1 A 6 D 11 C 2 D 7 A 12 D 3 C 8 D 13 D 4 B 9 C 14 C 5 C 10 B 15 A
16. a) Each correct structure = 1 x 4 i. ii. iii. iv. b) Geometrical isomer present @ each C in C=C is surrounded by 2 different atoms / group of atoms [1]
cis - isomer trans - isomer (Structures [1] label cis trans [1] )
17. correct type of reaction [1] x 4 reagent [1] x 4 Type of reaction Reagent I Free radical substitution Br 2 under UV / hv ii. Elimination Alumina @ conc. H 2 SO 4
under heating iii. Oxidation Cold, dilute KMnO 4 /H +
@ OH - iv. Nucleophilic substitution Ethanolic conc. NH 3
under reflux
18. a) i. Calculate mole [1] ; stating empirical formula [1] Element Carbon, C Hydrogen, H Mass 92.3 7.7 Mole 92.3/12 = 7.7 7.7 / 1 = 7.7 Mol ratio 7.7 / 7.7 = 1 7.7 / 7.7 = 1 Empirical formula = CH ii. (CH) n = 104 ; (13)
x n = 104 ; n = 8 Molecular formula = C 8 H 8 [1] Structure [1]
iii. Major [1] Minor [1] (no label only 1)
iv. to produce polystyrene / container. 18 .b) Each structure = 1 m x 8 A : CH 3 CH 2 Cl / AlCl 3 B : Cl 2 ; uv C : D : I 2 in NaOH E : F : CH 3 COCl / AlCl 3
b) i. rate = k[CH 3 CH 2 CH 2 CH 2 Cl][CN - ] / CN - is first order [1] - increasing CN - will increase the rate of reaction [1] ii. - rate of reaction increased [1] Since C-Br bond length is longer / bond strength weaker [1] c) m1 : 2-chloro-2-methylpropane [1] m2 : [1] m3 : steric hindrance [1]
20.a) m1 : Acidity decrease according to order [1]
m2 : cyclohexane is electron-donating / positive inductive [1] m3 : caused alkoxide more readily to accept proton @ cause equilibrium shift to left [1] m4 : benzene is electron withdrawring / negative inductive [1] m5 : caused phenol more readily to donate proton @ caused equilibrium shift to right [1] m6 : NO 2 gives negative inductive / electron withdrawing / stabilised phenoxide ion formed [1]
20. b) Alternative 1 : Reagent : acidified KMnO 4 / H + [1] Observation : purple colour decolourised by cyclohexanol but not by phenol [1] Equation : [1]
Alternative 2 : Reagent : bromine water [1] Observation : brown colour decolourised and white precipitate is formed when added to phenol [1] Equation : bromination of phenol [1]
20 c) m1 : Saytzeff rule : in elimination of H-X or H 2 O, H is preferable to eliminate from neighbouring C with less H [1] m2 : reagent : alumina / conc. H 2 O under heating [1] m3 : Structure of 2,3-dimethylpentan-3-ol [1]