PIROMETALURGIA GENERAL

MIN 220

TRABAJO PRCTICO 1
DIAGRAMA Fe O - S
La reacciones sern:
1. 2Fe + O2(g) = 2FeO
2. Fe + SO2(g) = FeS + O2(g)
3. 2/3FeO +2/3 SO2(g) =2/3 FeS + O2(g)

Para la primera reaccin:

2Fe + O2(g) = 2FeO

(

(
(

Para la segunda reaccin:

Fe + SO2 (g) = FeS + O2 (g)

(
(

Para la tercera reaccin:

)
)

2/3FeO +2/3 SO2 (g) =2/3 FeS + O2 (g)

(
(

)
(

Lpez Flores Luis Alberto

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

Temperatura [C]

800

2Fe + O2 = 2FeO

G = -126670 + 31.58*T

Tem [K]

1073

1.987

-92785

aFe

aFeO

LogPo2

LogPso2

0.1

-20.9

-22.000

0.9

0.48

-20.1573

-21.111

0.8

0.6

-19.4754

-20.099

0.7

0.64

-19.0793

-19.087

0.6

0.66

-18.7094

-18.075

0.5

0.61

-18.5023

-17.063

0.4

0.49

-18.4942

-16.051

0.3

0.35

-18.5917

-15.039

0.2

0.22

-18.7094

-14.500

0.1

0.10

-18.9081

-14.210

1.0

1.0

-21.56

-13.920

Fe + SO2 = FeS + O2

Lpez Flores Luis Alberto

G = 49119 - 3.4768*T

Tem [K]

1073

1.987

45388.4

aFe

aFeS

LogPo2

LogPso2

1.0

1.0

-21.56

-13.920

0.9

0.3

-22.5

-14.353

0.8

0.5

-23.5

-14.724

0.7

0.7

-24.5

-15.254

0.6

0.9

-25.5

-15.849

0.5

0.7

-26.5

-16.918

0.4

0.5

-27.5

-18.031

0.3

0.3

-28.5

-19.254

0.2

0.1

-29.5

-20.948

0.1

0.02

-30

-22.364

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

2/3FeO + 2/3SO2 = 2/3FeS + O2

G = 74690 - 12.519*T

Tem [K]

1073

1.987

61257.1

aFeO

aFeS

LogPo2

LogPso2

1.0

0.1

-16.5

-8.336

0.9

0.3

-17

-7.882

0.8

0.5

-17.5

-8.003

0.7

0.7

-18

-8.283

0.6

0.9

-18.5

-8.628

0.5

0.7

-19

-9.447

0.4

0.5

-19.5

-10.310

0.3

0.3

-20

-11.283

0.2

0.1

-20.5

-12.726

1.0

1.0

-21.56

-13.920

Diagrama Fe - O - S a Actividades Normales

Nro

Log pO2(g)

Log pSO2(g)

Log pO2(g)

Log pSO2(g)

Fe-FeO

-21.558

-22.000

-21.558

-13.920

Fe-FeS

-30.000

-15.934

-21.558

-13.920

FeO-FeS

-17.359

-5.000

-21.558

-13.920

Lpez Flores Luis Alberto

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

DIAGRAMA Fe - O - S
-6.0
-8.0

Log(Pso2)

-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-30.0

-28.0

-26.0

-24.0

-22.0

-20.0

-18.0

-16.0

Log(Po2)

Lpez Flores Luis Alberto

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

Temperatura [C]

850

2Fe + O2 = 2FeO

G = -126670 + 31.58*T

Tem [K]

1123

1.987

-91206

aFe

aFeO

LogPo2

LogPso2

0.1

-19.7512

-22.000

0.9

0.48

-19.0084

-21.111

0.8

0.6

-18.3266

-20.099

0.7

0.64

-17.9305

-19.087

0.6

0.66

-17.5606

-18.075

0.5

0.61

-17.3535

-17.063

0.4

0.49

-17.3453

-16.051

0.3

0.35

-17.4429

-15.039

0.2

0.22

-17.5606

-14.500

0.1

0.10

-17.7592

-14.210

1.0

1.0

-21.56

-13.920

Fe + SO2 = FeS + O2

Lpez Flores Luis Alberto

G = 49119 - 3.4768*T

Tem [K]

1123

1.987

45214.6

aFe

aFeS

LogPo2

LogPso2

1.0

1.0

-21.56

-13.920

0.9

0.3

-22.5

-14.799

0.8

0.5

-23.5

-15.170

0.7

0.7

-24.5

-15.700

0.6

0.9

-25.5

-16.294

0.5

0.7

-26.5

-17.363

0.4

0.5

-27.5

-18.477

0.3

0.3

-28.5

-19.700

0.2

0.1

-29.5

-21.393

0.1

0.02

-30

-22.809

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

2/3FeO + 2/3SO2 = 2/3FeS + O2

G = 74690 - 12.519*T

Tem [K]

1123

1.987

60631.2

aFeO

aFeS

LogPo2

LogPso2

1.0

0.1

-16.5

-9.352

0.9

0.3

-17

-8.898

0.8

0.5

-17.5

-9.019

0.7

0.7

-18

-9.299

0.6

0.9

-18.5

-9.644

0.5

0.7

-19

-10.463

0.4

0.5

-19.5

-11.326

0.3

0.3

-20

-12.299

0.2

0.1

-20.5

-13.742

1.0

1.0

-21.56

-13.920

Diagrama Fe - O - S a Actividades Normales

Fe-FeO

-21.558

-22.000

-21.558

Log
pSO2(g)
-13.920

Fe-FeS
FeOFeS

-30.000

-15.934

-21.558

-13.920

-17.359

-5.000

-21.558

-13.920

Nro

Lpez Flores Luis Alberto

Log pO2(g)

Log pSO2(g)

Log pO2(g)

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

DIAGRAMA Fe - O - S
-6.0
-8.0

Log(Pso2)

-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-30.0

-28.0

-26.0

-24.0

-22.0

-20.0

-18.0

-16.0

Log(Po2)

Lpez Flores Luis Alberto

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

Temperatura [C]

900

2Fe + O2 = 2FeO

G = -126670 + 31.58*T

Tem [K]

1173

1.987

-89627

aFe

aFeO

LogPo2

LogPso2

0.1

-18.7004

-22.000

0.9

0.48

-17.9576

-21.111

0.8

0.6

-17.2757

-20.099

0.7

0.64

-16.8796

-19.087

0.6

0.66

-16.5097

-18.075

0.5

0.61

-16.3027

-17.063

0.4

0.49

-16.2945

-16.051

0.3

0.35

-16.3921

-15.039

0.2

0.22

-16.5097

-14.500

0.1

0.10

-16.7084

-14.210

1.0

1.0

-21.56

-13.920

Fe + SO2 = FeS + O2

Lpez Flores Luis Alberto

G = 49119 - 3.4768*T

Tem [K]

1173

1.987

45040.7

aFe

aFeS

LogPo2

LogPso2

1.0

1.0

-21.56

-13.920

0.9

0.3

-22.5

-15.206

0.8

0.5

-23.5

-15.577

0.7

0.7

-24.5

-16.107

0.6

0.9

-25.5

-16.702

0.5

0.7

-26.5

-17.771

0.4

0.5

-27.5

-18.884

0.3

0.3

-28.5

-20.107

0.2

0.1

-29.5

-21.801

0.1

0.02

-30

-23.217

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

2/3FeO + 2/3SO2 = 2/3FeS + O2

G = 74690 - 12.519*T

Tem [K]

1173

1.987

60005.2

aFeO

aFeS

LogPo2

LogPso2

1.0

0.1

-16.5

-10.281

0.9

0.3

-17

-9.827

0.8

0.5

-17.5

-9.949

0.7

0.7

-18

-10.229

0.6

0.9

-18.5

-10.573

0.5

0.7

-19

-11.392

0.4

0.5

-19.5

-12.255

0.3

0.3

-20

-13.229

0.2

0.1

-20.5

-14.672

1.0

1.0

-21.56

-13.920

Diagrama Fe - O - S a Actividades Normales

Fe-FeO

-21.558

-22.000

-21.558

Log
pSO2(g)
-13.920

Fe-FeS
FeOFeS

-30.000

-15.934

-21.558

-13.920

-17.359

-5.000

-21.558

-13.920

Nro

Lpez Flores Luis Alberto

Log pO2(g)

Log pSO2(g)

Log pO2(g)

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

DIAGRAMA Fe - O - S
-6.0
-8.0

Log(Pso2)

-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-30.0

-28.0

-26.0

-24.0

-22.0

-20.0

-18.0

-16.0

Log(Po2)

Lpez Flores Luis Alberto

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

Temperatura [C]

950

2Fe + O2 = 2FeO

G = -126670 + 31.58*T

Tem [K]

1223

1.987

-88048

aFe

aFeO

LogPo2

LogPso2

0.1

-17.7354

-22.000

0.9

0.48

-16.9926

-21.111

0.8

0.6

-16.3108

-20.099

0.7

0.64

-15.9146

-19.087

0.6

0.66

-15.5448

-18.075

0.5

0.61

-15.3377

-17.063

0.4

0.49

-15.3295

-16.051

0.3

0.35

-15.4271

-15.039

0.2

0.22

-15.5448

-14.500

0.1

0.10

-15.7434

-14.210

1.0

1.0

-21.56

-13.920

Fe + SO2 = FeS + O2

Lpez Flores Luis Alberto

G = 49119 - 3.4768*T

Tem [K]

1223

1.987

44866.9

aFe

aFeS

LogPo2

LogPso2

1.0

1.0

-21.56

-13.920

0.9

0.3

-22.5

-15.580

0.8

0.5

-23.5

-15.952

0.7

0.7

-24.5

-16.482

0.6

0.9

-25.5

-17.076

0.5

0.7

-26.5

-18.145

0.4

0.5

-27.5

-19.258

0.3

0.3

-28.5

-20.482

0.2

0.1

-29.5

-22.175

0.1

0.02

-30

-23.591

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

2/3FeO + 2/3SO2 = 2/3FeS + O2

G = 74690 - 12.519*T

Tem [K]

1223

1.987

59379.3

aFeO

aFeS

LogPo2

LogPso2

1.0

0.1

-16.5

-11.135

0.9

0.3

-17

-10.681

0.8

0.5

-17.5

-10.802

0.7

0.7

-18

-11.082

0.6

0.9

-18.5

-11.427

0.5

0.7

-19

-12.246

0.4

0.5

-19.5

-13.109

0.3

0.3

-20

-14.082

0.2

0.1

-20.5

-15.525

1.0

1.0

-21.56

-13.920

Diagrama Fe - O - S a Actividades Normales

Fe-FeO

-21.558

-22.000

-21.558

Log
pSO2(g)
-13.920

Fe-FeS
FeOFeS

-30.000

-15.934

-21.558

-13.920

-17.359

-5.000

-21.558

-13.920

Nro

Lpez Flores Luis Alberto

Log pO2(g)

Log pSO2(g)

Log pO2(g)

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

DIAGRAMA Fe - O - S
-6.0
-8.0

Log(Pso2)

-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-30.0

-28.0

-26.0

-24.0

-22.0

-20.0

-18.0

-16.0

Log(Po2)

Lpez Flores Luis Alberto

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

Temperatura [C]

1000

2Fe + O2 = 2FeO

G = -126670 + 31.58*T

Tem [K]

1273

1.987

-86469

aFe

aFeO

LogPo2

LogPso2

0.1

-16.8462

-22.000

0.9

0.48

-16.1035

-21.111

0.8

0.6

-15.4216

-20.099

0.7

0.64

-15.0255

-19.087

0.6

0.66

-14.6556

-18.075

0.5

0.61

-14.4485

-17.063

0.4

0.49

-14.4404

-16.051

0.3

0.35

-14.5379

-15.039

0.2

0.22

-14.6556

-14.500

0.1

0.10

-14.8543

-14.210

1.0

1.0

-21.56

-13.920

Fe + SO2 = FeS + O2

Lpez Flores Luis Alberto

G = 49119 - 3.4768*T

Tem [K]

1273

1.987

44693

aFe

aFeS

LogPo2

LogPso2

1.0

1.0

-21.56

-13.920

0.9

0.3

-22.5

-15.925

0.8

0.5

-23.5

-16.296

0.7

0.7

-24.5

-16.826

0.6

0.9

-25.5

-17.421

0.5

0.7

-26.5

-18.490

0.4

0.5

-27.5

-19.603

0.3

0.3

-28.5

-20.826

0.2

0.1

-29.5

-22.520

0.1

0.02

-30

-23.936

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

2/3FeO + 2/3SO2 = 2/3FeS + O2

G = 74690 - 12.519*T

Tem [K]

1273

1.987

58753.3

aFeO

aFeS

LogPo2

LogPso2

1.0

0.1

-16.5

-11.921

0.9

0.3

-17

-11.467

0.8

0.5

-17.5

-11.589

0.7

0.7

-18

-11.869

0.6

0.9

-18.5

-12.213

0.5

0.7

-19

-13.032

0.4

0.5

-19.5

-13.895

0.3

0.3

-20

-14.869

0.2

0.1

-20.5

-16.312

1.0

1.0

-21.56

-13.920

Diagrama Fe - O - S a Actividades Normales

Fe-FeO

-21.558

-22.000

-21.558

Log
pSO2(g)
-13.920

Fe-FeS
FeOFeS

-30.000

-15.934

-21.558

-13.920

-17.359

-5.000

-21.558

-13.920

Nro

Lpez Flores Luis Alberto

Log pO2(g)

Log pSO2(g)

Log pO2(g)

Ingeniera Metalrgica

PIROMETALURGIA GENERAL

MIN 220

DIAGRAMA Fe - O - S
-6.0
-8.0

Log(Pso2)

-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-30.0

-28.0

-26.0

-24.0

-22.0

-20.0

-18.0

-16.0

Log(Po2)

Lpez Flores Luis Alberto

Ingeniera Metalrgica