Test 12 Paper 1 JEE Advanced 2014

PHYSICS
1. (D)
2. (D)
3. (C)
4. (B)
5. (C)
6. (A)
7. (C)
8. (C)
9. (D)
10. (B)
11. (A, B, C, D)
12. (A, B, D)
13. (B, C)
14. (B, C, D)
15. (B, C, D)
16. (7)
17. (3)
18. (7)
19. (3)
20. (4)
CHEMISTRY
21. (B)
22. (B)
23. (D)
24. (B)
25. (B)
26. (A)
27. (A)
28. (B)
29. (B)
30. (D)
31. (A, B, C, D)
32. (A, B, C)
33. (B, C)
34. (A, B, C, D)
35. (A, B)
36. (7)
37. (3)
38. (4)
39. (6)
40. (2)
MATHEMATICS
41. (A)
42. (C)
43. (B)
44. (A)
45. (A)
46. (D)
47. (A)
48. (C)
49. (A)
50. (A)
51. (C, D)
52. (A, B, C)
53. (B, D)
54. (A, C, D)
55. (A, C)
56. (8)
57. (8)
58. (6)
59. (2)
60. (1)
ANSWERS
Test - 12 (Paper - I) (Answers & Hints) All India Aakash Test Series for JEE (Advanced)-2014
1/10
TEST - 12 (Paper - I)
All India Aakash Test Series for JEE (Advanced)-2014 Test - 12 (Paper - I) (Answers & Hints)
2/10
1. Answer (D)
x
dx
v = r = x sin
( sin )
M
dL dx x x
l

=

2
0
sin
l m
L x dx
l
=
2
sin
3
M l
L

=
axis
( sin ) sin
M
L dx x x
l

=

=
2
2
sin
3
M l

2. Answer (D)
By conservation of momentum
v
1
x
M
v
2
m
along x-axis, mv
0
= mv
1
cos + mv
2
cos ...(i)
along y-axis, mv
1
sin = mv
2
sin ...(ii)
By coefficient of restitution, e = 1
2 1
0
cos( )
1
0 cos )
v v
v
+
=

v
2
v
1
cos( + ) = v
0
cos ...(iii)
Solving (i), (ii) & (iii)
sin(2 )
sin
m
M
+
=
3. Answer (C)
Net acceleration,
( )
2 2
2 . cos
net
a a a a a = + +
2 sin
2
a

=
a
net
a
a
-
And its direction with horizontal is
2

=
4. Answer (B)
By COM, m
1
v
0
= (m
1
+ m
2
)v
1
0
1 2
m
v v
m m

=

+

By COE,
2 2
1 0 1 2 1 2
1 1
( )
2 2
mv m m v m gh = + +
2
0 2
1 2
2
v m
h
m m g

=

+
5. Answer (C)
By conservation angular momentum about P
0
P
2 2
0
2 2
2 1
5 5
MR x MR

= +

0
7
=
so
0
7
cm
R
v

=
ANSWERS & HINTS
PART - I (PHYSICS)
3/10
6. Answer (A)
Force on fluid element
x
dx
df = dm
2
x
2
dv
dm dm x
dt
=
2
dv
dm v dm x
dx
=
2
0
v
v dv xdx =

2 2
2
/ 2
2 2
l
l
v x
=

3
2
v l =
7. Answer (C)
According to the Wein's law,
1 2
1 2 m m
T T =
...(i)
As, power reduces to
1
16
By Stefan's law, P = AT
4
so T
1
= 2T
2
From (ii),
1 2
2 2
2
m m
T T =
2 1
2
m m
=
= 2 450 nm = 900 nm
8. Answer (C)
R v
v
s
m
By conservation of energy initially and at opening,
loss in PE = gain in KE,
2
1
2 2
GMm GMm
mv
R R
+ =
GM
v
R
=
Once particle enters into the shell, it experiences no
force hence, its velocity remains unaltered.
9. Answer (D)
2 2
1 1
2 2
AY
l mv
l

=

10. Answer (B)
Charge flow, U = qV
5
6
10 J
2.5 10 V
U
q
V
= =
= 0.4 10
11
C
No. of flow of electrons,
11
19
0.4 10 C
1.6 10 C
n

= 2.5 10
7
electrons
11. Answer (A, B, C, D)
Volume remains conserved,
3 3
1 1
3 3
R n r =
1/ 3
R n r =
Capacitance, C = 4
0
r C' = n
1/3
C
Potential
2/ 3
1/ 3
'
'
Q nq
V n V
C n C
= = =
Potential energy,
2 2
5/ 3
1/ 3
'
2 ' 2
Q n q
U n U
C n C
= = =
12. Answer (A, B, D)

v
AD
= v
AC
+ v
CD
i 6 = 4 5 + 5 2
i = 5A
Current in DB = i
AD
+ i
CD
= 2 + 5 = 7A
Also v
CB
= v
CD
+ v
DB
3 R = 5 2 + 7 5
R = 15
P
DC
= i
CD
2
R
DB
= (7)
2
5 = 245 watt
13. Answer (B, C)
0
2sin
4
i
B n
d n

=

/
n
/
n
a
a
0
2sin
4 cos
i
n
n
a
n

=

0
tan
2
ni
a n

=

And
Lt
n

0
2
i
B
a
=
tan( / )
( / )
Lt
n
n
n
=
0 0
1
2 2
i i
a a

=
4/10
14. Answer (B, C, D)
3000 rad/ s
30
= = 100 rad/s
rms
rms
2 2 2 2
24
( ) 4 (100 )
v
I
R L
= =
+ +
= 4.72A
Power P = I
rms
2
R = (4.72)
2
4 = 89 W
V
R
= I
rms
R = 4.72 4 = 18.88 V
V
L
= L I
rms
= 100 0.01 4.72 = 13.82 V
15. Answer (B, C, D)
For first surface,
2 2 2 1
1
v R

=
For 2nd surface,

3 3 2 2
2 1
v v R

=
v
1
v
2
=
Solving
3
2
3 1
R
v f

= =

when
3
>
1
, f = +ve
16. Answer (7)
2
2 2
1 1 1
( 1)
1
K
R z
z
2
1
2
1
( 1)
( 1)
z
z

=

z
1
1 =
1.5405
28
1.6548
= 27
z
1
= 28 = 4 7
so x = 7
17. Answer (3)
Mass defect, m = (2 2.0141 4.0026) 931 MeV
Energy used per reaction,
25
(2 2.0141 4.0026) 931
100
E =
= 5.9584 MeV = 9.5334 10
13
J
Total energy obtained in 25 days
= (200 MW) 24 3600 25
Mass of deuterium required
=
21 6
13
(0.669) 10 200 10 24 3600 25
3kg
9.5334 10
18. Answer (7)

Let
1 2 3

B Bi B j B k
= + +
Hence,
1 2 3

[ ( )] q vi B i B j B k + + =
0

( 3 4 ) qvB j k +
2 3 0 0

3 4 B k B j B j B k = +
B
2
= 4B
0
and B
3
= 3B
0
Also,
1 2 3

( q vj B i B j B k

+ +

=
0
(3 ) qvB i
2 3 0

3 B k B i B i + =
B
1
= 0
Hence,
0

(0 4 3 ) B i j k B = + +
so + + = 7.
19. Answer (3)
The energy of system at small angular displacement
2 2 2 2
1 1 1 1
(2 ) ( )
2 2 2 2
E k R k R mV I = + + +
Since E is a constant
0
dE
dt
=
2 2
4 0
d d dv d
kR kR mV I
dt dt dt dt

+ + + =
2 2
5 0 kR MR I + + =
2
2
5
.
kR
MR I

=

+
so,
10
.
3
k
M
= so
3
2
10
M
T
k
=
20. Answer (4)
Displacement of string in fundamental mode
y(x, t) =
sin .sin( )
x
A t
L

Consider an element dx at position x. Its mass is dm
= dx and it oscillates in a simple harmonic motion
with an amplitude
sin
x
A
L

and angular frequency
. Its energy is
2
2
1
( ) ( ) sin
2
x
dE dx A
L

=

5/10
Using .
T
L
2 2
2
sin
2
A T x
dE dx
L L

=

Total energy,
2 2
2
2
A T
E
L
= .
0
sin
L
x
dx
L

=
2 2
4
A T
L
.
so x = 4
PART - II (CHEMISTRY)
21. Answer (B)
Si
O
O
O
22. Answer (B)

Bismuth has outer electronic configuration 5s
2
5p
3
. Due
to inert pair effect +5 oxidation state of bismuth is
least stable.
23. Answer (D)
Me
Me
There is no element of symmetry.
24. Answer (B)
CH = CH CH = CH
2 2
CH CH CH = CH
2 2
DBr
D
CH CH = CH CH
2 2
D
Br
25. Answer (B)

OH
NH
2
HNO
2
N
2
+
OH
O
OH
C
H
H
+
26. Answer (A)
a
E
k Ae
RT
=
ln k
a
E
ln A
RT
=
a
E
ln k 5
RT
=
27. Answer (A)
Except Al all other metals are f - block elements.
28. Answer (B)
Free-radical mechanism.
29. Answer (B)
Fact
30. Answer (D)
NaH
+
Br
H
A, B, C and D are chiral because they neither have
plane of symmetry nor centre of symmetry.
32. Answer (A, B, C)
Br
H
Br
H
I
33. Answer (B, C)
Hydroxylic solvents such as water, ethanol will react
with (CH
3
CO)
2
6/10
Co
O
O C
O C
O
+3
, C
2
O
4
2
behaves as a strong ligand
35. Answer (A, B)
Heisenberg test and HNO
2
test.
36. Answer (7)
4 6 2
10 6
C H O 2
2
=
6 12 2
16 12 4
C H N 2
2 2
= =
8 11 3 2
19 13 6
C H O Br N 3
2 2
= =
37. Answer (3)
N N, N N O,
+
H N N N
+
F N N F, H N N H N N
H H
H H
N N
N N
H
H
H
H
N N
O
O
O
N O N
O
O
O
O
O
38. Answer (4)
CH
3
CH
CH
2
CH
2
CH
2
C
H
O
H
H
+
CH
3
CH
O
H
CH
OH
CH
3
O
OH
+
O
Two chiral carbons hence four stereoisomers.
39. Answer (6)
(iii)
(ii)
O
(i)
O
O O
( )
2
2
2 3
2 1.225 5.2 6
2 2
a
a a

= = = =

40. Answer (2)
C = C both bonds behave as a bonds according to
MOT.
PART - III (MATHEMATICS)
41. Answer (A)
x dy y dx + ln
x
x dy
y

= 0
2 2
ln
x x y dx x dy
dy
y y y
2
ln .
x x x
dy d
y y y

=

ln
x
d
y dy
y x x
y y

=

ln ln lnln
x
y c
y

+ =

ln
cy
x
cy x ye
y
= =
cy
y xe
=
42. Answer (C)
2
2 4
5
5 4.5 5
x
x x
I dx =

Put 5
2x
= t
2.5
2x
ln5 dx = dt
7/10
=
2
1
2ln5
5 4
dt
t t
=
2
1
2ln5
9 ( 2)
dt
t +
=
1
1 2
sin
2ln5 3
t
c
+
+

=
2
1
1 5 2
sin
2ln5 3
x
c

+
+

43. Answer (B)
f(x) = sin
4
x + cos
6
x
1
4
cos2x
1
32
cos6x
=
2 2
1 cos2 cos3 3cos
2 4
+
+

x x x
1 1
cos2 cos6
4 32
x x
=
1
4
(1 2cos2x + cos
2
2x) +
1
16
(cos
2
3x + 9cos
2
x
+ 6cos3x cosx)
1
4
cos2x
1
32
cos6x
=
1
32
[8 16 cos2x + 4 (1 + cos4x) + 1 + cos6x +
9(1 + cos2x) + 6(cos4x + cos2x) + cos2x cos6x]
=
1
[22 10cos4 ]
32
x +
fundamental period is
2
44. Answer (A)

tan tan tan tan tan . sin ( )
tan tan sin sin
A B A C A B C
B C B C
+ +
=
=
2
sin
cos sin sin
A
A B C
=
2 2
2 2 2
. .
2
k a
b c a
kb kc
bc

+

=
2
2 2
2 1
6 13
a
a a
=
45. Answer (A)

C, E, L, M, O, P, X
Words starting with CE or CL or CM = 5! each
Words starting with COE or COL = 4! each
Words starting with COME or COML = 3! each
Words starting with COMPE = 2!
Next words is COMPLEX
words before COMPLEX = 360 + 48 + 12 + 2
= 422
46. Answer (D)
342
2
1
2 2
sin cos
7 7
i i
=

+

=
342
1
2 2
cos sin
7 7
i i

=

+

=
342
1
i

=

where
7
= 1 and 1 + +
2
+ ...
6
= 0
=
2 3 4 5 6
1 1 1 1 1 1
i i

+ + + + + =

47. Answer (A)
+ = 3, = k,
3 7
3
+ =
Solving, we get
8 = 18 =
9 3
,
4 4
=
k = =
27
16
.
48. Answer (C)
cy bz qz ry rb cq
az cx rx pz pc ar
bx ay py xq aq pb

=

cy bz rb cq qz ry
az cx pc ar rx pz
bx ay aq pb py xq
2
| | 25 = = = adjA A
8/10
49. Answer (A)
Slope of BC =
3 3 1 1
3
4 1
+
=
/3
/3
B(1, 1)
A
(1, 1)
0
(4,3 3 1) +
3 3
BC is inclined at an angle
3
to x-axis
Bisector of ABC is inclined at angle
2
3
.
Equations of required bisector is
1 3 ( 1) y x =
3 3 1 x y + = +
50. Answer (A)
Let the plane be 1
x y z
a b c
+ + =
where a
2
+ b
2
+ c
2
= 100 ...(i)
Equation of line through origin and perpendicular to
the plane is
1 1 1
x y x
a b c
= = = (say)
Let the foot of the perpendicular be P :
, ,
a b c

It lies on the plane. Therefore
2 2 2
1 1 1
1
a b c

+ + =

2 2 2
2 2 2
a b c

+ + = ...(ii)
Also from (i)
2 2 2
2
100
+ + =

a b c
2
2 2 2
100
=

+ +

a b c
...(iii)
From (ii) and (iii)
2
2 2 2
2 2 2 2 2 2
100
a b c
a b c

+ + =

+ +

The locus of P is (x
2
+ y
2
+ z
2
)
2
=
2 2 2
100
1 1 1
x y z
+ +
51. Answer (C, D)
Clearly f takes value 1 whenever 2x is integer while g
takes value zero whenever 2x is an integer.
f and g intersect at no point.
1
2
g
x
f
0 1 3
2
2
y
Required area =
( )
4
2
0
{2 } {2 } x x dx
=
( )
1
2
2
0
8 2 (2 ) x x dx
=
( )
1/2
3/ 2
1/2
3
0
0
2 4
8 2
3 3
x
x

=
8 1
1
3 2

=
4
3
sq. units.
52. Answer (A, B, C)
1 3
2 0
2 3 4
= and
2
+ 4 +
2
=
2
+ 8 = 2
When = 2,
1 3
2 2 0
2 3 4
=
(8 6) (4 4) + 3(3 4) = 0
4
2
13 + 10 = 0
(4 5) ( 2) = 0
5
, 2
4
=
9/10
When = 2,
1 3
2 2 0
2 3 4
=
(8 + 6) (4 + 4) + 3(3 4) = 0
4
2
5 2 = 0
=
5 25 32 5 57
8 8
+
=
53. Answer (B, D)
1 0
1/3
2
x
1/3
y
1
1/3
2
2
, 1 1
3
2
( ) 2 , 1 2
3
2
, 2
3
x x x
f x x x x
x x
< <
= + <
>
Clearly f(x) is not differentiable at x = 0, 2. f(x) attains

minima at x = 1
54. Answer (A, C, D)
x
2
+ y
2
= 4 has a tangent y = mx + 2
2
1 m + . If this
line is also tangent to 2nd circle
then,
2
2
5 2 1
2
1
m m
m
+ +
=
+
5m +
2 2
2 1 2 1 m m + = +
m = 0 or 5m =
2
4 1 m +
25m
2
= 16 + 16m
2
m =
4
3
55. Answer (A, C)
4 2 4 2
( 1). 2 3 6 I x x x x x x dx = + + + +
=
5 3 6 4 2
( ) 2 3 6 x x x x x x dx + + + +
x < 0
=
1
.
6
t t dt

, 2x
6
+ 3x
4
+ 6x
2
= t
2
=
3
1
18
t c +
= 12(x
5
+ x
3
+ x) dx = 2t dt
=
1
18
(2x
6
+ 3x
4
+ 6x
2
)
3/2
+ c
=
3
| |
18
x
(2x
4
+ 3x
2
+ 6)
3/2
+ c
=
3
18
x
(2x
4
+ 3x
2
+ 6) + c
Similarly if x 0
5 3 6 4 2
( ) 2 3 6 = + + + +
I x x x x x x dx
=
3
18
x
(2x
4
+ 3x
2
+ 6)
3/2
+ c
56. Answer (8)
Equation does not have real and distinct roots
D 0 12 4log
2
k 0
log
2
k 3 k 8
The minimum value of k = 8
57. Answer (8)
2 2
3 3
0
5(2sin 2 )
lim
(4 )
2 4 ... 8 ...
3 3

+ + + +

x
x
x x
x x x x
4
4
0
4
sin2
20 . 16
2
lim
128 8
terms of
3 3
x
x
x
x
x x

=

+

320
8
40
= =
58. Answer (6)
Favourable cases
= co-efficient of x
9
in (x
1
+ x
2
+ ...+ x
6
)
3
10/10
= co-efficient of x
9
in
3
6
(1 )
1
x x
x

= co-efficient of x
6
in (1 3x
6
+ ...) (1 x)
3
=
8
C
6
3 = 25
The required probability =
25
216
p =
216p 19 = 6
59. Answer (2)
1 1 1 1
.....
1 4 4 7 7 10 46 49
+ + + +
+ + + +
1 4 4 7 7 10 46 49
...
3 3 3 3

= + + + +

1 7
2
3
= =

60. Answer (1)
2
1
1
2
2 7
4
3
2
5
4
2
[ 2 cos ] x dx
5 / 4 3 /2 7 / 4 2
5 / 4 3 / 2 7 / 4
2 1 0

= + + +

dx dx dx dx
2 1 0 1
4 4 4 2

= + + =

p = 1, q = 2
|p q| = 1

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PHYSICS

12. Answer (A, B, D)

For 2nd surface,

18. Answer (7)

22. Answer (B)

25. Answer (B)

44. Answer (A)

45. Answer (A)

Clearly f(x) is not differentiable at x = 0, 2. f(x) attains

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