СОДРЖИНА

Table of content

ПЛЕНАРНИ ПРЕДАВАЊА – PLENARY LECTURES

PL–01-E Paolo Piccardo, Dragan Temelkoski, Biljana Minčeva-Šukarova, Orhideja

Grupče
rd
"STUDIES ON 3 CENTURY BC SHIELDS
FROM THE REPUBLIC OF MACEDONIA"
PL–02-E Velimir Radmilovic
STRUCTURE AND COMPOSITION OF CORE/SHELL
NANOSTRUCTURES EMBEDDED IN SOLIDS
PL–03-E Alexander Milchev
NUCLEATION AND GROWTH PHENOMENA IN ELECTRO-
CRYSTALLIZATION: THEORY AND EXPERIMENTAL RESULTS
PL–04-E Anita Trajkovska
TRENDS IN DISPLAY TECHNOLOGIES – A CASE STUDY: LCD

ПРЕДАВАЊА ПО ПОКАНА – INVITED LECTURES

IL–01-E Radoslav Atanasoski
FUEL CELL CATALYSTS OF TOMORROW: FUNDAMENTALS AND
APPLICATION
IL–02-E Anita Grozdanov
SUSTAINABLE ECO-FRIENDLY POLYMER CONSTRUCTION
COMPOSITE MATERIALS
IL–03-E Igor Ćatić
AGRICULTURE PRODUCTS – FOOD FOR PEOPLE BEING OR FOR
MACHINERY
IL–04-E Marek Kozlowski
MATERIALS FROM RENEWABLE RESOURCES

„КЛУЧНИ“ ПРЕДАВАЊА – KEYNOTE LECTURES

KL–01-E Jarosław J. Panek, Aneta Jezierska
THE INTERACTION ENERGY INVESTIGATIONS OF SMALL
COMPLEXES ON THE BASIS OF SYMMETRY-ADAPTED
PERTURBATION THEORY
KL–02-E Igor Kuzmanovski, Sacha Javor, Jean-Louis Reymond, Marjana Novič
THE INFLUENCE OF DIFFERENT AMINO ACIDS ON THE
COMPACTNESS OF THE STRUCTURE OF DENDRIMERS –
CHEMOMETRIC APPROACH

KL–03-E Kostas Symeonides

ALTERNATIVE SOLUTIONS FOR WASTE MANAGEMENT: A SYMBIOSIS
BETWEEN WASTE MANAGEMENT OPERATIONS AND CEMENT
MANUFACTURE
KL–04-E Ilija Brčevski
URBAN ZONES AND TOXIC WASTE
KL–05-E Petra Najmanova, Jan Vanek, Iveta Cepelakova, Josif Tanevski,
BIOLOGICAL TREATMENT OF CONTAMINATED SOIL FROM THE SITE
OF NATO MILITARY BASE AT PETROVEC AIRPORT & RESEARCH AND
DEVELOPMENT ACTIVITIES IN BIOREMADIATION
KL–06-E Anka Trajkovska Petkoska
POLYMER CHOLESTERIC LIQUID CRYSTAL FLAKES AS A NOVEL
FORM FOR ELECTRONIC PAPER APPLICATION
KL–07-E N. Milosavljević, M. Kalagasidis Krušić, J. Filipović
SWELLING BEHAVIOUR AND MECHANICAL PROPERTIES
OF SEMI-IPNs OF CHITOSAN AND POLY(ETHYLENE GLYCOL)
KL–08-E Bogdana Koumanova
ADSORPTION OF TOXIC ORGANICS ON NATURAL MATERIALS FROM
AQUEOUS MEDIUM – MASS TRANSFER PROCESSES
KL–09-E Biljana Mangovska,
ENZYMATIC VS.TRADTIONAL SCOURING OF COTTON:
PROS AND CONS
KL–10-E Daniela Kovacheva
PEROVSKITE MATERIALS WITH INTERESTING ELECTRICAL AND
MAGNETIC PROPERTIES
KL–11-E Radmila Tomovska, Jozef Pola
ARF LASER PHOTOLYTIC DEPOSITION OF NANOPOLYMERIC
ORGANOSULFUR MATERIALS
KL–12-E Žarko Trpkoski
ENERGY CONSERVATION PROGAM WITH ENVIRONMENTAL
AND ECONOMIC EFFECTS AT TETEKS WOOL TEXTILE FACILITY

АНАЛИТИЧКА ХЕМИЈА И ХЕМИЈА НА ОКОЛИНАТА –

ANALYTICAL AND ENVIRONMENTAL CHEMISTRY
ACE–01-E Nataša Bakreska Kormušoska, Katarina Čundeva, Trajče Stafilov
DETERMINATION OF MANGANES FROM SURFACE WATER
BY ETAAS FOLLOWING FLOTATION PRECONCENTRATION WITH
CHROMIUM(III) ENTAMETHYLENEDITHIOCARBAMATE
ACE–02-E Margarita Ginovska, Hristina Spasevska, Jelena Dimitrijević,
Živko Prelogovski
PROCEDURE FOR ANALYSIS AND TREATMENT OF CONDENSATE
FROM COMPRESSOR SYSTEMS
ACE–03-E Jasmina Dimitrova-Shumkovska, Božidarka Đoshić-Markovska, Sandra
Petkovska, Marieta Shtakleva, Svetlana Stojanoska
EVALUATION OF OXIDATIVE STRESS IN LIVER OF ANIMAL MODEL
EXPOSED TO CHEMICAL CARCINOGEN – 7,12
DIMETHYLBENZ[A]ANTHRACENE
ACE–04-E Liljana Drvoshanova, Aleksandra Nikolova
ADING AD COMPANY PRODUCTION ACTIVITY
ACE–05-E Violeta Ivanova, Goran Milanov, Ana Sarafimovska, Klime Beleski, Marina
Stefova, Trajče Stafilov
HPLC DETERMINATION OF ORGANIC ACIDS IN MACEDONIAN WINES
ACE–06-E Bisera Janeska, Hristina Babunovska, Biljana Sapkareva
VALIDATION OF HEADSPACE GC METHOD FOR DETERMINATION
OF ETHANOL,TOLUEN AND TRICHLOROETHYLEN AS RESIDUAL
SOLVENTS IN CODEINE PHOSPHATE SESQUIHYDRATE
ACE–07-E Valentina Pavlova, Sonja Gadzovska-Simic, Simka Petrovska-Jovanovic
DEVELOPMENT AND OPTIMIZATION OF SPE METHOD FOR
DETERMINATION OF SOME METHYLENEDIOXY AMPHETAMINES IN
URINE
ACE–08-E Valentina Pavlova, Sonja Gadzovska-Simic, Simka Petrovska-Jovanovic
OPTIMISATION OF DERIVATIZATION PROCEDURE FOR ANALYSIS
OF PRIMARY, SECONDARY AND TERTIARY AMINES
ACE–09-E Valentina Pavlova, Katarina Čundeva, Hristina Gajtanovska, Marjana
Mladenovska
HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY METHOD FOR
DETERMINATION OF THEOBROMINE, THEOPHYLLINE AND CAFFEINE
IN COFFEE, CACAO AND TEA
ACE–10-E Milena Taseska, Petre Makreski, Vekoslava Stibilj, Radojko Jaćimović,
Trajče Stafilov, Gligor Jovanovski
DETERMINATION OF TRACE ELEMENTS IN CHALCOPYRITE BY
NEUTRON ACTIVATION ANALYSIS AFTER MATRIX ELEMENTS
SEPARATION
ACE–11-E Milan Antonijević, Zoran Simić, Zorica Petrović
COULOMETRIC-POTENTIOMETRIC DETERMINATION OF ACIDITY OF
HUMIC ACIDS BY APPLICATION SENSORS OF NATURAL SULPHIDE
MINERALS AS SENSORS
ACE–12-E Ceren Bilgin Guney, Fatma Yonsel
ON BOARD CHLORINE GENERATION AS A BALLAST WATER
TREATMENT OPTION
ACE–13-E Mustafa Çelebier, Mustafa Sinan Kaynak, Sacide Altınöz, Selma Sahin
HPLC METHOD DEVELOPMENT FOR THE SIMULTANEOUS ANALYSIS
OF AMLODIPINE BESYLATE AND VALSARTAN IN SAMPLES FOR
LIVER PERFUSION STUDIES
ACE–14-E V. Cibulic, J. Luković
PURIFING CONCEPTION AND CHARACTERISTICS OF WASTE WATER
OF THE PHARMACEUTICAL INDUSTRIES AD "AKTAVIS-ZDRAVLJE"
LESKOVAC
ACE–15-E M. D. Gaye Seye, M. Mbaye, A. Coly, A. Tine, J. J. Aaron
PHOTOCHEMICALLY INDUCED FLUORIMETRIC DETERMINATION OF
(α-CYPERMETHRIN:IMPROVEMENT BY CYCLODEXTRINS
ACE–16-E Zora Grahovac, Snežana S. Mitić, Todor Pecev, Emilija Pecev
DETERMINATION OF INSECTICIDE DIMETHOATE BY KINETIC
METHOD
ACE–17-E Kadrija Hasanovic, Snjezana Maric, Jovan Djukovic, Azra Jaganjac
IDENTIFICATION OF BENZENE AND PRODUCTS OF PHOTOCHEMICAL
DEGRADATION OF BENZENE IN PRESENCE OF OTHER AIR
POLUTANTS IN TUZLA AREA
ACE–18-E Azra Imamovic, Faiza Mustovic, Dragan Kresic, Lejla Klepo, Azra Jaganjac
CHEMICAL ASPECT OF ANTIMICROBIC INFLUENCE MECHANISMS OF
SILVER – IN VITRO –
ACE–19-E Margarita Koleva, Dimitrina Ivanova
INVESTIGATIONS UNDER THE QUALITY OF THE WOOL, RECEIVED
IN ECOLOGICAL METHODS FOR SKINS UNHAIRING
ACE–20-E Ružica Micić, Snežana S. Mitić
TRACE ANALYSIS OF COPPER(II) USING KINETIC-
SPECTROPHOTOMETRIC METHOD
ACE–21-E Dragan M. Milenović, Miodrag L. Lazić, Nada Č. Nikolić,
Zoran B. Todorović,
HPLC-UV ASSAY FOR NIFEDIPINE IN SWAB SAMPLES COLLECTED
FROM PHARMACEUTICAL MANUFACTURING EQUIPMENT SURFACES
ACE–22-E Dragan M. Milenović, Miodrag L. Lazić, Nada Č. Nikolić, Zoran B. Todorović
VALIDATION OF A LIQUID CHROMATOGRAPHIC METHOD FOR
DETERMINATION OF NIFEDIPINE RESIDUES ON STAINLESS STEEL
SURFACES DURING THE MANUFACTURE OF PHARMACEUTICALS
ACE–23-E Vojkan Miljković, Marija Pavlović, Biljana Kaličanin
DETERMINING OF THE LEAD AND CADMIUM CONTENT IN THE
KIDNEYS AND LIVER OF RATS
ACE–24-E Snežana S. Mitić, Gordana Ž. Miletić, Aleksandra N. Pavlović
DETERMINATION OF ACETYLSALICYLIC ACID BASED
ON "LIGAND-EXCANGE" REACTION
ACE–25-E Violeta Mitic, Marija Markovic, Dragana Pavlovic-Muratspahic, Vesna
Stankov-Jovanovic, Snezana Nikolic-Mandic
HEAVY METALS DISTRIBUTION IN TWO PLANT SPECIES GROWING IN
BURNT AND UNBURNT SOILS FROM THE VIDLIC MOUNTAIN
ACE–26-E Aleksandra N. Pavlović, Snežana S. Mitić, Gordana Ž. Miletić
QUANTITATIVE ANALYSIS OF ACETYLSALICYLIC ACID
IN COMMERCIAL DOSAGE FORMS AND HUMAN CONTROL SERUM
ACE–27-E Alexander Petrov, Galia Gentscheva, Ivan Havezov, Elisaveta Ivanova
UNCERTAINTY BUDGET OF THE FLAME ATOMIC ABSORPTION
SPECTROMETRIC DETERMINATION OF Co, Ni, Cu, Cd AND Pd IN
WATERS AFTER PRECONCENTRATION WITH 2-NITROSO-1-NAPHTOL
ACE–28-E Pavleta Petrova, Sonja Arpadjan-Ganeva
PASSIVE SAMPLING SYSTEMS FOR ESTIMATION OF WATER
POLLUTION AROUND COAL BURNING POWER PLANTS
ACE–29-E Snežana B. Tošić, Snežana S. Mitić, Aleksandra N. Pavlović
DETERMINATION OF DIAZEPAM BY KINETIC SPECTROPHOTOMETRY
ACE–30-E Todorka Vladkova
SURFACE MODIFICATION APPROACH TO NON-TOXIC BIOFOULING
CONTROL
ACE–31-E Valentina Živanović, Renata Kovačević, Gordana Milovanović
DETERMINATION OF Mn IN MORAVICA ACCUMULATION WATER BY
ICP-AES
ACE–32-E Ljupka Arsova, Isak Marcetic, Aleksandar Lozajic, Jan Vanek,
Vojtech Musil
BIOREMEDIATION OF SOIL CONTAMINATED BY OIL DERIVATIVES AT
THE LOCATION OF NIS PETROL - OIL RAFINERY IN NOVI SAD
ПРЕХРАНБЕНА ТЕХНОЛОГИЈА И БИОТЕХНОЛОГИЈА –
BIOTECHNOLOGY AND FOOD TECHNOLOGY
BFT–01-E Mirjana Bocevska, Danica Andreevska, Verica Ilievska, Imad Aldabas
EFFECT OF DEGREE OF MILLING ON PROTEIN CONTENT
IN FRACTIONS OF THREE RICE CULTIVARS
BFT–02-E Mirjana Bocevska, Vlado Samardjioski, Stojan Rendevski, Bozidar Ristovski
DIELECTRIC AND UV SPECTROSCOPY FOR DEEP FRYING OIL
QUALITY MONITORING
BFT–03-E Eleonora Winkelhausen, Elena Veličkova, Samuel A. Amartey, Slobodanka
Kuzmanova
BIOFUEL PRODUCTION BY YEASTS AND BACTERIA
BFT–04-E Darko Dimitrovski, Charlotte van Twisk, Matthijs Dekker, Dane Bicanic
COLORIMETRIC APPROACH TO QUANTIFICATION OF β-CAROTENE IN
MANGO
BFT–05-E Donka Doneva-Sapceska, Igno Tasev, Silvija Trpkovska, Goran Bojadziski,
Aco Dimitrovski
THE INFLUENCE OF ENOLOGICAL TANNINS ON THE COLOR OF THE
RED WINE VRANEC
BFT–06-E Sonja Gadzovska-Simic, Stephane Maury, Valentina Pavlova, Alain
Delaunay, Mirko Spasenoski, Claude Joseph, Daniel Hagège
PHENYLPROPANOID PRODUCTIONS IN HYPERICUM PERFORATUM L.
IN VITRO CULTURES
BFT–07-E Sonja Gadzovska-Simic, Kristina Savreska, Oliver Tusevski, Natasa
Brndevska, Valentina Pavlova, Mirko Spasenoski
EFFECTS OF SALICYLIC ACID ON PHENYLPROPANOID
PRODUCTIONS IN CALENDULA OFFICINALIS L.IN VITRO SHOOTS
BFT–08-E Sonja Gadzovska-Simic, Oliver Tusevski, Natasa Brndevska,
Valentina Pavlova, Natalija Atanasova-Pancevska, Djoko Kungulovski,
Mirko Spasenoski
EFFECTS OF FUNGAL ELICITOR ASPERGILLUS FLAVUS ON
PHENYLPROPANOID PRODUCTIONS IN HYPERICUM PERFORATUM L.
CELL SUSPENSIONS
BFT–09-E Irina Mladenoska, Daniela Nikolovska-Nedelkoska, Eleonora Winkelhausen,
Slobodanka Kuzmanova
INFLUENCE OF TEMPERATURE ON THE DONOR SELECTIVITY
OF NATIVE AND IMMOBILIZED ASPERGILLUS ORYZAE
β-GALACTOSIDASE
BFТ–10-E Daniela Nikolovska Nedelkoska, Irina Mladenoska, Eleonora Winkelhausen,
Slobodanka Kuzmanova
IMMOBILIZATION OF ASPERGILLUS ORYZAE β-GALACTOSIDASE FOR
EFFICIENT USE IN ORGANIC MEDIUM
BFТ–11-E Juliane Petrovska, Aco Dimitrovski
MICROBIOLOGICAL MONITORING OF WATER – SELECTIVE
ENUMERATION OF THE INDICATOR-MICROORGANISMS:
TOTAL/FAECAL COLIFORMS AND E. COLI BACTERIA
BFT–12-E Marija Srbinoska, Breda Simonovska, Irena Vovk, Kiril Filiposki
LUTEIN CONTENT IN FLOWERS OF TAGETES PATULA L. AND
TAGETES ERECTA L.
BFТ–13-E Julijana Tomovska, Bogdan Bogdanov
INITIATION OF METHOD FOR DETERMINATE ENZIMATYC ACTIVITY
ON ANGIOTENZIN CONVERTING ENZIME (ACE) IN WHEY
BFТ–14-E Maja Shishovska, Vera Trajkovska, Zorica Arsova-Sarafinovska,
Katerina Starkoska, Sandra Atanasovska
HPLC/DAD DETERMINATION OF PERMETHRIN RESIDUES IN WINE
BFT–15-E Slavica B. Ilić, Sandra S. Konstantinović, Dragiša S. Savić,
Vlada B. Veljković, Miodrag L. Lazić, Gordana Gojgić-Cvijović
ANTIBIOTIC PRODUCTION BY STREPTOMYCES HYGROSCOPICUS
ON MODIFIED MEDIA WITH ISATIN-3-THIOSEMICARBAZONE
COMPLEXES
BFT–16-E Zoran Jovanovic, Vesna Stankov-Jovanovic, Snezana Nikolic-Mandic,
Violeta Mitic, Radisav Mitic
ENZYME INHIBITON BASED ASSAY FOR MAPROTILIN
DETERMINATION IN PHARMACEUTICALS
BFT–17-E Sandra S. Konstantinović, Blaga C. Radovanović, Vanja S. Cakić,
Slavica B. Ilić
ANTIMICROBIAL ACTIVITY OF SOME ISATIN SCHIFF BASES
BFT–18-E Ida Leskosek-Cukalovic, Slavica Jelacic, Viktor Nedovic, Sasa Despotovic
BEER WITH THYME AND OREGANO-BEVERAGE WITH
FARMACODYNAMIC PROPERTIES
BFT–19-E Verica Manojlovic, Radoslava Stojanovic, Nikos Agouridis, Branko Bugarski,
Ida Leskosek-Cukalovic, Maria Kanellaki, Viktor Nedovic
IMMOBILIZED YEAST IN PVA/ALGINATE BEADS AIMED FOR BEER
PRODUCTION
BFT–20-E Viktor Nedovic, Verica Manojlovic, Ida Leskosek-Cukalovic, Branko Bugarski
IMMOBILIZED CELL SYSTEMS FOR FERMENTATION PROCESSES
BFT–21-E Blaga Radovanovic, S. Mitic, D. Kostic, M. Conic
TOTAL POLYHENOLS, ANTHOCYANINS AND FREE RADICAL
SCAVENGING OF SOME RED GRAPES VARIETIES FROM SOUTH
SERBIA
BFT–22-E Olivera Stamenković, Vlada Veljković, Zoran Todorović, Miodrag Lazić,
Dejan Skala
THE PREPARATION AND CATALYTIC ACTIVITY OF CALCIUM OXIDE IN
THE SUNFLOWER OIL METHANOLYSIS REACTION
BFT–23-E I. Stanisavljević, D. Veličković, M. Lazić, V. Veljković
THE ULTRASOUND EXTRACTION OF OIL FROM TOBACCO
(NICOTIANA TABACUM L.) SEEDS
BFT–24-E Snežana Trmčić
NUTRITIVE VALUE OF WHITE WINES
BFT–25-E Snežana Trмčić, Zoran Rajić, Dušan Milić, Branka Kalanović, Bojan
Dimitrijević
THE IMPACT OF PACKAGING COSTS ON BUSINESS RESULTS IN
WINE PRODUCTION
BFT–26-E Snežana Trmčić, Zoran Rajić, Dragić Živković, Dušan Milić
THE PLACE AND ROLE OF THE ECONOMIC MODELS IN REVIEW AND
IMPROVEMENT OF THE BUSINESS RESULTS
ХЕМИСКО ИНЖЕНЕРСТВО – CHEMICAL ENGINEERING
CHE–01-E Slavcho A. Aleksovski
ISOLATION OF ESSENTIAL OIL FROM FOENICULUM VULGARE
CHE–02-E Slavcho A. Aleksovski
COMPARISON OF ESSENTIAL OIL COMPOSITION OF CARUM CARVI L.
OBTAINED BY HYDRODISTILLATION AND SOXHLET EXTRACTION
METHODS
CHE–03-M Aleksandar Anastasovski
MASS PINCH TECHNOLOGY – POSSIBLE TOOL FOR WASTE WATER
TREATMENT SYSTEMS OPTIMISATION
CHE–04-E Balalovska -Gekic Gordana
QUALITY OF DIESEL PRODUCED BY OKTA
CHE–05-E Zoran Bozinovski, Dejan Dimitrovski, Kostadin Nikolovski
REMOVING THE ARSENIC FROM POTABLE WATERS BY THE USE OF
FERRIC/FERROUS-ORIGIN COAGULANTS AND FLOCCULANTS
CHE–06-E Jovica Georgijev, Nadija Al Asadi
REVAMP OF THE ISOMERIZATION UNIT
CHE–07-E Gligor Denkovski
ACCREDITING OF THE LABORATORY – THEORY AND PRACTICE
CHE–08-E Dejan Dimitrovski, Zoran Bozinovski; Kostadin Nikolovski
REMOVAL OF NICKEL IONS FROM AQUEOUS SOLUTIONS WITH
ADSORPTION ON NATURAL ZEOLITES
CHE–09-Е Toni Zikovski
PRODUCTION OF DIESEL WITH 10 ppm S
CHE–10-Е Mirko Marinkovski, Radmila Tomovska, Radek Fajgar
UV LASER PREPARATION AND CHARACTERIZATION OF TiO2 BASED
PHOTOCATALYSTS CONTAINING SiO2
CHE–11-Е Mirjana Minceva, Julija Taparcevska, Liljana Markovska, Vera Meshko
2+
DIFUSION MODELS FOR ADSORPTION KINETICS OF Pb ONTO
NATURAL ZEOLITE
CHE–12-Е Mirjana Minceva, Julija Taparcevska, Liljana Markovska, Vera Meshko
2+
SINGLE COMPONENT ADSORPTION OF Pb BY NATURAL ZEOLITE
CHE–13-Е Aleksandar Sokolovski
SULPHUR RECOVERY UNIT
CHE–14-Е Suzana Crvenkova
SOUR WATER STRIPPER UNIT
CHE–15-Е Mirko Aleksić, Ivana Banković-Ilić, Miodrag Lazić, Vlada Veljković,
Dejan Skala
SPECIFIC INTERFACIAL AREA IN A RECIPROCATING PLATE COLUMN
WITH RASHIG RINGS PLACED IN INTERPLATE SPACES
CHE–16-Е Ivana Banković-Ilić, Ivica Stamenković, Olivera Stamenković,
Vlada Veljković, Miodrag Lazić
MODELING THE KINETICS OF VEGETABLE OIL METHANOLYSIS
REACTION
CHE–17-Е Bogdan Bonev, Milka Boneva, Angel Komarev
APPLICATION OF THE REVERSE OSMOSIS PROCESS FOR TREATING
GROUND WATERS OF HIGH MINERAL CONTENT FOR THE
HOUSEHOLD WATER NEEDS OF TPP ENEL MARITZA EAST 3
CHE–18-Е Bogdan Bonev, V. Nenov
COPPER RECOVERY FROM COPPER LOADED ION-EXCHANGERS
CHE–19-Е Goran Boskovic, Marijana Kovacevic, Sanja Ratković, Paula Putanov
FAVORABLE Pd-SnO2 ENTITIES FOR WATER DENITRATION
REACTION
CHE–20-Е Christo B. Boyadjiev
DIFFUSION MODELS OF COLUMN APPARATUSES AND SCALE – UP
CHE–21-Е Sead Hrustanović, Tatjana Lučić, Azra Jaganjac
DIOXIN EMISSIONS IN INDUSTRIES
CHE–22-Е Sead Hrustanović, Tatjana Lučić, Azra Jaganjac
POSSIBILITY OF FLUE GAS DESULFURIZATION (FGD) –GYPSUM USE
FOR VARIOUS PRODUCTS
CHE–23-Е M. Karsheva, S. Georgieva
FLOW BEHAVIOUR DURING FORMULATION OF COSMETIC OIL JELS
BASED ON THE NATURAL AND SYNTHETIC UV-PROTECTION
COMPONENTS
CHE–24-Е Ana Marjanović, Olivera Stamenković, Vlada Veljković, Zoran Todorović,
Miodrag Lazić, Dejan Skala
THE BASE CATALYZED ETHANOLYSIS OF SUNFLOWER OIL
CHE–25-Е Krasi Panayotova, Maria Doichinova, Christo Boyadjiev
ON THE SCALE EFFECT AND SCALE-UP IN COLUMN APPARATUSES
1. INFLUENCE OF THE VELOCITY DISTRIBUTION
CHE–26-Е Krasi Panayotova, Maria Doichinova, Christo Boyadjiev
ON THE SCALE EFFECT AND SCALE-UP IN COLUMN APPARATUSES
2. SCALE EFFECT MODELING
CHE–27-Е Petya Popova, Christo Boyadjiev
ON THE MODELING OF FERMENTATION SYSTEMS
CHE–28-Е Olivera Stamenković, Vlada Veljković, Zoran Todorović, Miodrag Lazić,
Dejan Skala
PREPARATION AND CATALYTIC ACTIVITY OF CaO IN OIL
METHANOLYSIS REACTION
CHE–29Е Marija B. Tasić, Vlada B. Veljković,
BENCH-SCALE SIMULATION OF STARCH ACID HYDROLYSIS
PROCESS
CHE–30-Е Dragan Tošković, Časlav Lačnjevac, Miloš B. Rajković, Dušan Stanojević,
Miladin Gligorić, Aleksandar Marinković, Nebojsa Ralevic
EXTRACTION OF GALLIUM FROM DECOMPOSED BAYER’S ALKALINE
SOLUTIONS USING MODIFIED CHELATE RESINS
CHE–31-Е Vlada Veljković, Olivera Stamenković, Zoran Todorović, Miodrag Lazić,
Dejan Skala
BARIUM HYDROXIDE AS A CATALYST IN THE SUNFLOWER OIL
METHANOLYSIS REACTION
CHE–32-Е Aleksandra Zarubica, Goran Boskovic
Pt-Nb AND Pt-Re DOUBLY MODIFIED SULFATED ZIRCONIA – BASED
CATALYSTS

ЕЛЕКТРОХЕМИЈА – ELECTROCHEMISTRY
ECH–01-Е Lasko Basnarkov, Lihnida Stojanovska-Georgievska, Cosimo Ancora,
Margarita Ginovska, Giampiero Ruani, Hristina Spasevska
EQUIVALENT CIRCUIT ANALYSIS OF TiO2/CuInS2 SOLAR CELLS
ECH–02-E Marija Davčeva, Valentin Mirčeski
STUDYING HOMOGENEOUS REDOX REACTIONS OF BIOCHEMICAL
IMPORTANCE WITH VOLTAMMETRIC METHODS. GLUTATHIONE
OXIDATION
ECH–03-M Ирена Мицкова, Љубомир Арсов,
СТРУКТУРНИ ИСТРАЖУВАЊА НА АНАТАЗНАТА ФОРМА НА
ТИТАНОВИ ОКСИДИ
ECH–03-E Irena Mickova, Ljubomir Arsov
STRUCTURAL STUDY THE FORM ANATASE OF TITANIUM OXIDES
ECH–04-M Ирена Мицкова, Абдурауф Пруси
ПОЛУПРОВОДНИЧКИ СВОЈСТВА НА ТЕРМИЧКИ ФОРМИРАНИ
НИОБИУМОВИ ОКСИДИ
ECH–04-E Irena Mиckova, Abduaruf Prusi
SEMICONDUCTING PROPERTIES OF THERMALLY FORMED NIOBIUM
OXIDES
ECH–05-E Perica Paunovic, Dragan Slavkov, Toma Gligorivski, Aleksandar Dimitrov,
Svetomir Hadži Jordanov
GALVANIC CORROSION OF HOT-DEEP ZINC PLATED PIPES IN A HOT
WATER RECIRCULATION SYSTEM
ECH–06-E Orce Popovski, Perica Paunović, Ana Tomova, Rose Smileski, Aleksandar
Dиmitrov, Svetomir Hadži Jordanov
ELECTRODEPOSITION OF METALLIC PHASE ON POROUS
ELECTROCATALYST SUPPORT
ECH–07-E Orce Popovski, Ana Tomova, Perica Paunović, Dragan Slavkov,
Aleksandar Dimitrov, Bogdan Ranguelov, Veselin Tonchev,
Svetomir Hadži Jordanov
MORPHOLOGY OF SILVER NANO-POWDER PRODUCED BY
PULSATING ELECTRODEPOSITION
ECH–08-E Mimoza M. Ristova, Valentin Mirceskи, Ratka Neskoska, Metodija Najdoski,
Ivan Drangov
ZnO:In AND TiO2 COATING ON ELECTROHROMIC Cu2O FILMS FOR
VOLTAGE CYCLING LIFETIME IMPROVEMENT
ECH–09-E Birhan Sefer, Valentin Mirceski, Kurt Kalcher
CARBON ELECTRODES MODIFIED WITH CARBON NANOTUBES FOR
THE DETERMINATION OF HYDROGEN PEROXIDE
ECH–10-E Filip Spasovski, Valentin Mirčeski
ELECTROCHEMICAL STUDY OF ClO4- ION TRANSFER KINETICS
ACROSS STEROL MEMBRANE SUPPORTED AT THE WATER|
2-NITROPHENYLOCTYL ETHER INTERFACE BY MEANS OF THIN FILM
ELECTRODES
ECH–11-Е Ljiljana Gajić-Krstajić, Nevenka Elezović, Ljiljana Vračar, Nedeljko Krstajić
KINETICS OF THE HYDROGEN OXIDATION N THE PRESENCE
OF THE CARBON MONOXIDE AT Pt/C ELECTRODE
ECH–12-Е Kurt Kalcher, Birhan Sefer, Petr Kotzian, Sabina Begic, Emir Turkusic,
Karel Vytras
HETEROGENEOUS CARBON ELECTRODES
ECH–13-Е Šebojka Komorsky-Lovrić Boris-Marko Kukovec, Zora Popović, Vlasta
Vojković, Marijana Vinković
SYNTHESIS AND CHARACTERIZATION OF COBALT COMPLEXES
WITH 3- AND 6-METHYLPICOLINIC ACID; SPECTROPHOTOMETRIC
STUDY OF COMPLEXES IN SOLUTION
ECH–14-Е A. Kowal, M. Kopczyk, A. Cuesta, C. Gutierrez, J. Marco
PREPARATION OF HIGHLY DOPED TIN DIOXIDE POLYCHRYSTALLINE
LAYERS AND CHARACTERIZATION BY USE OF EERS, XPS AND AFM
ECH–15-Е Milivoj Lovrić, Šebojka Komorsky-Lovrić
A DISTRIBUTION OF REACTANT CONCENTRATION AT THE SURFACE
OF AN INLAID SENSOR UNDER HYDRODYNAMIC CONDITIONS
ECH–16-E Ljubica J. Pavlović, Miomir G. Pavlović, Borka M. Jović,
Vesna M. Maksimović
ELECTRODEPOSITION AND MORPHOLOGY OF IRON POWDER BY
CONSTANT CURRENTS
ECH–17-Е Miomir G. Pavlović, Miladin Gligorić, Miroslav M. Pavlović,
Ljubica J. Pavlović, Milorad V. Tomić, Nebojša D. Nikolić
SOME QUESTIONS ABOUT MORPHOLOGY AND STRUCTURE
OF ELECTRODEPOSITED METAL COATINGS
ECH–18-E Jasna Stevanović, Jasna Stajić-Trošić, Vladan Ćosović, Olivera Pešić,
Branka Jordović
CHARACTERIZATION OF TERNARY CO-NI-MO ALLOY POWDERS
OBTAINED BY ELECTROCHEMICAL DEPOSITION FROM ALKALINE
ELECTROLYTE
ECH–19-E Jasna Stevanović, Jasna Stajić-Trošić, N.Talijan, A.Grujić, J. Popić
ELECTROCHEMICAL DEPOSITION OF POW DER OF TERNARY CO-NI-
MO ALLOY FROM ALKALINE ELECTROLYTE ..................................................... 223
ECH–20-E İncilay Süslü, Nuran Özaltın, Sacide Altınöz
VOLTAMMETRIC DETERMINATION OF CANDESARTAN CILEXETIL BY
COMPLEX FORMATION WITH CU (II)
ECH–21-E Milorad V. Tomić, Ljubica J. Pavlović, Miomir G. Pavlović, Dušan Stanojević,
Milovan Jotanović
AN ELECTRON MICROSCOPE INVESTIGATION OF ELECTROLYTIC
SILVER POWDERS
ECH–22-Е Dragan Tošković, Časlav Lačnjevac, Miloš B. Rajković, Dušan Stanojević,
Dragica Čamovska
STUDY OF CORROSION RESISTANCE OF CHROMIUM-NICKEL
STEELS IN CALCIUM-HYPOCHLORITE SOLUTION
ECH–23-E B. B. Vukanović, M. V. Budimir, R. P. Mihajlović, M. V. Vukanović,
M. P. Gavrilović
EFFECT OF LIGAND 1,10-PHENANTROLIN ON THE REDOX REACTION
OF METAL IONS AND ITS POTENTIOMETRIC DETERMINATION BY
PYRITE ELECTRODE
НАСТАВА – EDUCATION
EDU–01-Е Rajna Bogeska, Blagica Cekova, Vera Andonovska
PROJECTS GRADING CRITERIA
EDU–02-E Violeta Solakova, Blagica Cekova, Rajna Bogeska, Filimena Karafiljkovska
APPLICATION OF THE ACTIVITY – RESEARCH PROCESS IN THE
EDUCATION
EDU–03-M Blagica Cekova, Violeta Solakova, Rajna Bogeska
APPLICATION OF THE ACTIVITY – FORMATIVE AND SUMMATIVE
EVALUATION IN THE EDUCATIONAL PROCESS
EDU–04-E Sasho Guergov
A METHOD FOR DESIGN OF RECONFIGURABLE MULTIFUNCTIONAL
MACHINE TOOLS
EDU–05-E Oriade Olateju. A., Ehimen Joy, James Musa Jeb, Okoro Loveth, Oriade
Oluwasegun Benjamin, Ibrahim Mercy Idowu, Akinlolu Michael
THE EFFECT OF INFORMATION TECHNOLOGY (I.C.T) AND IT’S
RELEVANCE IN THE SECURITY WORLD
EDU–06-E Małgorzata Szafarska, Renata Wietecha-Posłuszny, Michał Woźniakiewicz,
Paweł Kościelniak
JUSTICE ABOVE ALL ELSE – ANALYTICAL CHEMISTRY
IN A FORENSIC COSTUME

НЕОРГАНСКА ХЕМИЈА И ТЕХНОЛОГИЈА –

INORGANIC CHEMISTRY AND TECHNOLOGY
ICT–01-E Ranko Adžiski, Emilija Fidančevska, Vojo Jovanov, Venceslav Vassilev
APPLICATION OF THE POLYFACTOR EXPERIMENT DESIGN IN THE
COURSE OF COMBUSTION OF RICE HUSK TO AMORPHOUS SILICA
ICT–02-E Vojo Jovanov, Snezana Petrovic, Emilija Fidancevska, Janja Ranogajec,
Biljana Anguseva, Sinisa Markov
BIOCORROSION OF CERAMICS FABRICATED FROM WASTE FLY ASH
AND CLAY
ICT–03-M Благој Павловски, Агрон Река,
ИСПИТУВАЊА НА МИНЕРАЛОШКИОТ СОСТАВ НА ВРЗИВНАТА
КОМПОНЕНТА КАЈ ВАР-ТРЕПЕЛНИ КЕРАМИЧКИ ПРОИЗВОДИ
ДОБИЕНИ ПО ХИДРОТЕРМАЛНА ПОСТАПКА
ICT–03-E Blagoj Pavlovski, Agron Reka,
RESEARCH OF MINERALOGICAL COMPOSITION OF BINDING
MATERIAL IN LIME-TRIPOLI CERAMIC PRODUCTS OBTAINED BY
HYDROTHERMAL TREATMENT
ICT–04-M Билјана Пејова, Иван Грозданов, Диана Нешева, Ана Петрова
СТРУКТУРА И ОПТИЧКИ СВОЈСТВА НА ТРОДИМЕНЗИОНАЛНИ
ГРУПАЦИИ ОД КВАНТНИ ТОЧКИ НА AgBiS2: XRD, AFM И UV-VIS-NIR
СТУДИЈА
ICT–04-E Biljana Pejova, Ivan Grozdanov, Diana Nesheva, Anna Petrova
STRUCTURE AND OPTICAL PROPERTIES OF 3D ASSEMBLIES OF
AgBiS2 QUANTUM DOTS: XRD, AFM AND UV-VIS-NIR STUDY
ICT–05-E Blagica Cekova, Dragi Kocev, Elena Kolcakovska
SYNTHESIS AND CHARACTERIZATION OF THE ZEOLITE ZSM-20
ICT–06-E Lilia Aljihmani, Venceslav Vassilev, Temenuga Hristova-Vasileva,
Emilija Fidancevska
NEW CHALCOGENIDE GLASSES FROM THE As2Se3-Ag4SSe-CdTe
SYSTEM
ICT–07-E Milica Hadnadjev, Dmitar Zoric, Radmila Marinkovic-Neducin,
Eva Loncar, Jonjaua Ranogajec
CHARACTERISTICS OF SELF-CLEANING TiO2 COATING ON CLAY
ROOFING TILES
ICT–08-E Ljubiša Mišić, Saša Ivanović, Dragan Marković, Tatjana Apostolovski-Trujić
HIGH TEMPERATURE RESISTANCE VESSELS PRODUCTION FOR
FIRE ASSAYING ANALYSES
ICT–09-E N. Štrbac, I. Mihajlović, D. Minić, D. Živković, B. Andjelić
THERMODYNAMIC AND KINETIC INVESTIGATIONS OF ROASTING
PROCESS OF COPPER CONCENTRATE WITH HIGHTER CONTENT OF
ARSENIC AND MERCURY
ICT–10-E Anja M. Terzic, Ljubica M. Pavlovic
INFLUENCE OF ADDITIVES ON PROPERTIES, MICROSTRUCTURE
AND PHASE-FORMATION OF CORUNDUM BASED REFRACTORY
CONCRETE
ICT–11-E Miloš Vasić, Milica Arsenović, Zagorka Radojević, Đorđe Janačković,
THE INFLUENCE OF MECHANICAL ACTIVATION ON CHARACTERISTIC
AND PROPERTIES OF MASONORY PRODCUTS
ICT–12-E Venceslav Vassilev, Lilia Aljihmani, Temenuga Hrisova-Vasileva
PHASE EQUILIBRIA IN THE GeSe2-Ag4SSe SYSTEM
ICT–13-E Venceslav Vassilev, Gergo Vassilev, Julita Dikova
PREPARATION AND PROPERTIES OF MULTICOMPONENT GeSe2-
Sb2Se3-AgI GLASSES
ICT–14-E Biljana Zlaticanin, Mirjana Filipovic
THE EFFECT OF TITANIUM CONTENTS ON THE STRUCTURE OF THE
Al-5wt. %Cu-5wt. %Mg ALLOY
ICT–15-E H. Ben Abdullah, Raouf Bennaceur
FIRST-PRINCIPLES CALCULATIONS OF THE ELECTRONIC AND
OPTICAL PROPERTIES OF In6S7 COMPOUND

ПОЛИМЕРИ И ПОЛИМЕРНИ МАТЕРИЈАЛИ – POLYMERS AND

POLYMER MATERIALS
PPM–01-Е Emilija Bajraktarova-Valjakova, Anita Grozdanov, Bona Bajraktarova ,
Elena Petkova
INTERFACE CHARACTERIZATION OF THE PORCELAIN/COMPOSITE
DENTAL SYSTEM IN THE RESTORATIVE DENTISTRY
PPM–02-E Jadranka Blaževska-Gilev, Jozef Pola
IR LASER ABLATION OF POLY(VINYL CHLORIDE-CO-VINYL ACETATE)
PPM–03-E Jadranka Blaževska-Gilev, Jozef Pola
IR LASER ABLATION OF POLY(VINYL ACETATE) LOADED WITH
METAL PARTICLES
PPM–04-E Jadranka Blaževska Gilev, Dijana Spaseska
COMPARATIVE STUDY OF REPROCESSING AND RECYCLING OF
POLY(VINYL CHLORIDE) AND POLY(VINYL CHLORIDE-CO-VINYL
ACETATE)
PPM–05-E Vesna Daniloska, Jadranka Blaževska-Gilev, Vesna Dimova, Radmila
Tomovska
UV LIGHT INDUCED SURFACE MODIFICATION OF LLDPE FILMS WITH
BIOACTIVE COMPOUNDS
PPM–06-M Бојан Димзоски, Gennaro Gentile, Maurizio Avella, Гордана Богоева-
Гацева
ДОБИВАЊЕ И СВОЈСТВА НА ЕКО-ПРИЈАТЕЛСКИ ПОЛИМЕРНИ
КОМПОЗИТИ
PPM–06-E Bojan Dimzoski, Gennaro Gentile, Maurizio Avella,
Gordana Bogoeva-Gaceva
PREPARATION AND PROPERTIES OF ECO-FRIENDLY POLYMER
COMPOSITES
PPM–07-E Bojan Dimzoski, Slobodan Prendžov, Magdalena Prendžova
PHYSICAL-MECHANICAL PROPERTIES OF POLYURETHANE FOAMS
SYNTHESIZED USING DIFFERENT TYPE OF POLYOLS
PPM–08-Е Todor Gavrilov, Ilco Gjuroski
CHARACTERIZATION OF RECYCLATES OF POLYETHYLENE’S FILMS
AND THEIR BLENDS
PPM–09-E Anita Grozdanov, Biljana Petrusevska, Aleksandra Buzarovska,
Vesna Panova
PROCESSING OF COMPOSITES BASED ON WOOD FLOUR AND
PHENOLIC RESIN
PPM–10-E Rubén Darío Betancourt Cortés, Milena Avramović, Miloš Milovanović,
Lynne Katsikas, Ivanka G. Popović
INCREASED THERMAL STABILITY OF POLY(METHYL
METHACRYLATE) PREPARED BY THE RAFT MECHANISM
PPM–11-E Peter Dineff, Dilyana Gospodinova, Lydia Kostova, Todorka Vladkova,
Chen Erfan
NEW ATTEMPT AT PLASMA AIDED FLAME RETARDATION IN WOOD
AND CELLULOSIC FIBROUS MATERIALS
PPM–12-E Strashimir Djoumaliisky, Georgi Kotzev, Tatjana Dobreva
PROCESSING AND PROPERTIES OF POLYPROPYLENE/CARBON
BLACK CONDUCTIVE COMPOSITES
PPM–13-E Enis S. Džunuzović, Milena Marinović-Cincović, Katarina Jeremić, Jovan
Nedeljković
PREPARATION AND CHARACTERIZATION OF PMMA /α-Fe2O3
NANOCUBES COMPOSITE
PPM–14-E Valentin Gaydarov, Galina Zamfirova, Rosario Benavente, María L. Cerrada,
José M. Pereña
MICROHARDNESS INVESTIGATION OF DIFFERENT TYPES OF
POLYPROPYLENE AND THEIR BLENDS WITH ETHYLENE-OCTENE
COPOLYMERS
PPM–15-E Nina Hauptman, Marta Klanjšek Gunde, Marijan Maček,
Marija Bešter Rogač
ELECTRICAL PROPERTIES OF EPOXY–BASED CARBON BLACK
NANOCOMPOSITE AND ITS TECHNOLOGICAL RELIABILITY
PPM–16-E Rumiana Kotsilkova, Boryana Milosheva, Evgeni Ivanov,
Ekaterina Krusteva, Antonia Topliyska
POLYMER NANOCOMPOSITES FOR STRUCTURAL APPLICATION.
DESIGN, SYNTHESIS AND CHARACTERIZATION
PPM–17-E Rosa Mateva, Svetlana Petrova, I. Iliev
SYNTHESIZES AND PROPERTIES OF BIODEGRADABLE AND
BIOCOMPATIBLE BLOCK COPOLYMERS OF PEG AND CLO
PPM–18-E Rosa Mateva, Kr. Zhilkova, Galina Zamfirova, R. Díaz-Calleja,
A. Garcia-Bernabé
BLOCK COPOLYMERS OF ξ-HEXANOLACTAM AND (-DODECALACTAM
WITH AN ELASTIC POLYPROPYLENEOXIDE BLOCK. STRUCTURE –
PREOPERY RELATIONSHIPS
PPM–19-E Kamelija Ruskova, Nikolaj Dishovsky
CONSTANT MAGNETIC FIELD INFLUENCE ON THE VULCANIZATION
OF UNFILLED RUBBER BASED BLENDS
PPM–20-E Todorka Vladkova, Ivan Keranov, Petar Dineff
NEW POSSIBILITIES TO PDMS SURFACE MODIFICATION
PPM–21-E Jasna Vuković, Slobodan Jovanović, Manfred D. Lechner
SYNTHESIS AND CHARACTERIZATION OF ALIPHATIC
HYPERBRANCHED POLYESTERS
PPM–22-E Lyubov Yotova, Svetlana Petrova, Tzvetan Velinov, Rosa Mateva
AMPHIPHILIC BIODEGRADABLE-BIOCOMPATIBLE BLOCK
COPOLYMERS ON THE BASE OF POLY(ETHYLENEGLYCOL-CO-
CAPROLACTONE)
PPM–23-E Darina Zheleva
INVESTIGATION OF TYPE CARBON BLACK ON THE STEARIC ACID
DISPERSION EFFECT IN FILLED RUBBER BLENDS
PPM–24-E Miltcho Natov, Stefanka Vassileva, Margita Natova
ON THE CHEMICAL INTERACTIONS BETWEEN
POLY(UNDETANEAMIDE) AND POLY(BUTADIENE-CO-
ACRYLONITRILE) DURING REACTIVE EXTRUSION

СПЕКТРОСКОПИЈА, ОРГАНСКА И СТРУКТУРНА ХЕМИЈА –

SPECTROSCOPY, ORGANIC AND STRUCTURAL CHEMISTRY
SOSC–01-E Slobotka Aleksovska, Igor Kuzmanovski, Sandra Dimitrovska-Lazova
STRUCTURAL CORRELATIONS IN CUBIC AND HEXAGONAL
PEROVSKITES OF A2+(B′2+0,33B″5+0,67)O3 TYPE USING MULTIPLE
LINEAR REGRESSION AND ARTEFICIAL NEURAL NETWORKS
SOSC–02-E Jane Bogdanov
STEREOCHEMISTRY OF NUCLEOPHILIC ADDITION TO CARBONYL
GROUPS OF SPIROKETONES
SOSC–03-E Jane Bogdanov
SYNTHESIS AND CHARACTERIZATION OF NEW SYMMETRICALLY
SUBSTITUTED 2,7-DIMETHYLNAPHTHALENE DERIVATIVES
SOSC–04-E Jane Bogdanov
THEORETICAL STUDIES ON MONOSUBSTITUTED 2,7-DIMETHYL-
APHTHALENE DERIVATIVES AND THEIR RADICAL ANIONS
SOSC–05-E Jane Bogdanov, Menče Najdoska, Brankica Veličkovski
ISOLATION AND ANALYSIS OF THE ESSENTIAL OIL FROM FOENICULI
FRUCTUS
SOSC–06-E Vesna Dimova, Nada Perisic-Janjic
SOLVENT AND SUBSTITUENT EFFECTS ON THE ELECTRONIC
-1
SPECTRA OF N -ARYL/HETEROARYLAMINO/METHYL/ETHYL-1,2,4-
TRIAZOLES
SOSC–07-E Vesna Dimova, Nada Perisic-Janjic
QSAR STUDY ON INHIBITION OF B. SUBTILIS, E. COLI AND S.
ENTERITIDIS BY 1,2,4-TRIAZOLES: PHYSICOCHEMICAL APPROACH
USING SURFACE TENSION, REFRACTIVE INDEX, DENSITY AND
POLARIZABILITY
SOSC–08-E Vladimir Ivanovski, Miha Bukleski
IR SPECULAR REFLECTANCE SPECTRA OF ALUMS OBTAINED FROM
POWDERED SAMPLES – DISPERSION ANALYSIS
SOSC–09-M Ахмед Јашари, Агим Шабани, Муртезан Исмаили, Кристина
Младеновска,
Луминита Силагхи-Думитреску, Божана Михова, Емил Поповски
РЕАКЦИИ НА 4-ХИДРОКСИКУМАРИН СО НЕКОИ АЛДЕХИДИ ВО
ВОДНА СРЕДИНА
SOSC–09-E Ahmed Jashari, Agim Shabani, Murtezan Ismaili, Kristina Mladenovska,
Luminita Silaghi-Dumitrescu, Bozhana Mikhova, Emil Popovski
REACTIONS OF 4-HYDROXYCOUMARIN WITH SOME ALDEHYDES IN
AQUEOUS MEDIA
SOSC–10-E Olivera Magdenoska, Verče Manevska, Biljana Minčeva-Šukarova
MICRO-RAMAN SPECTROSCOPIC STUDIES OF SOME FIBRES FROM
HUMAN AND ANIMAL ORIGIN
SOSC–11-E Karolina Pendovska, Zoran Zdravkovski
DEVELOPMENT OF A METHOD FOR ASSESMENT OF OCCUPATIONAL
PESTICIDE EXPOSURE IN HUMAN HAIR
SOSC–12-Е Viktor Stefov, Adnan Cahil, Bojan Šoptrajanov, Metodija Najdoski, Filip
Spirovski, Bernward Engelen, Heinz Dietrich Lutz, Violeta Koleva
FOURIER TRANSFORM INFRARED AND RAMAN SPECTRA OF
MgRbPO4·6H2O
SOSC–13-E Olgica Trenčevska, Kiro Stojanoski, Bohuslav Gaš, Vasko Aleksovski,
Angel Mitrevski
THE STUDY OF PROTEINS IN SERUM SAMPLES USING AN
OPTIMIZED LAB-ON-A-CHIP PROTEIN ELECTROPHORESIS METHOD
SOSC–14-E Rachid Benslimane
CHARACTERIZATION OF FIBROUS MATERIALS BY USING IMAGE
PROCESSING AND ANALYSIS
SOSC–15-E Majlinda Daci-Ajvazi, Nexhat Daci, Sevdije Govori, Osman Leci,
Vuksan Kalaj, Teuta Selimi, Bashkim Thaqi, Dafina Hoxha
MICROBIOLOGICAL ACTIVITY OF SOME NEWLY SYNTHESIZED
ASPIRIN HETEROARYL DERIVATIVES
SOSC–16-E Yordanka Ganeva, Miglena Valyova, Stanimir Stoyanov, Ivan Petkov,
Daniela Antonova
GAS-CHROMATOGRAPHIC-MASS SPECTRAL STUDY
OF TRITERPENOIDS AND STEROLS FROM HIERACIUM HOPPEANUM
SOSC–17-E Jože Grdadolnik
INTRINSIC BACKBONE PREFERENCES ARE FULLY PRESENT IN
BLOCKED AMINO ACIDS
SOSC–18-E Pavle A. Hadzic, Mirjana M. Popsavin, Vojkan M. Zoric
OXETANE RING IN CARBOHYDRATES NUCLEOPHILIC RING OPENING
WITH GRIGNARD REAGENTS
SOSC–19-E Hamide Ibrahimi, Sevdije Govori, Violetë Vrajolli, Osman Leci, Arleta Rifati
SYNTHESIS OF SOME DIAZEPINES AND OXAZEPINES FROM THEIR
CORRESPONDING PYRIMIDINES
SOSC–20-E Sandra S. Konstantinović, Blaga C. Radovanović, Slavica B. Ilić,
Budimir V. Konstantinović
IDENTIFICATION OF SOME ISATIN SCHIFF BASES
SOSC–21-E Thomas G. Mayerhöfer, Jürgen Popp,
PSEUDOOPTICAL CONSTANTS OF POLYCRYSTALLINE MATERIALS
WITH OPTICALLY LARGE CRYSTALLITES
SOSC–22-E Gabriel Munteanu, Cornel Miclea
PROPERTIES OF SOME CYCLODEXTRINES EVALUATED BY
QUANTUM CHEMICAL CALCULATIONS
SOSC–23-E Zorica D. Petrović, Dusica M. Simijonović, Vladimir P. Petrović
DIETHANOLAMINE: AN USEFUL LIGAND, BASE AND REACTION
MEDIUM FOR PHOSPHINE-FREE Pd-CATALYZED HECK REACTIONS
SOSC–24-E A. D. Popova, Y. I. Binev, P. J. Vassileva-Boyadjieva, I. G. Binev
EXPERIMENTAL IR, AND COMPUTATIONAL AB INITIO AND DFT B3LYP
STUDIES ON SPECTRAL AND STRUCTURAL CHANGES, CAUSED BY
THE CONVERSION OF METHYL CYANOACETATE INTO CARBANION
SOSC–25-E Arleta Rifati, Sevdije Govori, Osman Leci,Arlinda Bytyçi, Hamide Ibrahimi
NEW[1,2,4]-TRIAZOLE-3-THIONES FROM CORRESPONDING
HYDRAZINES
SOSC–26-E Simeon Stoyanov, Bistra Stamboliyska, Angelina Popova
IR SPECTRA AND STRUCTURE OF 2-[5,5-DIMETYLL-3-(2-PHENYL-
VINYL)CYCLOHEX-2-ENYLIDENE]-MALONONITRILE AND ITS
POTASSIUM CYANIDE AND SODIUM METHOXIDE CARBANIONIC
ADDUCTS: EXPERIMENTAL AND B3LYP STUDIES
SOSC–27-E Evelina Velcheva, Bistra Stamboliyska, Pavlina Boyadjieva
DFT AND EXPERIMENTAL STUDIES ON THE IR SPECTRA AND
STRUCTURE OF O-VANILLIN AND ISO-VANILLIN AND THEIR
OXYANIONS
ТЕКСТИЛНО ИНЖЕНЕРСТВО – TEXTILE ENGINEERING
TXE–01-E Elena Tomovska
COMPONENTS OF APPAREL E-RETAILERS WEBSITES
AND THEIR RELATIONSHIP TO ONLINE PURCHASE
TXE–02-M Sonja Cortosheva, Maja Nofitoska
ANALYSES OF THE STRUCTURE OF THE WORKING TIME
IN THE PROCESS OF IRONING
TXE–03-E Milena Miljković, Milovan Purenović, Sonja Randjelović
THE DIFFERENCES IN THE WHITENESS LEVELS OF THE HYDROGEN-
PEROXIDE AND TECOWHITE AC BLEACHED COTTON
TXE–04-E Mirjana Mizdrakovic, Dragan Djordjevic, Miodrag Smelcerovic
BEECH ASH – A NATURAL ADSORBENT FOR DECOLOURIZATION OF
WASTE WATERS AFTER TEXTILE DYEING
TXE–05-E Tanja J. Nikolić, Vlada B. Veljković, Petar D. Škundrić
ANTIMICROBIAL COTTON FIBERS FOR MEDICAL APPLICATIONS
TXE–06-E Christo Petrov
STRUCTURAL PECULIARITIES IN LADY’S SHOULDER ARTICLES FOR
DISPROPORTIONATE FIGURES
TXE–07-E Christo Petrov, Radka Atanasova
COMPUTER AIDED PATTERN DESIGN OF THE LADIES’ COAT HOODS
TXE–08-E Dragan Radivojevic, Jovan Stepanovic, Vasilije Petrovic
ANALYSIS OF BREAKING CHARACTERISTICS OF THREAD YARNS
TXE–09-E Nebojša Ristić, Ljubiša Milenković, Ivanka Ristić
THE USE OF CHROME DYES ON WOOL: ENVIRONMENTAL AND
QUALITY APPROACH
TXE–10-E Miodrag Smelcerovic, Dragan Djordjevic, Mirjana Mizdrakovic,
ECOLOGICAL FINISHING OF WOOLEN FABRICS WITH WATER
EXTRACTS OF SOME PLANTS
TXE–11-E Rossitza Krüger, Margarita Neznakomova, Christo Petrov
ORGANIC COTTON AND PRINCIPLES OF ORGANIC PRODUCTION
TROUGH ON THE TEXTILE SUPPLY CHAIN
TXE–12-E Zoran Angjelkoski
PRODUCTION OF CEMBED KNITTING YARN WITH ELASTINE
ON EFFECTIVE TWISTING MACHINES
TXE–13-E Gordana Blaževska
METHODS OF PROCESSING OVER THE KNITTING GARMENTS OF
100% WOOL AND MIXTURES RICH IN WOOL
TXE–14-E Borko Blažeski
ENZYME WASHING OF READY MADE GARMENT
TXE–15-E Ljubiša Gjorgjeski
ANTI-MICROBE PROTECTION OF THE KNITWEAR SOCK YARN
TXE–16-E Marica Hristova
PRESSING AND FINAL FINISHING OF A READY-MADE GARMENT
OPCW CONVENTION ON THE PROHIBITION OF THE DEVELOPMENT,
PRODUCTION, STOCKPILING AND USE OF CHEMICAL WEAPONS AND
ON THEIR DESTRUCTION
LECO Instruments

CV CV’s OF PLENARY, INVITED AND KEY NOTE LECTURES

th
SPONSORS OF THE 20 CONGRESS OF CHEMISTS AND
TECHNOLOGISTS OF MACEDONIA

INDEX
 ХХ конгрес на хемичарите и технолозите на Македонија
20th Congress of Chemists and Technologysts of Macedonia

PPM–11-E

NEW ATTEMPT AT PLASMA AIDED FLAME RETARDATION IN

WOOD AND CELLULOSIC FIBROUS MATERIALS

Peter Dineff*, Dilyana Gospodinova*, Lydia Kostova**, Todorka Vladkova***, and Chen Erfan****
e-mail: dilianang@abv.bg
* Technical University of Sofia, Department of Electrical Engineering, Bulgaria
** Interiorprotect, Ltd., Sofia, Bulgaria
*** University of Chemical Technology and Metallurgy, Sofia, Bulgaria
**** Sheniang Institute of Chemical Technology, Sheniang, Liaoning, China

Introduction

The plasma aided flame retardation has been conceived and developed as a result of a new plasma aided process: the
plasma aided capillary impregnation of water solution, which evolved as a fire protection process for wood, wooden
products and cellulosic fibrous materials using original phosphorous and nitrogen flame retardants (PhNFR),
manufactured by Interiorprotect, Ltd. (Sofia, Bulgaria) under the trade name of CSE-96. The plasma-chemical surface
pre-treatment of wood modifies the chemical activity of its surface as well as the capillary activity of wood and
improves such technological characteristics of the capillary impregnation process as the penetration depth, speed of
solution spreading and adsorption, and specific quantity of adsorbed solution per unit of area. This allows using the
plasma aided retardation as a finishing process and applying it in situ, [1, and 2].
This study was developed as part of an investigation of the thermal degradation analysis of flame retarded wood (FR
wood), wooden products, and cellulosic fibrous materials. The study was focused on well-known thermal methods of
analysis of degradation of wood, cellulose, hemicellulose, and lignin.
The methods included thermogravimetric analysis (TGA), differential thermal analysis (DTA), and differential scanning
calorimetry (DSC). These thermal methods were used for evaluation of the influence of FR and plasma FR wood
treatment on pyrolysis. Thermal analyses gave basic information on the mechanism of pyrolysis and combustion as well
as data on the effect of FR wood treatment and modification. However, the correlation between results of thermal
analyses and real fires has not been established yet, [2].
Wood cell wall is thought to be a composite material made of cellulose microfibrils embedded in a water-reactive
matrix of hemicellulose and lignin. The ability of the matrix to adsorb water is thus of critical importance in the water
solution capillary impregnation of wood (N. Barber 1968; I. Cave 1972). It is known that machining and heat treatments
reduce wood hygroscopicity and chemical activity by modifying this water-reactive matrix (E. Obataya et al. 2000; E.
Obataya and B. Tomita 2002) in different ways. Cold plasma pre-treatment redresses the wood surface balance,
chemical and capillary activities, and as result of all changes increases the impregnation ability of wood and wooden
materials (P. Dineff and D. Gospodinova 2005), [1, 2].
A discussion of the general thermal degradation process for natural wood and FR wood is followed by use of this
method to analyze the thermal degradation of various kinds of FR woods including plasma aided flame retarded wood.

Experimental

The plasma aided flame retardation process involves three tools which are used for exerting direct impact on the
thermal degradation of flame retarded wood: the first one consists in impregnating natural pine wood (Pinus sylvestis)
with a 30-percent water solution of PhNFR (CSE-96) – sample CSE; the second one consists in adding 5 vol. % of
anionic surfactant (AS5) to the impregnating solution CSE-96 – sample AS5; the third one consists in performing cold
plasma surface pre-treatment for 60 s in the plasma of dielectric barrier discharge (10 kHz) burning in air at atmospheric
pressure and room temperature – sample HF. The thermal degradation of all RF wood samples is compared with the

Ohrid 2008
 ХХ конгрес на хемичарите и технолозите на Македонија
20th Congress of Chemists and Technologysts of Macedonia

basic sample made of natural pine wood (Pinus sylvestris). The thermal destruction of the PhNFR used, which contains
about 13.5 mass % (as P2O5) is investigated separately.
Experimental conditions for all runs were as follows: thermogravimetric (TG), derivative thermogravimetric (DTG), and
differential calorimetric (DSC) analyses were completed by Perkin-Elmer’s equipment in air; the heating rate was
10 0C/min and a heating range from 26 ÷36 0C to 600 0C was used; sample size usually was about 3.0 mg. All runs were
done at least twice.

Results and Discussion

The thermal destruction of PhNFR starts intensively with a mass loss at about 143 0C (2 mass %) and rapidly attains its
maximum at 190 0C (DTG), whereas in the range 26÷ 232 0C, i. e. before the flash point of 268.6 0C, its mass decreases
with 30 mass %. This process is conducted with active heat absorption up to 356.5 0C, the general endothermic effect
being 1236.8 J/g J/g. The exothermic effect from the destruction of FR after this temperature remains about two times
lower, namely 528.0J/g, Fig. 1.

Temperature T, 0C
Loss of Mass (derived) ∆M, %

Temperature T, 0C
Rate of Loss of Mass ∆M/∆T, %/0C

10

Heat Flow q, mJ/min

100 200 300 400 500 600 400 500
0 0 100 200 300 Exo
0

-10 356.5
-0.2 -20
264.6
-20 116.7 226.5
TG
-0.4 -40 -30
DTG Enthalpy
DSC 187.6 Endothermic:
-40
- 439.623 J/g;
-0.6 -60
Exothermic:
Flame RetardantCSE-96 -50
+ 81.334 J/g
190 172.6
-0.8 -80 -60
Fig. 1. TG/DTG and DSC - thermograms of phosphor and nitrogen containing flame retardant (PhNFR).

The thermograms from the thermogravimetric (TGA) and differential thermal analysis (DTA) (a), and differential
scanning calorimetry (DSC) of all FR-wood materials investigated and those of a natural wood sample are represented
in a common coordinate system, Fig. 2, the characteristic peaks and enthalpy for the characteristic areas of thermal
degradation – the endothermic area of dehydratation, desorbtion of gases, and thermal destruction of PhNFR; and the
exothermic areas corresponding to flaming and glowing with char formation - being given systematically in Table 1 and
Table 2. A comparison between the two basic cases – plasma aided flame retarded wood (HF) и natural wood (K) – is
represented separately, the characteristic points – ignition, burning, and flash points, the characteristic peaks of flaming
L and glowing N – being shown on the curve of the basic relationship (K), Fig. 3. Combining the anionic active
phosphor and nitrogen FR-water solution with cold plasma aided capillary impregnation creates new FR-wood products

Table 1
Peak Pine sample (K) CSE impregnation (CSE) Surfactant aided Plasma aided impregnation
impregnation (AS5) (HF)
Temperature Heat flow Temperature Heat flow Temperature Heat flow Temperature Heat flow
0 0 0 0
C mJ/min C mJ/min C mJ/min C mJ/min
A 76.7 - 6.710 74.7 - 7.026 70.1 - 5.638 68.2 - 4.788
B 132.2 -14.886 130.4 - 12.672 129.0 - 10.486
C 197.3 - 22.342 191.9 - 19.850 195.0 - 15.073
IP 132.5 227.38 227.0 221.9
L 261.8 28.743 262.4 23.918 258.1 24.202
M 331.8 106.502 344.1 40.5010 369.2 39.500 349.0 30.2539
N 468,8 91.623 489.6 78.290 500.6 69.124 497.4 62.736

Ohrid 2008
 ХХ конгрес на хемичарите и технолозите на Македонија
20th Congress of Chemists and Technologysts of Macedonia

Temperature T, 0C
0 100 200 300 400 500 600
Loss of Mass (derived) ∆M, %
0
K
-10
CSE
HFAS5
-20
AS5
-30
-40
HFAS5
-50
-60
CSE
-70
AS5
-80
-90 Zone A Zone B
-100 K

a)

120
Heat Flow q, mJ/min

100
K

80 dT/dt = 10 K/min

CSE
60
K
CSE AS5
40
AS5 HFAS5
HFAS5
20
Exothermic effects K
0 100 K 200
0
300 400 500 600
HFAS5 Temperature T, 0C
-20
Endothermic effects
b)
Fig. 2. TG/DTG and DSC thermograms of natural basic pine (K) wood (Pinus sylvestris) and different kind of FR
wood: CSE – capillary impregnation with CSE-96 FR-solution; AS5 - capillary impregnation with CSE-96 FR-solution
improved by 5 vol. % of anionic surfactant “Antikristalin” (Interiorportect, Ltd., Bulgaria); HF – cold plasma aided
capillary impregnation with anionic surfactant corrected FR water solution CSE-96.

with increased thermal degradation stability and reduced enthalpy of burning – 8.122 kJ/g versus 19.526 kJ/g (a
reduction of 42 %), Table 2. In addition, the endothermic effect of PhNFR (peaks B and C) displaces substantially the
ignition point from 132.5 0C to 221.9 0С, Fig. 3. The heat flow of peak L (flaming) remains very low (24.202 versus
106.502 mJ/min) and almost equal to the heat flow of the flash point of natural pine wood, Table 1.
Acknowledgement
The financial support of the National Science Fund, Ministry of Education and Science of Bulgaria, for the Research
Project VU-TN-09/2005 is gratefully acknowledged.

Ohrid 2008
 ХХ конгрес на хемичарите и технолозите на Македонија
20th Congress of Chemists and Technologysts of Macedonia

Smoldering Flaming Glowing

Dehydration Non-Flammable Flammable Volatile Chars Ash
Desorbtion of Gases Volatile Maters Maters

Peak A Peak L Peak N

(endo) (exo) (exo)
468.8 Wood: White pine
76.7 331.8
120
Heat Flow q, mJ/min

100
Wood

80 Flash
Exothermic Effects point
268.6 HF_CSE_A5
60 (FR Wood)
Burning
point
40 Ignition
222.6
point
132.5
20
200
0
0 300 400 500 600
100
-20 Endothermic Effects Ignition Temperature T , 0C
221.9 point
68.2 129.0 195.0 258.1 349.0 497.4 Fire Retardant Wood
Peak A Peak B Peak C Peak L Peak M Peak N
(endo) (endo) (endo) (exo) (exo) (exo)

Fig. 3. Parallel between the DSC - thermograms of natural basic pine wood (Pinus sylvestrum) and FR pine wood
treated by plasma aided impregnation

Table 2
Thermal Pine sample (K) CSE impregnation (CSE) Surfactant aided Plasma aided
effects impregnation (AS5) impregnation (HFAS5)
Temperature Enthalpy Temperature Enthalpy Temperature Enthalpy Temperature Enthalpy
0 0 0 0
C kJ/g C kJ/g C kJ/g C kJ/g
Endo 36.2 27.4 26.0 28.8
- 5.516 - 1.020 - 1.572 - 1.427
thermal 132.5 227.4 227.0 221.9
IP 132.5 227.4 227.0 221.9
Exo 132.5 227.4 227.0 221.9
1.709 0.840 1.022 0.645
thermal 331.8 277.0 297.1 269.2
Exo 331.8 277.0 297.1 269.2
17.816 9.671 8.717 7.477
thermal 600.0 600.0 600.0 600.0
Exo 132.5 277.0 227.0 221.9
19.525 10.512 9.739 8.122
thermal 600.0 600.0 600.0 600.0

References

[1] P. D. Dineff and L. G. Kostova, Method of Plasma-Chemical Modification. Patent WO2006/133524 A3.
[2] V. Repellin and R. Guyonnet, Evaluation of Heat-Treated Wood Swelling by Differential Scanning Calorimetry in
Relation to Chemical Composition, Holzforschung, Vol. 59, pp. 28÷34, 2005.

Ohrid 2008