Base Completa

PROPRIEDADES TERMOFSICAS DE SUBSTANCIAS PURAS

Esta base de dados foi copiada de "The Properties of Gases and Liquids, 4th. Edition", por Reid, Prausnitz y Poling, McGraw Hill, 1987.
A origem desta cpia desconhecida

NMERO

COMPONENTE

FRMULA

MASSA
MOLECULAR
kg/kmol

168
170
206
236
237
240
258
311
321
379
386
429
483
529
567
578
584
77
117

ETANO
ETANOL
PROPANO
1-BUTENO
2-BUTENO,cis
ISOBUTILENO
N-BUTANO
N-PENTANO
TER-BUTIL METIL ETER
N-HEXANO
ETIL BUTIL ETER
N-HEPTANO
N-OCTANO
N-NONANO
N-DECANO
N-UNDECANO
N-DODECANO
AGUA
METANOL

C2H6
C2H6O
C3H8
C4H8
C4H8
C4H8
C4H10
C5H12
C5H12O
C6H14
C6H14O
C7H16
C8H18
C9H20
C10H22
C11H24
C12H26
H2O
CH4O

PARA CALCULO DE Pvap SEGUNDO PRAUSNITZ

EQ.1

Pgina 1

30.070
46.069
44.094
56.108
56.108
56.108
58.124
72.151
88.150
86.178
102.177
100.205
114.232
128.259
142.286
156.313
170.340
18.015
32.042

TEMP. PRESSO
CRTICA CRTICA
K
(TC)
305.4
513.9
369.8
419.6
435.6
417.9
425.2
469.7
496.4
507.5
531.0
540.3
568.8
594.6
617.7
638.8
658.2
647.3
512.6

bar
(PC)
48.8
61.4
42.5
40.2
42.0
40.0
38.0
33.7
33.7
30.1
30.4
27.4
24.9
22.9
21.2
19.7
18.2
221.2
80.9

VOLUME
CRTICO

COMPRES.
CRTICA

cm3/mol
(VC)

(ZC)

148.3
167.1
203.0
240.0
234.0
239.0
255.0
304.0

0.285
0.240
0.281
0.277
0.271
0.275
0.274
0.263

370.0
390.0
432.0
492.0
548.0
603.0
660.0
713.0
57.1
118.0

0.264
0.270
0.263
0.259
0.260
0.249
0.240
0.240
0.235
0.224

Base Completa

ln(Pvap/Pc)=(1-x)^-1*[(VPA)*x+(VPB)*x^1.5+(VPC)*x^6]
sendo x=1-(T/Tc)
EQ. 2
lnPvp= VPA - (VPB)/T + (VPC)*lnT + (VPD)*Pvp/T^2
EQ. 3
lnPvp= VPA - (VPB) / [T+VPC]

Pgina 2

Base Completa

S PURAS

cGraw Hill, 1987.

FACTOR H VAPORIZ.
ACNTRICO
(TB)
(w)
0.099
0.644
0.153
0.191
0.202
0.194
0.199
0.251
0.269
0.299
0.400
0.349
0.398
0.445
0.489
0.535
0.575
0.344
0.556

kJ/mol
(DHV)
14.707
38.744
18.774
21.916
23.347
22.117
22.393
0.258
28.853
31.798
31.698
34.413
8.823
9.388
9.920
10.430
40.656
35.254

CAPACIDADE CALORFICA GS IDEAL

CP = A + B T + C T 2 + D T 3
(A)
5.4090E+00
9.0140E+00
-4.2240E+00
-2.9940E+00
4.3960E-01
1.6050E+01
9.4870E+00
-3.6260E+00
2.5340E+00
-4.4130E+00
2.3630E+01
-5.1460E+00
-6.0960E+00
-8.3740E+00
-7.9130E+00
-8.3950E+00
-9.2380E+00
3.2200E+01
2.1150E+01

T em [K], CP em [J/mol K]
(B)
(C)
1.7810E-01 -6.9380E-05
2.1410E-01 -8.3900E-05
3.0630E-01 -1.5860E-04
3.5320E-01 -1.9900E-04
2.9530E-01 -1.0180E-04
2.8040E-01 -1.0910E-04
3.3130E-01 -1.1080E-04
4.8730E-01 -2.5800E-04
5.1360E-01 -2.5960E-04
5.8200E-01 -3.1190E-04
5.3670E-01 -2.5280E-04
6.7620E-01 -3.6510E-04
7.7120E-01 -4.1950E-04
8.7290E-01 -4.8230E-04
9.6090E-01 -5.2880E-04
1.0540E+00 -5.7990E-04
1.1490E+00 -6.3470E-04
1.9240E-03 1.0550E-05
7.0920E-02 2.5870E-05

EQ. PRESSO CONSTANTES PARA EQ. DE PRESSO DE VAPOR

DE VAPOR
VP A
VP B
VP C
PS em [bar] , PC em [bar] , T em [K] , TC em [K]

(D)
8.7130E-09
1.3730E-09
3.2150E-08
4.4630E-08
-6.1600E-10
9.0980E-09
-2.8220E-09
5.3050E-08
4.3030E-08
6.4940E-08
4.1570E-08
7.6580E-08
8.8550E-08
1.0310E-07
1.1310E-07
1.2370E-07
1.3590E-07
-3.5960E-09
-2.8520E-08

Pgina 3

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
1
1

-6.34307
-8.51838
-6.72219
-6.88204
-6.88706
-6.95542
-6.88709
-7.28936
-7.8252
-7.46765
-8.30292
-7.67468
-7.91211
-8.24480
-8.56523
73.501
77.628
-7.76451
-8.5480

1.01630
0.34163
1.33236
1.27051
1.15941
1.35673
1.15157
1.53679
2.95493
1.44211
2.02889
1.37068
1.38007
1.57885
1.97756
9305.80
1002.50
1.45838
0.76982

-1.19116
-5.73683
-2.13868
-2.26284
-2.19304
-2.45222
-1.99873
-3.08367
-6.94079
-3.28222
-3.26245
-3.53620
-3.80435
-4.38155
-5.81971
-8.729
-9.236
-2.77580
-3.11

Base Completa

Pgina 4

Base Completa

E PRESSO DE VAPOR
T MIN.
T MAX. EQ. DE ANTOINE PARA PRESSO DE VAPOR
ln PS = A - B/(T+C)
VP D
PARA PRESSO DE VAPOR
PS em [kPa] , T em [K]

, T em [K] , TC em [K]
-2.03539
8.32581
-1.38551
-2.61636
-3.12758
-1.46110
-3.13003
-1.02456
12.17416
-2.50941
-6.32274
-3.20243
-4.50132
-4.04412
-0.29982
8813.0
10030.0
-1.23303
1.54481

133.0
293.0
145.0
170.0
203.0
170.0
170.0
195.0
287.0
220.0
311.0
240.0
260.0
343.0
368.0
350.0
360.0
275.0
288.0

305.4
513.9
369.8
419.6
435.6
417.9
425.2
469.7
496.4
507.5
531.0
540.3
568.8
594.6
617.7
638.8
658.2
647.3
512.6

(A)
13.6485
16.8967
13.7108
13.7412
13.8019
13.7376
13.6630
13.8181

(B)
1511.42
3803.98
1872.46
2132.42
2210.71
2125.75
2154.90
2477.07

(C)
-17.16
-41.68
-25.16
-33.15
-36.15
-33.15
-34.42
-39.94

13.8214
14.0325
13.8585
13.9274
13.9519
13.9962
14.0389
14.0982

2697.55
2921.52
2911.32
3120.29
3291.45
3456.80
3614.07
3774.56

-48.78
-55.15
-56.51
-63.63
-71.33
-78.67
-85.45
-91.31

Pgina 5

T MIN.
T MAX. EQ. DE ANTOINE PARA PRESSO DE VA
PARA EQ. DE ANTOINE DADOS SEGUNDO HENLEY E SEADER
K
(TMIN)

K
(TMAX)

130.0
270.0
164.0
190.0
200.0
190.0
195.0
220.0

199.0
369.0
249.0
295.0
305.0
290.0
290.0
330.0

245.0
265.0
270.0
292.0
312.0
330.0
348.0
364.0

370.0
400.0
400.0
425.0
452.0
476.0
498.0
520.0

PS em [psia] , T em [F], Tc em
(A)
5.383894

(B)
2847.921

5.353418
5.58272
5.45629
5.61676
5.74162
5.85365

3371.084
3941.014
3977.563
3953.678
4126.385
4598.287

6.03924

5085.758

5.98627
6.41410
6.22189
6.33557
7.21247
6.56114
6.53247
7.51333

5278.902
5947.491
6662.655
6213.998
7475.258
6739.220
7173.790
6468.101

Base Completa

Pgina 6

Base Completa

PARA PRESSO DE VAPOR

O HENLEY E SEADER

EQ.DE HARLACHER PARA PRESSO DE VAPOR

ln PS = A + B/T + C ln T + D PS/(T2)
PS em [kPa] , T em [K]

[psia] , T em [F], Tc em [R]

(B)

DENSIDAD LIQ. TEMP.REF. PARA VOLUME de LQ.

@TDEN
LIQDEN
(298,15 K)
g/cm3

(C)
434.898

(A)

(C)

414.488
404.7410
394.4956
405.9166
409.5179
394.4148

41.477
46.318
47.594
48.817
46.319
54.667

-3266.92
-3996.80
-4217.05
-4104.56
-4065.57
-4827.08

-4.179
-4.788
-4.938
-5.157
-4.781
-5.313

1.810
2.460
2.580
2.460
2.680
3.680

382.7940

55.264

-5587.42

-5.885

4.778

359.5259
360.2600
330.9600
317.6512
350.7821
292.5740
389.4747
396.2652

59.261
64.624
71.118
73.460

-6303.87
-7100.69
-7969.42
-8563.64

-6.373
-7.053
7.890
-8.149

6.000
7.310
8.690
10.200

53.321
70.253

-6869.50
-7064.20

-5.115
-7.680

1.050
1.860

Pgina 7

(D)

(LIQDEN)
0.548
0.789
0.582
0.595
0.621
0.594
0.579
0.626
0.659
0.749
0.684
0.703
0.718
0.730
0.740
0.748
0.998
0.791

K
(TDEN)
183.0
293.0
231.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0
293.0

m3/kmol
(VL)
0.055205
0.058515
0.075642
0.089621
0.087450
0.089434
0.096647
0.116126
0.119828
0.131287
0.147113
0.163655
0.179321
0.195342
0.212084
0.228505
0.018067
0.040691

Base Completa

Pgina 8

OLUME de LQ.
(298,15 K)
m3/kmol
TB
TB
TB
TB
TB
TB

PROPRIEDADES CALCULADAS

Base Completa

Hl
POLINMIO DE AJUSTE DA CORRELAO
A
128.8
616.45
167.13

B
-687.43
-3314
-894.31

C
2293.5
8971.6
2941.5

D
-3141.4
-10687
-3887.6

E
1577.4
4722.6
1889

221.7
254.77

-1093.1
-1261

3508.2
4110

-4526.3
-5240.5

2154.5
2454.6

296.61

-1430.8

4676.1

-5902.1

2731.6

340.29
382.86
422.32

-1606.9
-1774.7
-1925.6

5264
5836.6
6379.1

-6590.7
-7264.8
-7910.2

3020.1
3302.9
3574.1

373.19

-1946.3

5313.5

-6534.5

2991.3

TB

Pgina 9

Base Completa

Pgina 10

Base Completa

Pgina 11