Universidad de San Carlos de Guatemala

Facultad de Ingeniera
Escuela de Ingeniera Qumica

rea de Fisicoqumica
Fisicoqumica 1
Ing. William Fagiani
PRINCIPIOS TERMODINMICOS

PRINCIPIOS BSICOS
Funcin
Funcin de
estado
Gas Ideal
(1834)

= (, , )

Van der Waals

(1873)
Virial
(Kammerlingh
Onnes)
(1901)
Beattie
Bridgeman
(1928)
Benedict
Webb
Rubin
(1940)
Redlich
Kwong
(1949)

=
2

=

1 0 =

= 1 0

2
tr
3

= 0
tr =

1
2
2

( )

= , = tr , + rot , + vib ,

2 2

= 0.125

+
+
+
2 3

= gi

+ 2
3

= 0.421875

3
3
=
2
2
=

= 0 1

2
3
=

= 0 1

0
1

+ 0 0 2 2 +
+
+
1 + 2 exp 2

3
6 3 2

( + )

Hederer Peter
Wenzel
(1976)

gi =

Soave
Redlich
Kwong
(1972)
Peng
Robinson
(1976)

=
tr , = tr =

Sustancias
Reales

= (, , )

= 0.42747

= 0.08664

2 2

= 1 + 1
= 0.08664

= 0.48 + 1.574 0.176 2

2 2
=
= 0.45724

2
= 1 + 1
= 0.0778

= 0.37464 + 1.54226 0.26992 2

=

2 2
= 0.08664

= 0.42747

( + )

2
+ 2 2

2 2.5

( + )

= 0.42748

LEYES DE LA TERMODINMICA
LEY 0
LEY 1

( )

= , = tr , + rot , + vib ,
= + +

RELACIONES

9
=
+ 32
5

= +

rev =
LEY 2

= + 273.15
K

= +

=+

rev
=

= +

= +

= ( )

=+

= +

= +

= +

sat

sat