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LECTURE XIII-XIV
http://www.its.ac.id/personal/material.php?id=fahmi
Outline
1st Chapter 2nd Chapter
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Definition
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Causes
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Corrosion in Metal
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Corrosion in Metal
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Corrosion in Metal
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Electrochemical Cell
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Environmental Effects
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Form of Corrosion General corrosion (uniform corrosion) Galvanic Crevice Pitting Inter-granular SCC Erosion Corrosion Hydrogen Embrittlement
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Form of Corrosion
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Galvanic Corrosion
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Galvanic Corrosion
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Galvanic Corrosion
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Crevice Corrosion
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Crevice Corrosion
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Crevice Corrosion
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Pitting Corrosion
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Intergranular Corrosion
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Intergranular Corrosion
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Selective leaching
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Erosion corrosion
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2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure 22.8 Examples of stress cells. (a) Cold work required to bend a steel bar introduces high residual stresses at the bend, which then is anodic and corrodes. (b) Because grain boundaries have a high energy, they are anodic and corrode.
Metallurgy Lab. Mech. Eng. Dept. ITS Surabaya xi 33
Hydrogen Embrittlement
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Corrosion Environments
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Corrosion Preventions
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Cathodic Protection
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Cathodic Protection
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Anodic Protection
Fairly new concept Used where cathodic protection is not practical, such as in strongly alkaline or acidic environments, anodic protection is a useful corrosion control technique. Basics formation of protective film through externally applied currents
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suitable for active-passive alloys (e.g. stainless steel, nickel alloys, titanium) requires a broad potential range for passivity need sizable/expensive electrical equipment risky if potential slips into the active/pitting region used often for very aggressive solutions when other methods fail, e.g. for protection of tanks storing of strong acids (e.g. sulphuric, phosphoric, nitric)
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Advantage-disadvantage
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Cathodic
+ can be used for all metals installation cost is low corrosion rate can be reduced to zero
Anodic
can be used in extremely aggressive environment applied current is direct measure of corrosion rate operating conditions can be easily controlled operation cost low
can only be used in weak only applicable to active-passive to moderate environment metals operating conditions must installation cost is high be determined by empirical testing.
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METALLURGY II
(RM-1421)
MINGGU XIV
UAS
Dosen: Fahmi Mubarok, ST., MSc. Metallurgy Laboratory Mechanical Engineering ITS- Surabaya 2008
Jadwal kuliah : Tiap hari Senin pukul 15.00 16.40 Ruang c-121
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