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LITERATURES
References/Textbook:
Smith, J.M., Van Ness, H.C., and Abbott, M.M. (2001). Introduction to Chemical Engineering Thermodynamics. 6th Edition. New York: McGraw Book Co. Elliot, J. R. and Lira, C.T., (1999), Introductory Chemical Engineering Thermodynamics, Prentice Hall PTR. etc
Introduction to Multicomponents VLE Systems VLE Calculation in Mixtures by an Equation of State Activity Models
Modified Raoult's laws Margules Equation Van Laar Equation Regular-Solution Theory Wilson's Equation UNIQUAC UNIFAC
4.
Mass Balance
F = L + V (over all)
==> 1 = L/F + V/F zAF = yAV + xAL (zA = overall mole fraction) ==> zA = yA.V/F + xA.L/F de Percentage of liquid: L/F = (zA-yA) / (xA-yA) ==> ce cd Percentage of vapor: V/F = (xA-zA) / (xA-yA) ==> ce Remember that: L/F + V/F = 1
=y P fi i
i =
fi yi P
=y P f i i i
For ideal gases ==> i = 1 and fio =P For LIQUID: Activity: ==> Activity Coefficient ==>
=y P fi i
ai= i/ f f
i = i /x i f f
o i
GAMMA APPROACH V L Pi P sat i i Remember: Fugacity of component i in LIQUID: f io = i sat P isat exp RT
P P
i i sat
RT
L =i x i P sat i
Ideal Solutions
Ideal Solutions:
No synergistic effect of the components in mixture each component operates independently no energy change for mixing no volume change
LEWIS/RANDALL Rule:
is fi fi
is =xi i =xi f i f
V= f L f i i
f L = sat P
i i V sat exp
y i f i =x i f i
L
P P
i i sat i
yi xi
P =
sat
sat
isat exp V
[ P P / RT ]
i L i i sat
RT V L P i P
sat
RT
i
V
=1, dan
exp V
[ P P / RT ]
i L i i sat
Ki=
Pi
sat
atau
Pi
y i P= xi Pisat
Ki=
sat Pi
Pc,i 10
VLE CALCULATIONS
Bubble-point Pressure (BP) Dew-point Pressure (DP) Bubble-point Temperature (BT) Dew-point Temperature (DT) Isothermal Flash (FL)
BP DP BT DT FL
y i = K i xi =1
i i
y i = K i xi =1
i i
x i = Ki =1
i i i
x i = Ki =1
i
z i 1K i
i
K i L /F 1K i
K i x i=1 ,
i i
Pi
sat
xi =1
sat sat
P1
sat
x1
P2
sat
x 2 =1
P=x1 P 1 x 2 P2
Tidak diperlukan iterasi, karena temperature dan tekanan uap diketahui. Hk Raoult linear bubble pressure line (P-x,y) x 2 =1 x1
P=x1 P sat 1x 1 P sat =x 1 P sat P sat P sat 1 2 1 2 2
P1
P2
Diselesaikan tanpa iterasi, sebab tekanan uap adalah tertentu pada temperatur yang ditentukan, sehingga:
P=
1 y1 P1 sat y2 P sat 2
Diselesaikan dengan iterasi Temperatur (yang mengubah Pisat), hingga tekanan sama dengan tekanan yang diketahui.
P=
1 y1
sat P1
y2 P sat 2
Diselesaikan dengan iterasi Temperatur (yang mengubah Pisat), hingga tekanan sama dengan tekanan yang diketahui.
z i =x i
==>
xi=
zi K i L 1K i F yi=
yi
zi K i L K i 1K i F
Dalam perhitungan flash, L/F harus diiterasi hingga xi=1, Tetapi dalam flash, kita juga harus menyelesaikan yi=1 Untuk penyelesaian uap dan cairan, maka secara simultan: (xi-yi)=0 ==> fungsi objective Note that: 0<L/F<1 Kasus-kasus flash: zi, feed flow rate, P, T ==> diketahui
Bubble Calculation:
y i=1,
i
atau
xi K i =
i
xi Psat i
i
=1
Dew Calculation:
x i=1,
i
atau
Ki
i
= P
i
yi Pisat
=1
Rules:
bubble- & dew-pressure calculation ==> no iteration required bubble- & dew-temperature calculation ==> iteration required
T = xi T i
i
sat
atau T =
y i T r ,i T sat i
i
y i T c, i
i
z 1K
Penyelesaian
(a) Temperatur dimana semua uap terkondensasi ==>
bubble point temperatur Dengan MS Excel:
zi Pci (bar) Tci (K) 0,23 42,48 369,8 0,67 36,48 408,1 0,1 37,96 425,1 1 Tekanan (bar) = Tebak T (K) = Ki 0,152 1,609 0,181 0,612 0,200 0,433 8 310 Tebak T (K) = yi Ki 0,370 2,027 0,410 0,795 0,043 0,571 0,82 320 yi 0,47 0,53 0,06 1,06
Stream No. Name - - Overall - Molar flow kmol/h Mass flow kg/h Temp K Pres bar Vapor mole fraction Vapor mass fraction Enth MJ/h Heating values (60 F) Gross J/kmol Net J/kmol Actual vol m3/h Std liq m3/h Std vap 0 C m3/h Component mole fractions Propane I-Butane N-Butane
1 Feed 1.0000 54.8968 100.0000 8.0000 0.0000 0.0000 -166.77 2.722E+009 2.511E+009 0.0743 0.0991 22.4136 0.230000 0.670000 0.100000
3 Liquid Produ 1.0000 54.8968 319.7421 8.0000 0.0000 0.0000 -142.68 2.722E+009 2.511E+009 0.1072 0.0991 22.4136 0.230000 0.670000 0.100000
dew
zi
Pci (bar) Tci (K) 0,23 42,48 369,8 0,67 36,48 408,1 0,1 37,96 425,1 1,000
(b). ChemCAD 2
1 2 Vapor 1 Flash
Stream No. Name - - Overall - Molar flow kmol/h Mass flow kg/h Temp K Pres bar Vapor mole fraction Enth MJ/h Heating values (60 F) Gross J/kmol Net J/kmol Actual vol m3/h Std liq m3/h Std vap 0 C m3/h Component mole fractions Propane I-Butane N-Butane
1 Feed 1.0000 54.8968 100.0000 8.0000 0.0000 -166.77 2.722E+009 2.511E+009 0.0743 0.0991 22.4136 0.230000 0.670000 0.100000
2 Vapor Produc 1.0000 54.8968 324.9329 8.0000 1.000 -125.26 2.722E+009 2.511E+009 2.8142 0.0991 22.4136 0.230000 0.670000 0.100000
z 1K
xi=
zi K i L 1K i F
yi =
zi K i L K i 1K i F
2 Vapor