KHOA K THUT HA HC

TRNG I HC BCH KHOA TP. H CH MINH

TIU LUN
AEROGEL-SILICA V NG D NG
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
M C L C
M C L C .............................................................................................................................. 2
2.1.Qu trnh sol gel: ....................................................................................................... 5
2.3.Ti n ch t c a qu trnh Sol-el. ...................................................................................!
1. Gii thiu aegogel
1.1. nh ngha:
! "#t liu t$ng h%& '( ngu)n g*' t+ ,-t lo.i gel t/ong 0( th!nh &h1n 'h2t
l3ng '4a gel 05%' tha6 th7 89ng ,-t lo.i :h;. K7t <u= l!, 'ho gel '( t> t/?ng th2& "!
'@'h nhit. A( 'Bn '( '@' tCn g?i Dau: :h(i 0(ng 8EngF :hGng :h; /HnF :h*i /Hn. Io
t;nh 'h2t ,J "! &hKn t@n @nh D@ng t/ong "#t liu nCn t/ong gi*ng nh5 &ol6etilen 8 L&
l.i th!nh ,-t :h*i.
1.2. Lc !"#
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
CMng gi*ng nh5 '@' lo.i t/u6Nn thu67t ,! 8.n t+ng 0?' :h@'F t/u6Nn thu67t "N
Ae/ogel :h@ 8; On "! thP ". T2t '= nhQng gR ,! 'hPng ta 8i7t 0( l! "!o 'u*i nhQng
nE, 1STUF gi@o D5 h(a h?' ng5Ji VW '( tCn Xa,uel KiDtle/ Y1SUU Z 1S[\] 0^ '( ,-t
'u-' '@ 0- "i 0)ng nghi& '4a ,Rnh l! Cha/leD ea/ne_. KiDtle/ tin /9ng D` t)n t.i
,-t lo.i gel :hGng l3ng Y,-t 0a' t;nh '* hQu '4a gel] "i ,-t '2u t/P' "G 'bng 0a'
8itF 0( l! ,.ng l5i '@' lc /cng "G 'bng nh3 05%' g?i l! nano&o/e.
Xau :hi thd nghi, "! ga& nhiNu th2t 8.iF 'u*i 'bng thR KiDtle/ 0^ t/e th!nh
ng5Ji 01u tiCn tha6 th7 05%' t/.ng th@i l3ng '4a gel th!nh t/.ng th@i :h; 0f t.o /a ,-t
lo.i gel ,i :hGng t)n t.i e t/.ng th@i l3ng. g!o nE,F 1Sh1F Gng 0^ 'Gng 8* &h@t hin
'4a ,Rnh t/ong 8!i "i7t iCohe/ent jk&an_e_ Ae/ogelD an_ lellieDiF 0Eng t/Cn t.& 'h;
:hoa h?' Aatu/e.
1.h. mhKn lo.i Ae/ogel:
C( 8a lo.i Ae/ogel &h$ 8i7n nh2t hin na6 0( l! Dili'aF 'a/8on "! okit :i,
lo.iF tu6 nhiCn t/ong thd nghi, lnn tho' t7 thR Dili'a "nn th5Jng 05%' Dd _png hqn '=.
Khi nhH' 07n Ae/ogelF /2t '( thf ng5Ji ta 0ang @, 'h> 07n lo.i Dili'a. C@' 8.n 'Mng
:hGng nCn nh1, lnn giQa Dili'a "! Dili'onF Dili'a YDili' 0iGk;t] l! lo.i "#t liu 'h4 67u
0f D=n ku2t /a th46 tinh '@'h nhit 'Bn Dili'on l! ,-t 'h2t 8@n _nn _bng t/ong '@' "i
,.'h.
KhGng gi*ng nh5 Dili'a ae/ogel "i 8it _anh l! :h(i kanh ha6 :h(i l.nhF
:h(i /Hn Y_o hRnh thb ,J =o '4a n(]F 'a/8on ae/ogel '( ,!u 0en "! :hi DJ lCn '( '=,
gi@' gi*ng nh5 0ang DJ lCn nhQng hBn than. ChPng '( _in t;'h 8N ,at lnF 0- k*&
'ao "! :h= nEng _nn 0in t*t. C@' t;nh 'h2t n!6 l!, 'ho ae/ogelD 'a/8on /2t hQu ;'h
0*i "i tp 0inF &in "! h th*ng :hd ,u*i.
Ae/ogel oki_e :i, lo.i l!, t+ G k;t :i, lo.i "! Dd _png nh5 l! 'h2t kP' t@'
t/ong '@' &h=n rng h(a h?'. ChPng 'Mng 05%' rng _png t/ong ng!nh 'Gng nghi&
thu*' n$F D%i nano 'a/8on "! th#, 'h; l! 0f t.o /a t+ t;nh. Ae/ogel okit :i, lo.i nh5
DHt ha6 '/o, ngo!i '@' t;nh 'h2t t5qng to ng5Ji anh e, Dili'a &h$ 8i7n thR 'hPng 'Bn
'( ,-t 0if, :h@'F 0( l! ,!u DH' /2t 0s&. Ae/ogel '/o, '( ,!u kanh l@ 'K6 hoa' kanh
_5qng /2t 0#,t Ae/ogel okit nhG,F titaniaF ui/'onia '( ,!u kanh hoa' t/Hngt Ae/ogel
okit DHt '( ,!u 03 hoa' "!ng 0p't ngo!i /a 'Bn '( ,!u t;, hoa o=i h5qngF ,!u "!ng
D@ngF ,!u h)ng &ht... Vci lo.i okit :i, lo.i D` t.o /a ,-t lo.i ,!u :h@' nhau.
Ae/ogel Dili'a '( ,!u kanh _a t/JiF ,!u n!6 05%' t.o /a :hi '@' @nh D@ng t/Hng
ga& '@' &hKn td Dili'a '4a ae/ogel "! k=6 /a hin t5%ng t@n k. Yva6leigh]. C@' &hKn td
D` t@n k. @nh D@ngF nhQng tia D@ng '( 85' D(ng ngHn thR 8 t@n k. _w _!ng hqn Do "i
D(ng _!i. xei "R ,!u kanh "! ,!u t;, '( 85' D(ng ngHn nh2t nCn 'hPng _w 8 t@n k.
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
hqn '@' @nh D@ng '( thf nhRn th26 :h@'. Vat :h@'F _o ,Ht ng5Ji nh.6 '=, "i '@'
85' D(ng ,!u kanh la, hqn nCn 'hPng ta D` :hGng thf nhRn th26 05%' ,!u t;,.
1.y. X=n ku2t:
Ae/ogel 05%' D=n ku2t 89ng '@'h l26 th!nh &h1n l3ng /a :h3i gel 89ng :W thu#t
:hG DiCu ti h.n. iNu n!6 'ho &hL& 'h2t l3ng 05%' l!, :hG t+ t+ ,! :hGng gK6 /a
hin t5%ng Dp& 0$ "#t liu. Ae/ogel 01u tiCn 05%' D=n ku2t t+ Dili'agel
Ae/ogel 8Ht 01u ku2t hin nh5 ,-t lo.i gel "! 05%' g?i l! Al'ogel Z '@i tCn n!6 @, 'h>
gel Dili'a YXili' 0iGk;t] "! '@' &hKn tdi /5%u YAl'ohol] n9, 8Cn t/ong '@' lc /cng '4a
n(. gN 'q 8=nF 'h> '1n 'ho /5%u 8a6 hqi :h3i Dili'a l! 'hPng ta D` t.o /a '2u t/P' n!6F
gi*ng nh5 'hPng ta th$i :hGng :h; <ua ,-t ,i7ng 8?t 8ifn th2, n5' "#6F n( D` 8
:hG 0i. Tha6 "R 'h> _oa t/Cn Do 8*' hqiF gel :hG DiCu ti h.n YXu&e/'/iti'all6] 05%' 'h7
t.o <ua '@' 'Gng 0o.n nh5 Dau:
Ahit 0- "! @& Du2t &h=i 0.t 07n 0if, DiCu ti h.n Z e ,r' ,! :hGng '( Do
:h@' 8it giQa 'h2t l3ng "! 'h2t :h;.
Gi=, @& Du2t t/ong :hi nhit 0- "nn e t/Cn 0if, ti h.n. Khi @& Du2t gi=,F '@'
&hKn td 05%' gi=i &h(ng _5i _.ng :h; "! l3ng "i ,#t 0- :hGng _!6 0a'
Khd gel 89ng ngu)n nhit. T/5' :hi l!, l.nhF D` '( ,-t l5%ng /5%u nh3 05%'
ng5ng tp l.i th!nh 'h2t l3ngF Dau 0( D` 05%' 'hu6fn th!nh _.ng hqi nh5 8an 01u.
Kif, t/a th!nh &hO, 'u*i 'bng. AhQng gR 'Bn l.i D` l! ,-t 'h2t /Hn 89ng
Dili'aF nh5ng tha6 "R e _.ng l3ng thR n( l.i 'hra 016 :hGng :h;.
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
if, DiCu ti h.n D` l!, :hG '@' 'h2t l3ng zal'o{ :hi7n ,-t &h1n '4a al'ogel
8i7n th!nh :h;F t/ong :hi '2u t/P' lc /cng '4a Dili'a "nn :hGng 8 Dp& 0$. A'ogel Dau
:hi 8 :hd /5%u D` 05%' g?i l! Ae/ogel Y/5%u 0^ 8 tha6 th7 89ng :h;]. Gi=, \U 07n
SS| :h*i l5%ng 8an 01uF Ae/ogel l! lo.i "#t liu nhsF linh ho.t "! /2t hQu _png.
2. T$%& '( A)*+&), -.%& (/0%& (1( !+,2&),
}u@ t/Rnh DolZgel l! ,-t &h5qng &h@& /2t &h$ 8i7n "! 0@ng tin '#6 0f t$ng h%& "#t
liuF 0a' 8it l! '@' okit :i, lo.i "i Do 0)ng nh2t :;'h th5' h.t nh3F "! hRnh th@i 0a
_.ng ~\Z1U. A( liCn <uan 07n <u@ t/Rnh 'hu6fn 0$i '4a ,-t h t+ &ha l3ng iDoli th!nh
&ha /Hn igeli.}u@ t/Rnh DolZgel thGng th5Jng '( thf 05%' 'hia th!nh '@' 85' Dau:
hRnh th!nh _ung _'hF 0E' laiF gi! gelF :hGF "! 'G 0a'. V-t "!i nhQng 5u 0if, <uan
t/?ng '4a <u@ t/Rnh DolZgel l! Do 0qn gi=n '4a n(F "! tho' t7 l! n( l! ,-t 8in &h@&
:inh t7 "! hiu <u= '4a D=n ku2t "#t liu 'h2t l5%ng 'ao. <u@ t/Rnh DolZgel 0^ 05%' rng
_png t/ong D=n ku2t :;nh 'h2t l5%ng 'ao 'ho '@' th!nh &h1n <uang h?' "! D%iF l& &h4
,!ng ,3ngF "! 8-t okit t*t ~11Z1\
2.1. 341 5*6% !+, 7 &),#
}u@ t/Rnh XolZgel '( ngha l! Do t$ng h%& ,-t ,.ng l5i "G 'q '4a ,-t &h=n
rng h(a h?' t/ong _ung _'h e nhit 0- th2& hoa' Do hRnh th!nh '4a ,-t ,.ng l5i "G
0nh hRnh 0*i ngh'h "i :7t tinh t+ _ung _'h. a' 0if, / /!ng nh2t '4a &h=n rng
n!6 l! Do 'hu6fn 0$i t+ ,-t _ung _'h :eo Y'h2t l3ng] Dang ,-t hai Zhoa' 0a &ha gel
Y/Hn] _nn 07n :h@i ni, i<u@ t/Rnh DolZgeli.
Xo hRnh th!nh hu6Nn &hb 0)ng nh2t '4a '@' h.t :eo thf 05%' hifu theo t;nh to@n t*'
0- lHng gi= 0nh /9ng '@' h.t '( hRnh '1u 0f @& _png 0nh lu#t Xto:eD . T*' 0- lHng l!
0- nht '4a ,Gi t/5Jng kung <uanhF / 8@n :;nh '4a h.t :eoF ,#t 0- "#t liu
h.t :eoF "! ,#t 0- "#t 'h2t 8ao <uanh.
v /!ng hqnF ,-t Dol l! hu6Nn &hb _.ng :eo '4a '@' h.t /Hn t/ong ,-t 'h2t l3ng t/ong
&ha &hKn t@n nh3 Y1Z1UUU n,]. gR "#6F lo' h2& _nn l! lo' :hGng 0@ng :f "! :ho=ng
'@'h ngHnF 'hng h.n nh5 lo' hPt "an _e/ aalD "! 0in t;'h 8N ,atF 'hi &h*i '@'
t5qng t@'. <u@n t;nh &ha &hKn t@n l! nh3 04 0f n( thf hin 'hu6fn 0-ng 8/onF ,-t
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
85' _i 'hu6fn ngnu nhiCn 05%' t/u6Nn 8ei "a 'h., "i '@' &hKn td '4a ,Gi t/5Jng
hu6Nn &hb. Xol '( thf 05%' t$ng h%& 8ei T :W thu#tF &hKn t@n "! ng5ng tp '4a '@' h.t
Gel h(a l! <u@ t/Rnh ,! ,-t Dol 'h=6 to _o 05%' 'hu6fn 0$i th!nh ,-t ,.ng l5i /Hn
hI ,! ,Gi t/5Jng _ung ,Gi 8ao <uanh. V-t lo.i gel l! ,-t gi!u nda /Hn t/ong 'h2t
l3ng. Th#t thP " :hi 'h2t l3ng ,! :hGng 'ho &hL& '@' ,.ng l5i /Hn Dp& 0$F "! '@'
,.ng l5i /Hn :hGng 'ho &hL& 'h2t l3ng 'h=6 /a ngo!i ~1[ if, 8Ht 01u '4a gel h(a
th5Jng 05%' k@' 0nh 8ei ,-t Do gia tEng 0-t ng-t "N 0- nht "! 0@& rng 0!n h)i 07n
Dr' 'Eng. YThe &oint o gelation iD t6&i'all6 i_entiie_ 86 an a8/u&t /iDe in "iD'oDit6
an_ an elaDti' /eD&onDe to Dt/eDD.]. T$ng h%& ae/ogelF Do gel h(a thu#n tin nh2t gK6 /a
thGng <ua ,-t Do tha6 0$i t/ong 0- &H '4a _ung _'h &h=n rng. T/.ng th@i 'q h?' '4a
gel &hp thu-' /2t nhiNu "!o D* l5%ng '@' liCn :7t t/ong ,.ng. v /!ng l! ln hqn '@'
,r' 0- liCn :7t ngangF 'rng hqn '2u t/P' 05%' hRnh th!nh.
T.T. H(a h?' '4a <u@ t/Rnh XolZGel
C( ,-t D* thGng D* =nh h5eng 07n &h=n rng th46 &hKn "! ng5ng tp Y<u@ t/Rnh
XolZGel]F 8ao g), ho.t h(a '4a al:oki_e :i, lo.iF t> l n5'al:oki_eF &H _ung _'hF
nhit 0-F 8=n 'h2t '4a 'h2t tanF "! 'h2t thC, "!o. V-t <uan tK, :h@' nQa l! 'h2t kP'
t@' th5Jng 05%' thC, "!o 0f :if, Do@t th!nh &h1n "! ,r' 0- '4a th46 &hKn "!
ng5ng tp . x9ng '@'h tha6 0$i nhQng thGng D* <u@ t/Rnh n!6F "#t liu "i nhQng "i '2u
t/P' :h@' nhau "! 8N ,at h(a h?' '( thf thu 05%'. gi' kd l ti7& nQa l! DolF '( thf
t$ng h%& 05%' nhQng "#t liu 'e/a,i' e nhQng _.ng :h@' nhau. AhQng t2, &hi,
,3ng '( thf 05%' D=n ku2t t/Cn 'h2t nNn 89ng &h5qng &h@& D&in 'oating "! _i&Z
'oating. Khi ,! Dol 05%' 'aDt "!o :huGnF gel 5t D` hRnh th!nh. gi "i' l!, :hG "!
gia nhit ti7& theo 0(F gel D` 05%' 'hu6fn h(a th!nh 'e/a,i' 0a' hoa' l! '@' h.t th46
tinh. A7u 'h2t l3ng t/ong gel 5t 05%' lo.i 83 _5i 0iNu :in DiCu ti h.nF ,-t "#t liu
'o' : k*& "! ,#t 0- 'o' : th2& g?i l! ae/ogel thu 05%'. x9ng 'hrng '4a th46 &hKn
Dili'ate "! ng5ng tp 0f hRnh th!nh &ol6Dili'ate gel "! &hKn td 05%' th26 t/ong nhiNu h
thiCn nhiCn nh5 o&alD "! agateD. Al:oki_e :i, lo.i 01u tiCn 05%' t$ng h%& t+ XiCl
y
"!
al'ohol 8ei j8el,anF ng5Ji 0^ tR, /a h%& 'h2t gel l.i _5i @& Du2t :h; <u6fn "! XiZ
YOC
T
H
\
]
y
'( thf 05%' ke, nh5 l! t$ tiCn 'ho "#t liu th46 tinh.
2.8. T9:% c;5 c<= >41 5*6% ?+,2G),.
TiNn 'h2t l! nhQng "#t liu 01u tiCn 'ho <u@ t/Rnh DolZgel.
1. C@' tiNn 'h2t '( thf hBa tan 05%' t/ong ,Gi t/5Jng &h=n rng.
T. ChPng &h=i 04 nEng 0-ng 0f tha, gia "!o <u@ t/Rnh hRnh th!nh gel.
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
V-t D* ,u*iF oki_eF h6_/oki_eDF 'o,&lekeDF al:oki_eDF a'6lateDF "! a,ineD
05%' Dd _png nh5 tiNn 'h2t n7u hBa tan 05%' t/ong _ung ,Gi th;'h h%&. Al:oki_e l!
nhQng tiNn 'h2t DolZgel thGng _png nh2t F 8ei "R 'hPng lP' n!o 'Mng '( Dn. x/a_le6
"! nhQng '-ng Do 0^ gi=i th;'h h(a t;nh 'q 8=n '4a tiNn 'h2t. Ah2t l! 0f _o 0o@n lo.i
tiNn 'h2t 0f Dd _png 'ho ,p' 0;'h 'p thf. - &h=n rng '4a tiNn 'h2t :hGng 'h> &hp
thu-' "!o '2u t/P' h(a h?' ,! 'Bn &hp thu-' "!o 0iNu :in &h=n rng. Xo D@nh "i tiNn
'h2t '4a nhQng 'h2t :h@'F nEng l5%ng t.o th!nh ,.ng '4a Xi thR 'ao 0f t.o th!nh ,-t
_.ng gel. ( l! t.i Dao nhQng tiNn 'h2t al:oki_e 0Ht tiNn :h@' '( thf 05%' tha6 th7 8ei
nhQng tiNn 'h2t :h@' / hqn nh5 l! Dili'on al:oki_e YTjOXF TVOX] "! nhQng tiNn
'h2t '( thf tan t/ong n5' nh5 Aa
T
XiO
h
'ho <u@ t/Rnh DolZgel.
Ae/ogelD : n5' 05%' thu t+ tiNn 'h2t ,! :hGng '( Do 0iNu 'h>nh "N &h5qng
_in h(a h?' 05%' g?i l! tiNn 'h2t h6_/o&ho8i' Y: n5']F "! 0*i "i h6_/o&hili' Y5a
n5'] thR g?i l! tiNn 'h2t h6_/o&hili' nh5 8=ng 1.
2.@. C0 cA (B% C%&#
T.y.1. *i "i Xili'on Al:oki_e.
Dili'a gel 05%' t$ng h%& 89ng '@'h th46 &hKn tiNn 'h2t ,ono,e/ tet/a hoa' t/i Dili'on
al:oki_e 89ng akit "G 'q Y HClF C
T
O
y
H
y
] hoa' 8auo Y AH
h
F AH
y
OH] nh5 l! ,-t 'h2t
kP' t@'. C@' &h=n rng Dol gel k=6 /a t/ong Do hRnh th!nh ,.ng l5i Dili'a ~T\FT
Xo th46 &hKn:
Xo ng5ng tp:
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
T.y.T. A5' hBa tan Dili'a "! :ho@ng D=n: Yate/ Xolu8le Xili'ateD an_
Vine/alD].
Aat/i Dili'at YAa
T
XiO
h
] 0^F 0ang "! '( thf D` luGn luGn thf l! ngu)n "#t liu "i gi@ /
nh2t '4a akit Diliki' t5qng 0*i tinh :hi7t ,! t+ 0( Dili'a gel '( thf 05%' t$ng h%&.
Xili'at nat/i &h=n rng "i n5' 0f 'ung '2& akit Diliki' "! Dau 0( l! akit Diliki'
&ol6,e/iueD "! t.o Dili'a gel nh5 t/ong '@' &h=n rng Dau 0K6:
C@' akit Diliki' ng5ng tp 0f t.o th!nh '@' h.t Dili'a nh3F '@' 'huci "! _o 0( t.o th!nh
,-t ,.ng l5i _nn 07n l5%ng Dili' 0iokit gel nh5 hRnh _5i 0K6.
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
Hqn nQaF '( ,-t D* 8@o '@o '( Dn "N t$ng h%& Dili'a gel Dd _png nhG,F 'anki Dili'atF
olleDtoniteF "! "" ~T[ZTS.
A( l! 0iNu hifn nhiCn t+ '@' &h=n rng YT] Z Y\] /9ng '2u t/P' '4a DolZgel th46 tinh &h@t
t/ifn liCn tp' l! D=n &hO, '4a :7 ti7& &h=n rng th46 &hKn "! ng5ng tp Y"! ng5%' l.i
&h=n rngF tr' l!F eDte h(a "! ')n hoa' th46 &hKn Z:hd t/bng h%&] ~1\. gR "#6F :i7n
thr' "N 'q 'h7 "! 0-ng h?' '4a '@' &h=n rng n!6 D` 'ung '2& '@i nhRn DKu DH' "N gel
"! gel '( ngu)n g*' t+ th46 tinh.
mh=n rng th46 &hKn 05%' kP' t@' 8ei "i' 8$ Dung ,-t akit hoa' ,-t 8auo ~TS.
T/ong tho' t7 _.ng 'u*i 'bng '4a th46 &hKn Dili'a &hp thu-' "!o &H '4a _ung _'h.
,r' 0- &H th2& Y'( t;nh akit 'ao]F '@' h.t Dili'a '( ku h5ng t.o th!nh ,-t 'huci
thng "i ,#t 0- liCn :7t ngang th2&. iNu n!6 _nn 07n ,-t gel ,N,F 0( l! 0=o ng5%'
"! '( thf 05%' &hKn t@n l.i t/ong _ung _'h. Ah5 gi@ t/ &H tEng lCnF D* l5%ng <ua '@'
liCn :7t giQa '@' &ol6,e/ '@' 'huci 'Mng tEng. &H 'ao Y/2t 8auo]F '@' &ol6,e/ t/e
nCn &hKn nh@nh nhiNu "! D* l5%ng liCn :7t ngang tEng lCn. 0- &H th2&F th46 &hKn
k=6 /a 8ei Do t2n 'Gng lo' 0in td "!o '@' ngu6Cn td ok6 '4a nh(, al:okitF t/ong :hi
0( e &H 'ao F th46 &hKn "! t/bng h%& k=6 /a 8ei @i nhKn t2n 'Gng "!o ion Xi YXiy ].
Agu6Cn tdF ionF hoa' nh(, ,! '( @i lo' ,.nh ,` 0*i "i '@' 0in td 05%' g?i l! '@'
ionF t/ong :hi '@' ion _5qng 05%' g?i l! nu'leo&hileD. A(i 'hungF t2t '= '@' ion l! '@'
t@' nhKn ok6 h(a "! t2t '= nu'leo&hileD l! 'h2t :hd.
}u@ t/Rnh gel h(a "i '@' nh(, nh3 hqn hBa tan "! t@i :7t t4a "!o '@' 'huci ln hqn
0f '@' &hKn td nh3 hqn gi=, t/ong D* 0( nh5ng Do hc t/% '4a '@' &hKn td ln hqn 0f
&h@t t/ifn 'ho ti :hi 'hPng t#& h%& th!nh _.ng /a'tan. }u@ t/Rnh n!6 05%' g?i l! Do
'h;n ,u)i YnhM t5qng] ODtal_ ~hU.
T.y.h. xN ,at 5a n5' "! : n5' YH6_/o&hili' an_ H6_/o&ho8i'
Xu/a'eD]:
TCn : n5' zH6_/o&ho8i'{ "! 5a n5' zH6_/o&hili'{ &h@t Dinh t+ Do :7t h%& '4a
ith46 Z h6_/oiF '( ngha l! n5' t/ong ti7ng H6 .&F i&ho8oDi '( ngha l! ighLti
t/ong ti7ng H6 .&F "! i&hili'i '( ngha l! i6Cu th5qngi t/ong ti7ng H6 .&. AhQng
thu#t ngQ ,G t= lo' 0O6 / /t "! lo' hPt giQa n5' "! 8N ,at. Ah5 thf hin t/ong
HRnh 1F 5a n5' ha6 : n5' 05%' &hKn 8it "i '@' gi@ t/ '4a g(' ti7& kP': nh3 hqn
hoa' ln hqn SU .
x=ng 1: C@' tiNn 'h2t 0f t$ng h%& Dili'a ae/ogel
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0
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
Khi nEng l5%ng 8N ,at '4a /Hn l! th2&F n( :hGng th2, n5' t+ 8N ,at '4a n( "!
ng5%' l.iF 'ho th26 Do : n5' hoa' 5a n5'. Hin na6F '@' 8N ,at : n5' 05%' Dd
_png t/ong ng!nh 'Gng nghi& 'ho ,-t lo.t '@' rng _png 8ao g), 'h2t &h4 : n5'
'ho 'h*ng /> DLtF lo.i 83 _1u /a :h3i n5'F <u=n l Do '* t/!n _1uF "! '@' <u@ t/Rnh
t@'h h(a h?' 0f t@'h /iCng '@' h%& 'h2t :hGng &hKn 'o' "! '( 'o'. f t$ng h%& '4a
ae/ogel : n5' "! 5a n5'F hai 85' 'h;nh l! liCn <uan 07n: Ya] t$ng h%& al'ogel
89ng <u@ t/Rnh DolZgel "! Y8] l!, :hG '4a al'ogel 89ng '@' :W thu#t :h@' nhau.
T.y.y. !, :hG ae/ogel YI/6ing o Al'ogel]:
Xau :hi hRnh th!nh gel 89ng '@'h th46 &hKn "! &h=n rng ng5ng tpF ,-t ,.ng l5i XiZ
OZXi 05%' hRnh th!nh. Xo l^o h(a l! thu#t ngQ 'h> 0f tEng '5Jng ,.ng l5i gelF n( '(
thf liCn <uan 07n ng5ng tp thC,F hBa tanF t@i :7t t4a '4a h.t DolF 'hu6fn &ha t/ong 'h2t
/Hn hoa' &ha l3ng. iNu n!6 _nn 07n ,-t 'h2t /Hn k*& t/ong 0( _ung ,Gi 8 ,H' :st.
}u@ t/Rnh lo.i 83 &h1n ln _ung ,Gi t+ gel Y,! t/ong t/5Jng h%& '4a ,-t al:okit '(
ngu)n g*' t+ gel 'h4 67u l! ')n "! n5'] 05%' g?i l! D26 :hG. T/ong <u@ t/Rnh D26
:hGF nrt ,.ng gel k=6 /a _o lo' ,ao _nn 05%' hRnh th!nh t/ong '@' lc /cng t*t 8ei
,at &hKn '@'h '4a hqi n5'. mh5qng t/Rnh a&la'e 05%' @& _png t/ong t/5Jng h%&
n!6F :hi 8@n :;nh ,ao <u=n '!ng nh3F 'h2t l3ng D` _Kng lCn 'ao hqn F hoa' @& Du2t
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11
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
th46 tnh D` 'ao hqn. "R "#6 nEng l5%ng 8N ,at 'hu t/@'h nhi, 'ho Do gia tEng '4a
'-t 'h2t l3ng t/ong ,-t ,ao <u=nF 0- ln '4a @& Du2t ,at &hKn '@'h t/ong ,-t ,ao
,.'h '( thf 05%' t;nh 89ng '@'h 'Kn 89ng '@' lo' tnh l!F
5Jng :;nh '4a '@' lc /cng t/ong gel l! n,F 0f ,! '@' 'h2t l3ng gel &h=i t@' _png @&
lo' th46 tnh 'ao. C@' ,at :hu, t/ong '@' lc /cng "! '@' Dr' 'Eng 8N ,at '* gHng 0f
:Lo '@' h.t "i nhau :hi 'h2t l3ng t/ong '@' lc /cng 8*' hqi. C@' lo' l5%ng n!6 '( thf
ho.t 0-ng t/ong ,-t '@'h ,! 'hPng '* gHng 0f 0(ng t#& h%& lc /cngF Dau 0( l! '2u
t/P'. Ah5 "#6F gel "i '@' lc /2t t*t '( ku h5ng nrt g^6 "! thu nh3 t/ong <u@ t/Rnh
D26. f t/@nh rng Du2t D26 :hG n!6 KiDtle/ ,G t= <u@ t/Rnh t$ng h%& 01u tiCn '4a ,-t
ae/ogel 8ei D26 :hG DiCu ti h.n t/ong 01u nhQng nE, 1ShU ~h1F "! '@' <u@ t/Rnh t$ng
h%& ae/ogel :h@' nhau 0^ 05%' 8@o '@o t+ 0(.
T/ong nhQng nE, 1S[UF Dili'a ae/ogel 05%' t$ng h%& 89ng 'a'1'h D26 :hG DiCu ti
h.n e nhit 0- 'ao '4a ,-t lo.i gel 5t 05%' t$ng h%& t+ <u@ t/Rnh th46 &hKn TVOX
t/ong ,ethanol ~hT. t/ong nhQng nE, 1SUF '@' nh! nghiCn 'ru 0^ 0.t 05%' ,-t hifu
8i7t ,i "N tiN, nEng '4a ae/ogelF "! Dili'a _oa t/Cn TeoDF t$ng h%& ;t t*n :L, "! ;t
0-' h.i hqn Do "i TVOX. }u@ t/Rnh D26 DiCu ti h.n nhit 0- th2&F Dd _png CO
T
l3ng
0^ 05%' @& _png.~hh
T.y.\. X26 :hG DiCu ti h.n '4a ae/ogel:
T/ong &h5qng &h@& D26 :hG DiCu ti h.nF gel 05%' D26 :hG e ,-t 0if, ti h.n 0f lo.i
83 '@' lo' ,ao _nnF nh5 ,G t= _5i 0K6. Aga6 Dau :hi 'h2t l3ng 8Ht 01u 8*' hqi :h3i
gelF Dr' 'Eng 8N ,at t.o /a ,at :hu, l, t/ong '@' lc /cng '4a gel. Khi Do 8a6 hqi
'4a 'h2t l3ng ti7& tp'F lo' nLn hRnh th!nh kung <uanh 'hu "i '4a lc /cng "! n( 'o /Pt
l.i Cu*i 'bngF Dr' 'Eng 8N ,at gK6 /a Do Dp& 0$ '4a thKn gel ~hy. f ngEn 'han Dr'
'Eng 8N ,at hRnh th!nhF gel 05%' D26 :hG DiCu ti h.n t/ong ,-t n)i h2&F nh5 thf hin
t/ong hRnh T.
Khi nhit 0- "! @& Du2t t/ong n)i h2& 0ang tEng t/Cn ,-t 0if, ti h.n Y'ho nhit 0-
ti h.n ,ethanol "! '@' gi@ t/ @& Du2t ti h.n Tyh C "! [.SVmaF /eD&.]F Ch2t l3ng
05%' 'hu6fn h(a th!nh ,-t 'h2t l3ng iDiCu ti h.niF t/ong 0( ,ci &hKn td '( thf _i
'hu6fn to _o "! Dr' 'Eng 8N ,at 'h2, _rt. A7u :hGng '( Dr' 'Eng 8N ,atF ,at :hu,
:hGng hRnh th!nh. C@' hqi 05%' Dau 0( t+ t+ tho@t /a :h3i n)i h2&F 'ho 07n :hi @& Du2t
t/ong n)i h2& 0.t 07n @& Du2t :h; <u6fn. Cu*i 'bngF n)i h2& 05%' /da 89ng nitq :hG Y
Trang
11
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
h8a/] 0f lo.i 83 '@' &hKn td _ung ,Gi 8 ,H' :st t+ gel :hG. mh5qng &h@& D26 :hG '4a
al'ogelD 05%' g?i l! iD26 :hG DiCu ti h.ni. HRnh h 'ho th26 'hu : nhit 0- @& Du2t
Dau :hi D26 DiCu ti h.n '4a al'ogelD.
T.y.. VGi t/5Jng @& Du2t X26 :hG "! Tha6 0$i 8N ,at h(a h?'.
Theo t/u6Nn th*ngF Dili'a ae/ogel 0^ 05%' t$ng h%& 89ng '@'h Dd _png &h5qng &h@&
D26 DiCu ti h.nF nh5ng 0iNu n!6 '( ,-t D* h.n 'h7 "N hiu <u= 'hi &h; '4a n(F <u@
t/Rnh liCn tp'F "! an to!n 8ei "R nhit 0- 'ao "! @& Du2t '1n thi7t 0f ti7& '#n '@' 0if,
<uan t/?ng. A7u 'a/8on _ioki_e l3ng 05%' Dd _png nh5 ,-t _ung ,Gi e nhit 0- th2&
'4a <u@ t/Rnh D26 DiCu ti h.nF 0- 8Nn h(a h?' '4a ae/ogel t/ong 81u :h; <u6fn D` 8
gi=, _1nF "R '@' h.t ae/ogel l! 5a n5'. f :hH' &hp' nhQng "2n 0N n!6F x/in:e/ gii
thiu ,-t &h5qng &h@& D26 @& Du2t th5Jng h2& _nn "N ,at th5qng ,.i 0f D=n ku2t
Dili'a ae/ogel ~h\. T/ong <u@ t/Rnh n!6F 8N ,at '4a gel 5t 05%' 8i7n 0$i h(a h?'
89ng '@'h tha6 th7 '@' nh(, 'hr' : n5' 89ng '@'h tha6 th7 '4a H t+ nh(,
h6_/ok6l 89ng '@'h l!, :hG @& Du2t 8Rnh th5Jng. Ah(, Dilanol 8N ,at YXiZOH] t/Cn
'@' 'p, Dili'a lKn '#n t/=i <ua '@' &h=n rng ng5ng tp _nn 07n 'o /Pt :hGng thf &hp'
h)i '4a ,.ng gel t/ong <u@ t/Rnh D26F nh5 thf hin t/ong hRnh y. }u@ t/Rnh n!6 '( thf
t.o /a '@' 8N ,at "i nEng l5%ng 'o' th2&F l!, gi=, 0@ng :f Dr' 'Eng 8N ,at. gR "#6F
n( l! '1n thi7t 0f tha6 0$i 8N ,at al'ogel "i '@' 0.i l Dda 0$i th;'h h%&F _o 0( 8N
,at '4a ae/ogel 05%' t/= l.i : n5'.
C( ,-t D* 'h2t '( :h= nEng l!, tha6 0$i '@' t;nh 'h2t l!, O, '4a 8N ,atF '( ngha l!F
thu*' thd : n5'. ChPng 8ao g), ,eth6lt/i,ethok6Dilane YVTVX]F heka,eth6l
_iDilauane YHVI]F _i,eth6l'hlo/oDilane YIVCD]F _i,eth6l_i'hlo/oDilane YIVIC]F
t/i,eth6l'hlo/oDilane YTVCX]F t/i,eth6lethok6Dilane Yt,eD]F "!
heka_e'6lt/i,ethok6Dilane YHITVX]. Xda 0$i 8N ,at '4a gel <ua Do tha6 th7 '4a H
t+ XiZOH 8ei nh(, :hGng &hKn 'o' o/a/6l al:6l l! ,-t 85' <uan t/?ng t/ong
&h5qng &h@& D26 @& Du2t th5Jng. AgEn 'han '@' &h=n rng ng5ng tp '4a 'p, Dili'aF "!
n(i /-ng /aF ngEn ng+a 'o /Pt '4a gel t/ong <u@ t/Rnh D26. T+ D26 :hG @& Du2t 8Rnh
th5Jng '( thf l!, gi=, 'hi &h; D=n ku2t '4a '@' ae/ogelF t1, <uan t/?ng '4a n( '(
tha6 0$i t+ ,-t :hu "o' <uan tK, :hoa h?' thu1n tP6 t/ong ,-t t/ong Dd _png tho' t7.
T.y.[. (ng 8Eng :hG:
V-t :h= nEng :h@' 0f t/@nh /anh gii &ha giQa 'h2t l3ng "! &ha :h; t/ong <u@ t/Rnh
D26 D26 :hG l! 0(ng 8Eng :hG. Ch2t l3ng t/ong lc /cng 8 0(ng 8Eng "! Dau 0( thEng
hoa t/ong 'hKn :hGng. ^ '( ,-t D* nc lo' 0f Dd _png &h5qng &h@& n!6 0f D=n ku2t
ae/ogel ~hZh. Tu6 nhiCnF giai 0o.n gi! h(a &h=i 05%' ,e /-ng 0f $n 0nh ,.ng
l5i gelF _ung ,Gi 05%' tha6 th7 8ei ,-t _ung ,Gi :h@' "i ,-t h D* gi^n ne th2&
"! @& Du2t 'ao thEng hoaF "! nhit 0- 0(ng 8Eng th2& l! 0.t 05%' 89ng '@'h thC,
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
,u*i. V-t nh5%' 0if, nQa l! ,.ng '( thf 8 &h@ h46 8ei Do :7t tinh '4a _ung ,Gi
t/ong '@' lc /cng. C/6ogelD _o 0( 'h> thu 05%' nh5 8-t.
Trang
13
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
8. D%& EF%&#
Ae/ogel '( t;nh 'h2t 0-' 0@o ,! 'hPng h2& _nn gii :hoa h?' "! 'Gng ngh
Ta8le : T)2ical 2ro2erties o3 silica aerogels.
m/o&e/t6 galue
T> t/?ng U.UhU.h\ g',
h
Iin t;'h 8N ,at UU1UUU ,
T
g
| Doli_D U.1h
5Jng :;nh lc k*&1\|
TU n,
5Jng :;nh h.t T\ n,
Chi7t Du2t 1.U1.U
H D* gi=n n nhit T . U Z y . U 1 U
H9ng D* 0in ,Gi 1.1
g#n t*' K, thanh t/u6Nn <ua 1UU ,D
Trang
1-
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
Io '@' t;nh 'h2t 0-' 0@oF 05%' Dd _png 'ho nhQng rng _png :h@' nhau 05%' t/Rnh
8!6 t/ong 8=ng Dau:
Ta8le : A&&li'ationD o the ae/ogel &e/D&e'ti"e to &/o&e/tieD.
m/o&e/t6 Thu-' t;nh A&&li'ation
- _nn nhit Yi] C@'h 0in t*t
Yi] !, 'h2t '@'h nhit t/ong kK6 _ong "! thi7t
8
Yii] T/ong Du*t Yii] 5u t/Q 'Gng ngh &hi, =nh
Yiii] Chu 05%' nhit 0-
'ao
Yiii] e G tGF thi7t 8 :hGng gian
Yi"] T/?ng l5%ng nhs Yi"] Ibng l!, thi7t 8 t/ong &in ,at t/Ji
V#t 0- -
k*&
Yi] vHn t$ng h%& nhs
nh2t
Yi] P' t@'
Yii] Iin t;'h 8N ,at ln Yii] C=, n
Yiii] Vulti&le
'o,&oDitionD
Yiii] 5u t/Q nhiCn liu
Yi"] T/ao 0$i ion
Y"] ?' 'h2t :h; G nhif,
Y"i] Agu6Cn liu 'ho &h=n rng t$ng h%&
Y"ii] Ch2t ,ang t/ong t.o ,!u
Y"iii] Te,&late
O&ti'al Yi] T/anD&a/ent Yi] ight eight o&ti'D
Yii] o /e/a'ti"e in_ek Yii] Che/en:o" _ete'to/D
Yiii] Vulti&le
'o,&oDition
Yiii] ight gui_eD
A'ouDti' Yi] o D&ee_ o Doun_ Yi] Xoun_ &/oo /oo,D
Yii] A'ouDti' i,&e_an'e ,at'hing in ult/aDoni'
_iDtan'e DenDo/D
Ve'hani'al Yi] jlaDti' Yi] jne/g6 a8Do/8e/
Yii] ight eight Yii] H6&e/"elo'it6 &a/ti'le t/a&
jle't/i'al
Yi] oeDt _iele't/i'
'onDtant
Yi] Iiele't/i'D o/ 'D
Yii] High _iele't/i'
Dt/ength
Yii] X&a'e/D o/ "a'uu, ele't/o_eD
Yiii] High Du/a'e a/ea Yiii] Ca&a'ito/D
h.1. Ae/ogel t/ong t$ng h%&:
Trang
15
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
T@' nhKn ae/ogel 05%' Dd _png l! Dili'on al:oki_e :7t h%& "i '@' okit
:i, lo.i. V-t D* nghiC, 'ru ,i t$ng h%& /a '@' Dili'a ae/ogel "i nhiNu rng _png
:h@' nhau. C2u t/P' "! thu-' t;nh '4a Dili'aZae/ogel ion okit 05%' l!, e :;'h th5'
nano 05%' nghiCn 'ru 8ei 'alaD "! '-ng Do. HRnh \ 'ho th26 1 Dili'aZae/ogel 05%'
t$ng h%& 89ng '@'h l!, :hG 8ei @& Du2t kung <uanh. AhQng nghiCn 'ru nh5 th7 n!6
'ho /a '@' "#t liu :h@' nhau nh5 D6ntheDiD o Dili'aZtitaniaF Dili'aZ'a/8onF Dili'a an_
alu,ina ,i'/oi8e/DF ha6 a'ti"ate_ 'a/8on &o_e/ 'o,&oDite ae/ogelD.
h.T. Ae/ogel 05%' Dd _png nh5 'h2t th2, hPt
T$ng h%& Gel : n5' 0f h2& thp '@' _ung ,Gi hQu 'q "! '@' lo.i _1u 05%' nghiCn
'ru 8ei A. gen:ateDha/a vao "! '@' '-ng Do. H? nghiCn 'ru Do h2& thp "! gi=i h2&
'4a ae/ogel Dili'a DiCu : n5' 0f h2& thu 11 _ung ,Gi hQu 'q "! h lo.i _1u. HRnh
_5i n!6 'ho th26 Do h2& thp "! gi=i h2& 'h2t hQu 'q :h@' nhau:

Trang
1!
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
T/5' h2& thp Aga6 l#& tr' :hi
8Ht 01u h2& thp
tU
TTU &hPt TyU &hPt T Dau
gi=i h2&
3.3. Ae/ogel aD a XenDo/
Ae/ogel '( lc k*& lnF :h= nEng ti7& kP' lnF :h= nEng ho.t 0-ng 8N ,at 'ao. Cho nCn
05%' Dd _png l!, '=, 8i7n. V-t nghiCn 'ru '4a ang "! '@' '-ng Do t/Cn h.t Dili'a
ae/ogel ,!ng ,3ng 'ho th26 0in t/e 'hPng gi=, :hi 0- O, tEng. xN ,at ae/ogel
,o_iie_ ;t 8 =nh h5eng 8ei 0- O, hqn Do "i ae/ogel 5a n5' "! '( thf 05%' Dd
_png 'h*ng En ,BnF t@' nhKn : n5' nh5 hRnh ":
h.y. Ae/ogel l! "#t liu t/ong "i ,.'h 0in t/e _o h9ng D* 0in ,Gi th2&.
Xili'a ae/ogel ,!ng ,3ng 05%' rng _png /-ng /^i t/ong '@' "i ,.'h
0in td _o t;nh 'h2t /2t 0a' 8it '4a 'hPng _o h9ng D* 0in ,Gi 'o' th2&F 0- k*& 'aoF
$n 0nh nhit 'ao.
Trang
1.
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
h.\. Ae/ogel l! 'h2t kP' t@'
Io _in t;'h 8N ,at ln _nn 07n nhiNu rng _png nh5 h2& thp h(a 'h2t
t/ong <u@ t/Rnh 'h=6 t/!n. T;nh nEng n!6 n( '( tiN, nEng l! 'h2t kP' t@'
hoa' ngu6Cn liu 'ho 'h2t kP' t@'. Ae/ogel hc t/% t/ong kP' t@' hcn t.& :hi
'@' &h=n rng l! l3ng ha6 :h;. ChPng 05%' 0a' t/5ng 8ei _in t;'h 8N ,at
th#t 'ao t/ong ,-t 0qn " :h*i l5%ngF 0- k*& 'ao l!, 'ho 'hPng /2t '( gi@
t/ t/ong kP' t@'. V-t D* kP' t@' Ae/ogel 05%' lit :C _5i 0K6:
Z T$ng h%& nit/il t+ hi_/o'a/8on Dd _png AO
Z Do8uten '( thf 'hu6fn 0$i th!nh ,etha'/6lonit/ile
Z T$ng h%& ,etanol t+ CO
h.. Ae/ogel t/ong "i' l5u t/Q ,e_ia
Io _in t;'h 8N ,at "! 0- k*& 'ao nCn '( thf l!, 8- l?' :h;F hPt O, t/ong
'@' &hi, =nh "! l5u t/d nhiCn liu hi_/o. Ae/ogel 'Bn 05%' 8i7t 07n l! DiCu
tp 0in '( t/e :h@ng /2t th2& hqn Do "i '@' DiCu tp 0in thGng th5Jng.
h.[. Ae/ogel 05%' Dd _png l! t7 8!o t/ong '@' t2, &hi, nEng l5%ng ,at t/Ji
h.. Ae/ogel l! "#t liu '@'h nhit
Io 0- k*& 'aoF 8Cn t/ong /cng 'ho nCn nhJ 0a' t;nh n!6 ,! :h= nEng
'@'h nhit '4a Ae/ogel l! 'o' t*t.
h.S. T/ong nh!F t4 l.nhF 'da D$ "! 'da D$ t1ng nh!.
h.1U. }u1n @o t/ang &hp' "! 'hEn
h.11. T/ong :hGng gian 05%' AaDa _bng l!, :;nh 'h*ng 8pi "! nhit
@. THAM KHGO
1. . . H/u8eDhF zAe/ogelD: the o/l_D lighteDt Doli_DF{ Che,iDt/6 an_ n_uDt/6F
no. TyF &&. TyT[F 1SSU. gie at X'o&uD
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
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oki_eD. ma/t h: /ea'tion o iDo&/o&anol o"e/ "ana_iaZtitania 'atal6DtDF{ A&&lie_
Catal6DiDF "ol. hhF no. 1F &&. T1SThUF 1S[.gie at X'o&uD
3. l. /i':e an_ A. j,,e/lingF zAe/ogelDF &/e&a/ationF &/o&e/tieDF a&&li'ationDF{
in Xt/u'tu/e an_ xon_ing [[: Che,iDt/6F X&e't/oD'o&6 an_ A&&li'ationD o XolZGel
GlaDDeDF &&. h[[F X&/inge/F xe/linF Ge/,an6F 1SST.
-. C. A. V. Vul_e/ an_ l. G. gan ie/o&F zm/e&a/ationF _enDii'ation an_
'ha/a'te/iuation o auto'la"e _/ie_ XiOT gelDF{ in Ae/ogelDF l. /i':eF j_.F &&. [\F
X&/inge/F xe/linF Ge/,an6F 1S.
5. . uF G. HuangF an_ . HeF zXolZgel &/e&a/ation
o xahkX,TkTi1O\y ,i'/oa"e _iele't/i' 'e/a,i'DF{ Ce/a,i'D nte/nationalF
"ol. h1F no. 1F &&. T1T\F TUU\. gie at mu8liDhe/ gie at Google X'hola/ gie at
X'o&uD
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,eDo&o/ouD titaniaZalu,ina 'e/a,i' 86 ,o_iie_ DolZgel ,etho_F{ lou/nal o AonZ
C/6Dtalline Xoli_DF "ol. h\UF &&. T[1T[F TUUy. gie at mu8liDhe/ gie at Google
X'hola/ gie at X'o&uD
.. v. lainF g. Gu&taF A. VanDinghF an_ K. X/eeni"aDF ze//oele't/i' an_
&ieuoele't/i' &/o&e/tieD o nonZDtoi'hio,et/i' X/1kxiTTkhTaTOS 'e/a,i'D
&/e&a/e_ /o, DolZgel _e/i"e_ &o_e/DF{Vate/ialD X'ien'e an_ jnginee/ing xF "ol.
11TF no. 1F &&. \y\F TUUy. gie at mu8liDhe/ gie at Google X'hola/ gie at
X'o&uD
/. K. iF l.ZH. iF an_ H. . . ChanF za8/i'ation o X,Z an_ VnZ_o&e_ lea_
titanate 'e/a,i' &o_e/ an_ 'e/a,i'D 86 DolZgel ,etho_DF{ Vate/ialD Che,iDt/6 an_
mh6Di'DF "ol. F no. 1F &&. h[F TUUy. gie at mu8liDhe/ gie at Google
X'hola/ gie at X'o&uD
0. m. jD'/i8anoF V. Va/'halF V. uiDa Xanu@nF m. AlonDoZGutiL//euF x. luli@nF
an_ j. Co/_on'illoF zoZte,&e/atu/e D6ntheDiD o X/AlTOy 86 a ,o_iie_ DolZgel
/oute: vI an_ va,an 'ha/a'te/iuationF{ lou/nal o Xoli_ Xtate Che,iDt/6F "ol. 1[F
no. F &&. 1S[1S[F TUU\. gie at mu8liDhe/ gie at Google X'hola/ gie at
X'o&uD
11. m. A. X. lo/geF m. Cal_aDF C. C. voDaF A. G. Oli"aF an_ l. . XantoDF zO&ti'al
i8e/ &/o8eD o/ luo/eD'en'e 8aDe_ ok6gen DenDingF{ XenDo/D an_ A'tuato/D xF "ol.
1UhF no. 1ZTF &&. TSUTSSF TUUy.gie at mu8liDhe/ gie at Google X'hola/ gie at
X'o&uD
11. H. VatDu_aF A. Ko8a6aDhiF T. Ko8a6aDhiF K. Vi6auaaF an_ V. Kua8a/aF
zvoo,Zte,&e/atu/e D6ntheDiD o '/6Dtalline 8a/iu, titanate thin il,D 86 highZ
'on'ent/ation DolZgel ,etho_F{ lou/nal o AonZC/6Dtalline Xoli_DF "ol. T[1F no. 1F &&.
1T1F TUUU. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
12. I. To/i:aiF C. K. Xuuu:iF H. Xhi,iuuF T. Dhiuu:aF l. agiF K. O/iiF an_ T.
Vi6a:aaF zCo,&a/iDon o highZ&u/it6 HTOT an_ mGOT la,eZuDe_ Dili'a glaDDeD
/o, DolZgel Dili'a &o_e/F{ lou/nal o AonZC/6Dtalline Xoli_DF "ol. 1[SF &&. hThhyF
1SSy. gie at X'o&uD
13. H. C. Ha,:e/F zA gene/al theo/6 o l6o&ho8i' 'olloi_D F{ lou/nal o vo6al
Aethe/lan_D Che,i'al Xo'iet6F "ol. \\F &. 1U1\F 1Sh.
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
1-. l. 6:le,aF X. e"ineF an_ X. e"ineF zGene/al _iD'uDDionF{ IiD'uDDionD o the
a/a_a6 Xo'iet6F "ol. \TF &&. h1ThThF 1S[1. gie at mu8liDhe/ gie at Google
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15. . X'huthF K. X. . XingF an_ l. eit:a,&F Han_8oo: o mo/ouD Xoli_DF "ol. hF
ile6ZgCHF einhei,F Ge/,an6F TUUT.
1!. m. l. lo/6F m/in'i&al o mol6,e/ Che,iDt/6F 'ha&te/ yF Co/nell Uni"e/Dit6
m/eDDF tha'aF AF UXAF 1S\h.
1.. C. l. x/in:e/F zH6_/ol6DiD an_ 'on_enDation o Dili'ateD: ee'tD on
Dt/u'tu/eF{ lou/nal o AonZC/6Dtalline Xoli_DF "ol. 1UUF no. 1hF &&. h1\UF
1S. gie at X'o&uD
1/. j. T:al'e'F v. AaDDF l. X'h,au'hF H. X'h,i_tF X. Ku/ai'aF A. xeua:F an_ H.
"an:o"i'F zC/6Dtalliuation :ineti'D o ,ullite /o, DingleZ&haDe gel _ete/,ine_ 86
iDothe/,al _ie/ential D'anning 'alo/i,et/6F{ lou/nal o AonZC/6Dtalline Xoli_DF "ol.
TThF no. 1ZTF &&. \[[TF 1SS. gie at X'o&uD
10. A. C. mie//e an_ G. V. maon:F zChe,iDt/6 o ae/ogelD an_ thei/
a&&li'ationDF{ Che,i'al ve"ieDF "ol. 1UTF no. 11F &&. yTyhyTF TUUT. gie at
mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
21. l. i"ageF mh. xa/8oukF j. T/oni'F an_ l. m. loli"etF X'ien'e o Ce/a,i'
m/o'eDDingF H. Hen'h an_ I. Ul/i'hF j_D.F iel6F Ae o/:F AF UXAF 1S.
21. . C. aCou/De an_ X. Ki,F zXolZgel &/o'eDDeD o/ i8e/D an_ il,D o
,ulti'o,&onent ,ate/ialDF{X'ien'e o Ce/a,i' m/o'eDDingF "ol. F no. SZ1UF &&. 11T
11hyF 1S[.
22. I. C. x/a_le6F v. C. Veh/ot/aF an_ I. m. Gau/F Vetal Al:oki_eDF A'a_e,i'
m/eDDF Ae o/:F AF UXAF 1S[.
23. H. X'h,i_tF zChe,iDt/6 o ,ate/ial &/e&a/ation 86 DolZgel &/o'eDDF{ lou/nal o
AonZC/6Dtalline Xoli_DF "ol. 1UUF &&. \1yF 1S.
2-. . I. O"'ha/ena:oF . . Ta/aDe"i'hF et al.F Kolloi_n6 hu/nalF "ol. hyF &. y1TF
1S[T.
25. C. l. x/in:e/ an_ G. . X'he/e/F XolZGel X'ien'e: The mh6Di'D an_ Che,iDt/6
o XolZGel m/o'eDDingF A'a_e,i' m/eDDF Xan IiegoF CaliF UXAF 1SSU.
2!. l. . Gu/a"F I. . Aa_a/giF an_ A. g. vaoF zje't o ,ike_ Catal6DtD D6Dte,
on TjOXZ8aDe_ Dili'a ae/ogelD _/ie_ at a,8ient &/eDDu/eF{ A&&lie_ Xu/a'e X'ien'eF
"ol. T\\F no. \F &&. hU1ShUT[F TUU.gie at mu8liDhe/ gie at Google
X'hola/ gie at X'o&uD
2.. j. V. lanigen an_ v. . G/oDeF Xili'eouD A_Do/8ent Vate/ialD An_ m/o'eDD
o/ m/e&a/ing Xa,eF U.X. matent no. hF ySyF [yF 1S[U.
2/. K. l. Vu/ata an_ . G. X'hle'htF The Dignii'an'e o inte/nal Dt/u'tu/e in
gelatiniuing Dili'ate ,ine/alDF U.X. Geologi'al Xu/"e6 xulletinF "ol. S\UF no. T\hhF
&&. h\TF 1Sy.
20. V. G. go/an:o"F g. m. VileDh:e"i'hF an_ . A. uuhele"D:iF The Xilokane
xon_F ConDultant xu/eauF Ae o/:F AF UXAF 1S[.
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,ate/ialDF{ mh6Di'al Che,iDt/6F "ol. TTF &&. TShhUF 1S[.
31. X. X. KiDtle/F zCohe/ent ek&an_e_ ae/ogelDF{ lou/nal o mh6Di'al Che,iDt/6F
"ol. hF no. 1F &&. \TyF 1ShT. gie at X'o&uD
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
32. G. A. Ai'olaon an_ X. l. Tei'hne/F zAe &/e&a/ation &/o'eDD o/ Dili'a ke/ogelD
an_ ae/ogelDF an_ thei/ tektu/al &/o&e/tieDF{ xulletin _e la Xo'iLtL Chi,i<ue _e
/an'eF "ol. \F &&. 1SUU1SUF 1S.
33. m. H. Tea/iF A. l. HuntF an_ K. I. otuDF zA,8ientZte,&e/atu/e
Du&e/'/iti'al _/6ing o t/anD&a/ent Dili'a ae/ogelDF{ Vate/ialD ette/DF "ol. hF no. SZ1UF
&&. hhh[F 1S\. gie at X'o&uD
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Dili'a gelF{ lou/nal o AonZC/6Dtalline Xoli_DF "ol. 1F no. hF &&. 1S1TUF
1SS\. gie at X'o&uD
35. C. l. x/in:e/ an_ . X'he/e/F zXolZgel D'ien'eDF{ in The m/o'eDDing an_ the
Che,iDt/6 o XolZGel m/o'eDDingF A'a_e,i' m/eDDF Xan IiegoF CaliF UXAF 1SSU.
3!. x. VathieuF X. xla'he/F v. mi/a/_F l. m. mi/a/_F x. XahouliF an_ . x/oue/DF
z/eeueZ_/ie_ /eDo/'inolZo/,al_eh6_e gelDF{ lou/nal o AonZC/6Dtalline Xoli_DF "ol.
T1TF no. TZhF &&. T\UT1F 1SS[. gie at X'o&uD
3.. I. Kl"anaF l. Chaou:iF V. ve&ellinZa'/oikF an_ G. V. maon:F zA ne
,etho_ o &/e&a/ation o ae/ogelZli:e ,ate/ialD uDing a /eeueZ_/6ing &/o'eDDF{ e
lou/nal _e mh6Di<ue Collo<ueDF "ol. \UF no. CyF &&. CyZTSCyZhTF 1SS. gie at
mu8liDhe/ gie at Google X'hola/
3/. G. V. maon:F zI/6ing ,etho_D &/eDe/"ing the tektu/al &/o&e/tieD o gelDF{ e
lou/nal _e mh6Di<ue Collo<ueDF "ol. \UF no. CyF &&. CyZ1hCyZTTF 1SS.
30. . CaDaDF A. voigF j. vo_/;gueuF j. VolinDF l. Tea_aF an_ l. Xo/tF zXili'a
ae/ogelZi/on oki_e nano'o,&oDiteD: Dt/u'tu/al an_ ,agneti' &/o&e/tieDF{ lou/nal o
AonZC/6Dtalline Xoli_DF "ol. T\F no. 1hF &&. h[yhF TUU1. gie at mu8liDhe/ gie
at Google X'hola/ gie at X'o&uD
-1. . CaDaDF A. voigF j. VolinDF l. V. G/en'heF l. ADenoF an_ l. Tea_aF z/on
oki_e nano&a/ti'leD hoDte_ in Dili'a ae/ogelDF{ A&&lie_ mh6Di'D AF "ol. [yF no. \F &&.
\S1\S[F TUUT. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
-1. m. XhaeDhF X. X,ithaF m. v. A/a"in_F an_ K. G.K. a//ie/F zje't o hZ
gl6'i_ok6&/o&6lt/i,ethok6Dilane &/e'u/Do/ on the &/o&e/tieD o a,8ient &/eDDu/e
_/ie_ Dili'a ae/ogelDF{ lou/nal o XolZGel X'ien'e an_ Te'hnolog6F "ol. \UF no. hF &&.
h\hh\F TUUS. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
-2. K. j. ma/,ente/ an_ . VilDteinF zVe'hani'al &/o&e/tieD o Dili'a
ae/ogelDF{ lou/nal o AonZC/6Dtalline Xoli_DF "ol. TThF no. hF &&. 1[S1SF 1SS. gie
at X'o&uD
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zVi'/o,e'hani'al &/o&e/tieD o 'a/8onZDili'a ae/ogel 'o,&oDiteDF{ A&&lie_ mh6Di'D
AF "ol. [yF no. 1F &&. 11S1TTF TUUT. gie at mu8liDhe/ gie at Google
X'hola/ gie at X'o&uD
--. A. gen:ateDa/a vaoF A. I. Heg_eF an_ H. Hi/aDhi,aF zA8Do/&tion an_
_eDo/&tion o o/gani' li<ui_D in elaDti' Du&e/h6_/o&ho8i' Dili'a ae/ogelDF{ lou/nal o
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mu8liDhe/ gie at Google X'hola/ gie at mu8Ve_ gie at X'o&uD
-5. A. gen:ateDa/a vaoF X. I. xhagatF H. Hi/aDhi,aF an_ G. V. maon:F
zX6ntheDiD o leki8le Dili'a ae/ogelD uDing ,eth6lt/i,ethok6Dilane YVTVX]
&/e'u/Do/F{ lou/nal o Colloi_ an_ nte/a'e X'ien'eF "ol. hUUF no. 1F &&. T[ST\F
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"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
TUU. gie at mu8liDhe/ gie at Google X'hola/ gie at mu8Ve_ gie at
X'o&uD
-!. C.ZT. angF C.Z. uF .ZC. ChenF an_ .ZH. HuangF zHu,i_it6 DenDo/D 8aDe_
on Dili'a nano&a/ti'le ae/ogel thin il,DF{ XenDo/D an_ A'tuato/D xF "ol. 1U[F no. 1F &&.
yUTy1UF TUU\. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
-.. l. . Gu/a"F A. gen:ateDa/a vaoF an_ I. . Aa_a/giF zXtu_6 o the/,al
'on_u'ti"it6 an_ ee't o hu,i_it6 on HVI ,o_iie_ TjOX 8aDe_ ae/ogel _/ie_ at
a,8ient &/eDDu/eF{ lou/nal o XolZGel X'ien'e an_ Te'hnolog6F "ol. \UF no. hF &&.
T[\TUF TUUS. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
-/. . K. iF I.ZK. angF .ZC. ChenF H.Zl. XuF l.ZC. uF an_ . . ChenZangF
zA no"el th/eeZ_i,enDional ae/ogel 8io'hi& o/ ,ole'ula/ /e'ognition o nu'leoti_e
a'i_DF{ A'ta xio,ate/ialiaF "ol. F no. yF &&. 1yT1y[UF TU1U. gie at
mu8liDhe/ gie at Google X'hola/ gie at mu8Ve_
-0. G. X. Ki,F X. H. H6unF an_ H. H. ma/:F zX6ntheDiD o loZ_iele't/i' Dili'a
ae/ogel il,D 86 a,8ient _/6ingF{ lou/nal o the A,e/i'an Ce/a,i' Xo'iet6F "ol. yF
no. TF &&. y\hy\\F TUU1. gie at X'o&uD
51. X.Zx. lungF X.Z. ma/:F l.ZK. angF H.ZH. ma/:F an_ H. Ki,F zA&&li'ation
o XiOT ae/ogel il, o/ inte/la6e/ _iele't/i' on GaAD ith a 8a//ie/ o XihAyF{ Thin
Xoli_ il,DF "ol. yy[ZyyF &&. \U\\F TUUy. gie at mu8liDhe/ gie at Google
X'hola/ gie at X'o&uD
51. X.Z. ma/:F X.Zx. lungF V.ZG. KangF H.ZH. ma/:F an_ H.ZC. Ki,F zVo_ii'ation
o GaAD an_ 'o&&e/ Du/a'e 86 the o/,ation o XiOT ae/ogel il, aD an inte/la6e/
_iele't/i'F{ A&&lie_ Xu/a'e X'ien'eF "ol. T1F no. 1yF &&. S1U\F TUUh. gie at
mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
52. G. X. Ki,F X. H. H6unF an_ H. H. ma/:F zX6ntheDiD o loZ_iele't/i' Dili'a
ae/ogel il,D 86 a,8ient _/6ingF{ lou/nal o the A,e/i'an Ce/a,i' Xo'iet6F "ol. yF
no. TF &&. y\hy\\F TUU1. gie at X'o&uD
53. l. . vouDDetF A. xou:ente/F x. Cha,&agnonF l. Iu,aDF j. Iu"alF l. .
}uinDonF an_ l. Xe/ughettiF zG/anula/ Dt/u'tu/e an_ /a'tal _o,ainD o Dili'a
ae/ogelDF{ lou/nal o mh6Di'D: Con_enDe_ Vatte/F "ol. TF no. yTF &&. yy\y\\F
1SSU. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
5-. G. V. maon: an_ T. VanualiF zX6ntheDiD o a'/6lonit/ile /o, &/o&6lene an_
nit/i' oki_e ,iktu/eD on m8OTZ/OT ae/ogel 'atal6DtDF{ Catal6DiD ette/DF "ol. T1F no.
hZyF &&. h1hSF 1SSh.gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
55. A. Xa6a/iF A. Gho/8elF G. V. maon:F an_ X. l. Tei'hne/F zKineti'D o the
'atal6ti' t/anDo/,ation o iDo8utene into ,etha'/6lonit/ile ith AO on Du&&o/te_
ni':el oki_e ae/ogelF{ vea'tion Kineti'D an_ Catal6DiD ette/DF "ol. 1\F no. yF &&. y\S
y\F 1S1. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
5!. H. I. GeDDe/ an_ m. C. GoDa,iF zAe/ogelD an_ /elate_ &o/ouD
,ate/ialDF{ Che,i'al ve"ieDF "ol. SF no. yF &&. [\[F 1SS. gie at X'o&uD
5.. . X,i/no"aF X. Xutti/uengongF an_ . A/ltF zeaDi8ilit6 Dtu_6 o h6_/o&hili'
an_ h6_/o&ho8i' Dili'a ae/ogelD aD _/ug _eli"e/6 D6Dte,DF{ lou/nal o AonZC/6Dtalline
Xoli_DF "ol. h\UF &&. \yUF TUUy. gie at mu8liDhe/ gie at Google X'hola/ gie
at X'o&uD
Trang
22
"#: $%o C&ng Thanh ' (gu) n Th *i+ Li,n
AEROGEL-SILICA V NG D NG GVHD:PGS.TS Nguy n Ng c H nh
5/. . X,i/no"aF X. Xutti/uengongF V. Xeile/F an_ . A/ltF zIiDDolution /ate
enhan'e,ent 86 a_Do/&tion o &oo/l6 Dolu8le _/ugD on h6_/o&hili' Dili'a
ae/ogelDF{ mha/,a'euti'al Ie"elo&,ent an_ Te'hnolog6F "ol. SF no. yF &&. yyhy\TF
TUUy. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
50. V. luu:oF Ae/ogel Ca&a'ito/D Xu&&o/t mulDeF Hol_ZU&F an_ Vain moe/
A&&li'ationDF Coo&e/ jle't/oni' Te'hnologieDF moe/Xto/ m/o_u'tDF Iu8linF CaliF
UXAF TUUT.
!1. T. . Ha,annF A. x. . Va/tinDonF l. . jla,F V. l. mellinF an_ l. T. Hu&&F
zAto,i' la6e/ _e&oDition o TiOT on ae/ogel te,&lateD: ne &hotoano_eD o/ _6eZ
DenDitiue_ Dola/ 'ellDF{ lou/nal o mh6Di'al Che,iDt/6 CF "ol. 11TF no. T[F &&. 1UhUh
1UhU[F TUU. gie at mu8liDhe/ gie at Google X'hola/ gie at X'o&uD
1. zm/e"enting heat eD'a&e th/ough inDulation 'alle_ zae/ogel{F{ AAXA Cm.
T. zIonZtoZja/th UDeD o/ X&a'e Vate/ialDF{ The Ae/oD&a'e Co/&o/ation.
h. V. . Au':olDF l. C. ChaoF an_ V. l. Xie/goDuF zVanne_ j"aluation o a
m/otot6&e Co,&oDite Col_ ate/ Ii"ing Ga/,ent UDing i<ui_D an_ Xu&e/inDulation
Ae/ogel Vate/ialDF{ Te'h. ve&. AjIUZU\ZUTF Unite_ XtateD Aa"6 jk&e/i,ental
Ii"ing UnitF TUU\.
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