T referencia

L (A)

V (A)
0.0000
0.0190
0.0721
0.0966
0.1238
0.1661
0.2337
0.2608
0.3273
0.3965
0.5079
0.5198
0.5732
0.6763
0.7472
0.8943
1.0000

T (C)
0.0000
0.1700
0.3891
0.4375
0.4704
0.5089
0.5445
0.5580
0.5826
0.6122
0.6564
0.6599
0.6841
0.7385
0.7815
0.8943
1.0000

T(K)
100
95.5
89
86.7
85.3
84.1
82.7
82.3
81.5
80.7
79.8
79.7
79.3
78.74
78.41
78.15
78.4

A: ETANOL
B: AGUA
LINEA DE OPERACIN

LIQUIDO
A
373.15
368.65
362.15
359.85
358.45
357.25
355.85
355.45
354.65
353.85
352.95
352.85
352.45
351.89
351.56
351.3
351.55

0
0.019
0.0721
0.0966
0.1238
0.1661
0.2337
0.2608
0.3273
0.3965
0.5079
0.5198
0.5732
0.6763
0.7472
0.8943
1

1
0.981
0.9279
0.9034
0.8762
0.8339
0.7663
0.7392
0.6727
0.6035
0.4921
0.4802
0.4268
0.3237
0.2528
0.1057
0

0
1
T (C)

T(K)
100
95.5
89
86.7
85.3
84.1
82.7
82.3
81.5
80.7
79.8
79.7
79.3
78.74
78.41
78.15
78.4

373.15
368.65
362.15
359.85
358.45
357.25
355.85
355.45
354.65
353.85
352.95
352.85
352.45
351.89
351.56
351.3
352.3

VAPOR
A
B
0.0000
0.1700
0.3891
0.4375
0.4704
0.5089
0.5445
0.5580
0.5826
0.6122
0.6564
0.6599
0.6841
0.7385
0.7815
0.8943
1.0000

1.0000
0.8300
0.6109
0.5625
0.5296
0.4911
0.4555
0.4420
0.4174
0.3878
0.3436
0.3401
0.3159
0.2615
0.2185
0.1057
0.0000

CALOR LATENTE VAP A

CALOR LATENTE VAP B

J/mol
39275.11
40667.22

273
50000.00
45000.00
40000.00
35000.00
Entalpia de mezcla , J/mol

entalpia A(J/mol)
Entalpia B (J/mol)
HA*XA
HB*XB
Hmezcla L
12393.89
7546.47
0.00
7546.47
23827.47
11724.94
7203.16
222.77
7066.30
22085
10784.87
6708.01
777.59
6224.36
18230
10459.22
6533.00
1010.36
5901.92
16757
10262.71
6426.53
1270.52
5630.92
15384
10095.28
6335.29
1676.83
5283.00
13654
9901.10
6228.89
2313.89
4773.20
11629
9845.85
6198.49
2567.80
4581.92
11034
9735.64
6137.71
3186.47
4128.84
9979
9625.82
6076.94
3816.64
3667.43
9337
9502.74
6008.59
4826.44
2956.83
8943
9489.09
6000.99
4932.43
2881.68
8927
9434.57
5970.62
5407.89
2548.26
8897
9358.40
5928.10
6329.08
1918.93
8934
9313.60
5903.05
6959.12
1492.29
8965
9278.35
5883.31
8297.63
621.87
9087
9312.24
5902.29
9312.24
0.00
9436

30000.00
25000.00
20000.00
15000.00
10000.00
5000.00
0.00

entalpia A(J/mol)
Entalpia B (J/mol)
HA*YA
HB*YB
Hmezcla V
46240.46
44046.70
0.00
44046.70
44046.70
45894.12
43893.49
7802.00
36431.60
44233.60
45399.27
43672.45
17664.86
26679.50
44344.36
45225.72
43594.31
19786.25
24521.80
44308.05
45120.47
43546.77
21224.67
23062.37
44287.04
45030.50
43506.02
22916.02
21365.81
44281.83
44925.81
43458.50
24462.10
19795.35
44257.45
44895.95
43444.93
25051.94
19202.66
44254.60
44836.31
43417.78
26121.63
18122.58
44244.21
44776.77
43390.64
27412.34
16826.89
44239.23
44709.90
43360.11
29347.58
14898.53
44246.11
44702.48
43356.71
29499.17
14745.62
44244.78
44672.81
43343.15
30560.67
13692.10
44252.77
44631.31
43324.16
32960.22
11329.27
44289.49
44606.87
43312.96
34860.27
9463.88
44324.15
44587.64
43304.15
39874.72
4577.25
44451.97
44661.69
43338.06
44661.69
0.00
44661.69

1.0000

0.9000

0.8000

0.7000

0.6000

0.5000

0.4000

0.3000

0.2000

0.1000

0.0000

50000.00
45000.00
40000.00
35000.00
30000.00
25000.00
20000.00
15000.00
10000.00
5000.00
0.00
0

0.1

0.2

0.3

0.4

0.5
X , fraccion molar

1.0000

0.9000

0.8000

0.7000

0.6

0.6000

0.5000

0.4000

0.3000

0.2000

0.1000

0.0000
0.0000

0.1000

0.2000

0.3000

0.4000

0.5000

0.6000

0.6

0.7

0.8

0.9

FRACCION DESTILADO
x
0.8824
0.8824
0.8771
0.88133
0.8771
0.8771
0.8771
0.8771
0.8771
0.873
0.873
0.873
0.873
0.873
0.873
0.8675
0.8675
0.8675
0.8675
0.8675
0.8675
0.861
0.861
0.861
0.861
0.861
0.861
0.853
0.853
0.853
0.853
0.853
0.853
0.843
0.843
0.843
0.843
0.843
0.843
0.83
0.83
0.83

0.6000

0.7000

0.8000

0.9000

1.0000

0.83
0.83
0.83
0.813
0.813
0.813
0.813
0.813
0.813
0.791
0.791
0.791
0.791
0.791
0.791
0.76
0.76
0.76
0.76
0.76
0.76
0.714
0.714
0.714
0.714
0.714
0.714
0.631
0.631
0.631
0.631
0.631
0.631
0.443
0.443
0.443
0.443
0.443
0.443
0.0998
0.0998
0.0998
0.0998
0.0998

XD=
y
0.8824
1
0.88133
0.88133
0.88133
1
0.88133
0.8771
0.8771
0.8771
0.8771
1
0.8771
0.873
0.873
0.873
0.873
1
0.873
0.8675
0.8675
0.8675
0.8675
1
0.8675
0.861
0.861
0.861
0.861
1
0.861
0.853
0.853
0.853
0.853
1
0.853
0.843
0.843
0.843
0.843
1

0.8824
x
0.8824
0.8824

0
44351.26

0.8771
0.8771

0
44351.26

0.8771
0.8824

9219.49
44351.26

0.873
0.873

0
44351.26

0.873
0.8771

9219.49
44351.26

0.8675
0.8675

0
44351.26

0.8675
0.873

9219.49
44351.26

0.861
0.861

0
44351.26

0.861
0.8675

9219.49
44351.26

0.853
0.853

0
44351.26

0.853
0.861

9219.49
44351.26

0.843
0.843

0
44351.26

0.843
0.853

9219.49
44351.26

0.83
0.83

0
44351.26

0.83
0.843

9219.49
44351.26

PLATOS IDEALES
x

0.843
0.83
0.83
0.83
0.83
1
0.83
0.813
0.813
0.813
0.813
1
0.813
0.791
0.791
0.791
0.791
1
0.791
0.76
0.76
0.76
0.76
1
0.76
0.714
0.714
0.714
0.714
1
0.714
0.631
0.631
0.631
0.631
1
0.631
0.443
0.443
0.443
0.443
1
0.443
0.0998

0.813
0.813

0
44351.26

0.813
0.83

9100
44351.26

0.791
0.791

0
44351.26

0.791
0.813

9100
44351.26

0.76
0.76

0
44351.26

0.76
0.791

9100
44351.26

0.714
0.714

0
44351.26

0.714
0.76

9100
44351.26

0.631
0.631

0
44351.26

0.631
0.714

9100
44351.26

0.443
0.443

0
44100

0.443
0.631

9100
44351.26

0.0998
0.0998

0
44100

0.0998
0.443

16600
44351.26

Hs, Cal/mol

Hs, J/mol
21.00
42.10
97.90
141.00
196.90
298.90
454.00
725.90
1297.00
2355.00
2996.00

87.78
175.98
409.22
589.38
823.04
1249.40
1897.72
3034.26
5421.46
9843.90
12523.28

fraccion molarAgua Fraccion EtOH

Hs, J/mol
0.05
0.95
87.78
0.10
0.90
175.98
0.20
0.80
409.22
0.30
0.70
589.38
0.40
0.60
823.04
0.50
0.50
1249.40
0.60
0.40
1897.72
0.70
0.30
3034.26
0.80
0.20
5421.46
0.90
0.10
9843.90
0.95
0.05
12523.28

14000.00
12000.00

y = 53321x4 -

10000.00
8000.00
6000.00
4000.00
2000.00
0.00
0.00

0.20

0.40

y = 53321x4 - 154128x3 + 165919x2 - 81269x + 16281

R = 0.9996

0.40

0.60

0.80

1.00