O# . M . %0 m ,r . #5 m ,r
( ( ml e* + ,r ml e* + ,r
Entonce/0
m . !". '$5 ml e* + ,r -(C(O# 7 #5 m ,r
ml e* + ,r
m . &(#. "$5 m ,r
m . 0. &(# "$5 ,r -(C(O#
Solu-ilidad en g/00 gr de solucin,
5. (!" ,r -(C(O# 0. &(# "$5 ,r -(C(O#
!00 ,r -(C(O# 9
9 . S . !!. %$$ ,r -(C(O# : !00 ,r de Solucin
CUADRO II'
T (
0
.) "0' "0" (%'
/ T ". (#$ 7 !0
;"
". "00 7 !0
;"
". "5& 7 !0
;"
S (gr/00 gr Sol.) !#. "5$ !". &(! !!. %$$
&og (S) !. !5$ !. !"# !. 0$'