Document Number Revision Total Number of Sheets Author UOP Job Number Client Ref Number Number of Beds

in main mode of operation Equipment Location PSA Type Pressure Unit of Measurement Feed Temperature Unit Nominal Feed Pressure Lowest Equalization Cut-Off Pressure Adsorber Design Pressure Minimum IA Supply Pressure IA Regulator Set-Point Max. IA Pressure for Positioners / Actuators High High Feed Flow Main Mode High High Feed Flow First Switchover Mode High High Feed Flow Second Switchover Mode Minimum sub-cycle time seconds kg/cm(g) kg/cm(g) kg/cm(g) kg/cm(g) kg/cm(g) kg/cm(g)

D-H6387-011/00-DI-02-UOP 0 4 Han Yuan Lee H6387 12 12-BED POLYBED PSA UNIT NOVOKUIBYSHEVSK, RUSSIA SMR kg/cm(g) C 22.3 3.9 27.8 4 4.2 7 213 754 Nm3/hr 162 024 Nm3/hr 131 781 Nm /hr 27
3

Knockout Drum in UOP scope ? Knockout Drum Differential Pressure Unit 2oo3 Transmitter on feed / IA PT ? Number of Beds Number of switchover modes Paired Adsorbers I/O Configuration

No kg/cm No 12 2 Yes Full I/O Redundancy

Name Knockout Drum Differential Pressure Transmitter Name Feed Pressure Transmitter Name IA Pressure Transmitter Name Adsorber Pressure Transmitters Name Tail Gas Drum PT Name 2oo3 Transmitters Name Feed Flow Transmitter Name ESD Contacts Name Valves Series #1 Name Valves Series #2 Name Valves Series #3 Name Valves Series #4 Name Valves Series #5 Name Valves Series #6 Name Valves Series #7 FT-FEED XS-ESD-A/B/C PV-011 THROUGH PV-121 XV-012 THROUGH XV-122 PV-013 THROUGH PV-123 PV-014 THROUGH PV-124 XV-015 THROUGH XV-125 XV-016 THROUGH XV-126 PT-001 PT-009 PT-010 THROUGH PT-120 PT-TGD

uop
A Honeywell Company

UOP N.V., Noorderlaan 147, B-2030 Antwerp, Belgium

PROJECT SPECIFICATION
Number D-H6387-011/00-DI-02-UOP Rev. :0 Sheet : 1 of 4 By : Han Yuan Lee

CAUSE AND EFFECT DIAGRAM - UNIT ME-751

UOP JOB NO. CLIENT REF. NO. PROJECT NAME EQUIPMENT LOCATION
:

H6387

: POLYBED 2 X 12-BED SMR PSA UNIT FOR COMBINED HYDROCRACKING UNIT HYDROGEN PRODUCTION SECTION 2x12 POLYBEDTM PSA UNIT
NOVOKUIBYSHEVSK REFINERY RUSSIA

0 REV.

HYL BY

09/05/2012 First Issue DATE DESCRIPTION

For Information WE PROC. CHK'D

ISSUE

JK PROJ. APP'D

This information is proprietary and shall not be disclosed outside your organisation, nor shall it be duplicated, used, or disclosed for any purpose other than as permitted under written agreement with UOP.

uop
A Honeywell Company

UOP N.V., Noorderlaan 147, B-2030 Antwerp, Belgium

PROJECT SPECIFICATION
Number D-H6387-011/00-DI-02-UOP Rev. :0 Sheet : 2 of 4 By : Han Yuan Lee

CAUSE AND EFFECT DIAGRAM - UNIT ME-751

This sheet is a record of all revisions to this specification. For convenience, the nature of each revision is briefly noted under description, however, the description is not a part of this specification.

DOC. REV.

SHEET NO.

DESCRIPTION

1-4

First issue

This information is proprietary and shall not be disclosed outside your organisation, nor shall it be duplicated, used, or disclosed for any purpose other than as permitted under written agreement with UOP.

uop
A Honeywell Company

UOP N.V., Noorderlaan 147, B-2030 Antwerp, Belgium

PROJECT SPECIFICATION
Number D-H6387-011/00-DI-02-UOP Rev. :0 Sheet : 3 of 4 : Han Yuan Lee By
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 REPRESSURIZATION LOOP HIGH HIGH DEVIATION ALARM 21 22 23 EQUALIZATION DEVIATION ALARM (ONE FOR EACH EQ STEP) 24 25 26 27 28 29 30 31 32 33 34 SECOND SWITCHOVER MODE (8 BEDS) ACTIVE ALARM 35 36 37 38 39

CAUSE AND EFFECT DIAGRAM - UNIT ME-751

PROVIDE PURGE LOOP HIGH HIGH DEVIATION ALARM

FIRST SWITCHOVER MODE (10 BEDS) ACTIVE ALARM

PSA SHUTDOWN - ALL AUTOMATIC ADSORBER VALVES (NOTE 11) CLOSE

PSA SWITCHOVER TO REDUCED NUMBER OF BEDS AUTOMATIC VALVES OF OFF-LINE ADSORBERS CLOSE

BLOWDOWN LOOP HIGH HIGH DEVIATION ALARM

LOW INSTRUMENT AIR PRESSURE SHUTDOWN

REPRESSURIZATION LOOP DEVIATION ALARM

MINIMUM SUB-CYCLE TIME REACHED ALARM

REPRESSURIZATION NOT COMPLETE ALARM

LOW FEED PRESSURE SHUTDOWN (NOTE 2)

HIGH KNOCKOUT DRUM LEVEL SHUTDOWN

HIGH INSTRUMENT AIR PRESSURE ALARM

PROVIDE PURGE LOOP DEVIATION ALARM

PROVIDE PURGE NOT COMPLETE ALARM

LOW INSTRUMENT AIR PRESSURE ALARM

HIGH FEED TEMPERATURE SHUTDOWN

LONG LONG ADSORPTION TIME ALARM

HIGH KNOCKOUT DRUM LEVEL ALARM

LOW KNOCKOUT DRUM LEVEL ALARM

BLOWDOWN LOOP DEVIATION ALARM

BLOWDOWN NOT COMPLETE ALARM

VALVE CALIBRATION ERROR ALARM

INSTRUMENT ERROR ALARM

CAUSE

EFFECT

SETPOINT & NOTE

P&ID (Note12)

FEEDBACK MISMATCH ALARM

1 2 3 4 5 6 7 8 9

FEED TEMPERATURE HIGH FEED TEMPERATURE HIGH HIGH FEED PRESSURE LOW FEED PRESSURE LOW LOW AND BYPASS OFF FEED PRESSURE HIGH INSTR. AIR PRESSURE LOW INSTR. AIR PRESSURE LOW LOW INSTR. AIR PRESSURE HIGH FEED KNOCKOUT DRUM LEVEL LOW

(NOTE 1) (NOTE 1)

ALARM TAG NAME

55 C 60 C 18 kg/cm(g)

60 120 5 15 5 5 15 5 (NOTE 3) (NOTE 3) (NOTE 3) DYNAMIC 0 DYNAMIC 0 DYNAMIC 0 1 1 1 1 1 1 0 0 0 0 5 0 0

CUSTOMER P&ID CUSTOMER P&ID UOP P&ID UOP P&ID UOP P&ID UOP P&ID UOP P&ID UOP P&ID CUSTOMER P&ID CUSTOMER P&ID CUSTOMER P&ID X PT-001 PT-001 PT-001 PT-009 PT-009 PT-009 X X X

X X X X X X X X X X X X X X X X X X X X X X X X X X X

(NOTE 2)

16 kg/cm(g) 24 kg/cm(g) 3.9 kg/cm(g) 3.5 kg/cm(g) 5.3 kg/cm(g) (NOTE 3) (NOTE 3) (NOTE 3) (NOTE 4) (NOTE 4) (NOTE 5) (NOTE 5) (NOTE 6) (NOTE 6) (NOTE 7) (NOTE 7) (NOTE 7) (NOTE 7) (NOTE 7) (NOTE 7) (NOTE 8) ADSORPTION TIME / ADSORBER ADSORPTION TIME / ADSORBER (NOTE 9) (NOTE 10) (NOTE 12)

10 FEED KNOCKOUT DRUM LEVEL HIGH 11 FEED KNOCKOUT DRUM LEVEL HIGH HIGH 12 REPRESSURIZATION END PRESSURE NOT REACHED 13 REPRESSURIZATION NOT COMPLETE ALARM AND NO SWO BYPASS AND NOT 8-BED MODE 14 PROVIDE PURGE END PRESSURE NOT REACHED 15 PROVIDE PURGE NOT COMPLETE ALARM AND NO SWO BYPASS AND NOT 8-BED MODE 16 BLOWDOWN END PRESSURE NOT REACHED 17 BLOWDOWN NOT COMPLETE ALARM AND NO SWO BYPASS AND NOT 8-BED MODE 18 HIGH DEVIATION (PV - SP) IN REPRESSURIZATION LOOP 19 HIGH DEVIATION (PV - SP) IN PROVIDE PURGE LOOP 20 HIGH DEVIATION (PV - SP) IN BLOWDOWN LOOP 21 HIGH HIGH DEVIATION (PV - SP) IN REPRESSURIZATION LOOP 22 HIGH HIGH DEVIATION (PV - SP) IN PROVIDE PURGE LOOP 23 HIGH HIGH DEVIATION (PV - SP) IN BLOWDOWN LOOP 24 PRESSURE CHANGE OUTSIDE TOLERANCE DURING EQUALIZATION STEP 25 RUNNING ADSORPTION TIME > 1.2 * SET ADSORPTION TIME 26 RUNNING ADSORPTION TIME > 2 * SET ADSORPTION TIME 27 LONG LONG ADSORPTION TIME ALARM AND BYPASS OFF 28 VALVE FEEDBACK FAILURE 29 VALVE FAILURE 30 VALVE FAILURE ALARM AND NO SWO BYPASS AND NOT 8-BED MODE 31 TRANSMITTER SIGNAL NOT HEALTHY 32 ADSORBER PRESSURE TRANSMITTER FAILURE AND NOT FULL SWO BYPASS AND NOT 8-BED MODE 33 ADSORBER PRESSURE TRANSMITTER FAILURE AND NOT FULL SWO BYPASS AND 8-BED MODE 34 SEQUENCE SWITCHES TO FIRST SWITCHOVER MODE (10-BED) 35 SEQUENCE SWITCHES TO SECOND SWITCHOVER MODE (8-BED) 36 FEED FLOW TRANSMITTER FAILURE AND AUTO TIME MODE 37 CALCULATED SUB-CYCLE TIME <= MINIMUM SUB-CYCLE TIME 38 IVO DEVIATION 39 REMOTE SHUTDOWN 40 OPERATOR SHUTDOWN REQUEST FROM HMI 41 FULL SWITCHOVER BYPASS SELECTED 42 PARTIAL SWITCHOVER BYPASS SELECTED 43 LONG LONG ADSORPTION TIME SHUTDOWN BYPASS SELECTED 44 LOW LOW FEED PRESSURE SHUTDOWN BYPASS SELECTED 45 HIGH PSA FEED FLOW 46 HIGH HIGH PSA FEED FLOW 47 CPU FAILURE 48 I/O CARD FAILURE 49 PLC HARDWARE FAILURE

UOP P&ID UOP P&ID

(NOTE 11) (NOTE 11) X

X X

(NOTE 13)

2 0 0 0 0 0 CUSTOMER P&ID FT-FEED UOP P&ID UOP P&ID PT-010 THROUGH PT-120 PT-010 THROUGH PT-120 X X

X X X X X UOP P&ID XS-ESD-A/B/C X X X X X X CUSTOMER P&ID CUSTOMER P&ID FT-FEED FT-FEED X X X X X X X X

27 seconds (NOTE 14) (NOTE 15)

0 0 1 0

(NOTE 16) (NOTE 17) (NOTE 9) (NOTE 16) (NOTE 19) (NOTE 19) (NOTE 20) (NOTE 21) (NOTE 22)

0 0 0 0 0 DYNAMIC 0 2 2

This information is proprietary and shall not be disclosed outside your organisation, nor shall it be duplicated, used, or disclosed for any purpose other than as permitted under written agreement with UOP.

BYPASS SELECTED ALARM

TIME DELAY SECONDS

EQUIPMENT/ INSTRUMENT TAG NUMBER

HIGH PSA FEED FLOW SHUTDOWN

HIGH FEED TEMPERATURE ALARM

PLC HARDWARE FAILURE ALARM

SWITCH TO MANUAL TIME MODE

LONG ADSORPTION TIME ALARM

HIGH FEED PRESSURE ALARM

HIGH PSA FEED FLOW ALARM

LOW FEED PRESSURE ALARM

VALVE FAILURE ALARM

CPU FAILURE ALARM

I/O FAILURE ALARM

uop
A Honeywell Company

UOP N.V., Noorderlaan 147, B-2030 Antwerp, Belgium

PROJECT SPECIFICATION
Number D-H6387-011/00-DI-02-UOP Rev. :0 Sheet : 4 of 4 By : Han Yuan Lee

CAUSE AND EFFECT DIAGRAM - UNIT ME-751

NOTES: 1) ALARM AND SHUTDOWN TO BE PROGRAMMED IN CUSTOMER SYSTEM. SHUTDOWN SIGNAL IS COMMUNICATED HARD-WIRED TO THE PSA CONTROLLER. THE SIGNAL IS TYPICALLY BYPASSED UNTIL THE UNIT HAS BEEN STARTED. 2) LOW FEED PRESSURE SHUTDOWN CAN BE BYPASSED AT START-UP OF THE UNIT BY USING STARTUP MODE. 3) ALARM AND SHUTDOWN LIMIT VALUES BY CUSTOMER SHOULD ENSURE THAT NO LIQUID CARRY OVER TO PSA FEED INLET CAN OCCUR. SIGNALS TO BE PROGRAMMED IN CUSTOMER'S SCOPE. SHUTDOWN SIGNAL IS INCLUDED IN THE PSA REMOTE SHUTDOWN SIGNAL. 4) REPRESSURIZATION PRESSURE NOT REACHED: P(rep) < PT-001 - 1.115 KG/CM AT THE PRESET REPRESSURISATION TIME PLUS A DELAY THAT IS A FRACTION OF THE PRESET REPRESSURISATION TIME. 5) PROVIDE PURGE PRESSURE NOT REACHED: P(pp) > P(SET PP CUT-OFF) + 0.5 KG/CM AT THE PRESET PROVIDE PURGE TIME PLUS A DELAY THAT IS A FRACTION OF THE PRESET PROVIDE PURGE TIME. 6) BLOWDOWN END PRESSURE NOT REACHED: P(BD) > PT-TGD + 1 KG/CM AT THE PRESET BLOWDOWN TIME PLUS A DELAY THAT IS A FRACTION OF THE PRESET BLOWDOWN TIME. 7) HIGH DEVIATION IS ABSOLUTE VALUE OF PV - SP > 0.7 KG/CM. HIGH HIGH DEVIATION USES A LARGER ALARM LIMIT FOR EACH LOOP. THE HIGH HIGH LIMIT IS A FUNCTION OF THE PROCESS CONDITIONS. 8) PRESSURE CHANGE IS MONITORED DURING EACH EQUALISATION. IF THE PRESSURE CHANGE EXCEEDS THE TOLERANCE, THE ALARM IS RAISED. TOLERANCES ARE DIFFERENT FOR EACH EQUALISATION AND DIFFERENT FOR PROVIDE AND RECEIVE EQUALISATION STEPS. THERE IS ONE ALARM FOR EACH EQUALISATION. 9) LONG LONG ADSORPTION TIME BYPASS IS SET MANUALLY BY THE OPERATOR OR AUTOMATICALLY BY THE LOGIC AT EVERY START-UP. IT IS DE-ACTIVATED BY THE OPERATOR OR BY THE LOGIC - IF FEED FLOW > 35 % OF NOMINAL CAPACITY FOR 30 MINUTES. 10) VALVE FEEDBACK FAILURE ALARM IS GENERATED WHEN : - VALVES WITH DISCRETE FEEDBACK : AT LEAST ONE PROXIMITY SWITCH DEVIATES FROM VALVE COMMAND. - VALVES WITH ANALOG FEEDBACK : DEVIATION > 20% BETWEEN VALVE COMMAND AND ANALOG FEEDBACK. 11) VALVES WITH THE FOLLOWING TAG NUMBERS : PV-011 THROUGH PV-121 XV-012 THROUGH XV-122 PV-013 THROUGH PV-123 PV-014 THROUGH PV-124 XV-015 THROUGH XV-125 XV-016 THROUGH XV-126 12) VALVE FAILURE OCCURS IN ANY OF THE FOLLOWING CONDITIONS : - VALVES WITH DISCRETE FEEDBACK - BOTH PROXIMITY SWITCHES SHOW A FEEDBACK MISMATCH. - VALVE FEEDBACK ALARM OCCURRING SIMULTANEOUSLY WITH PRESSURE MONITORING ALARM WHEN VALVE IS COMMANDED TO OPEN. BOTH ALARMS MUST BE ON THE SAME VESSEL. - VALVE FEEDBACK ALARM WHEN THE VALVE IS COMMANDED TO CLOSE. 13) TRANSMITTER NOT HEALTHY SIGNAL MEANS THE TRANSMITTER IS SENDING AN ANALOG SIGNAL BELOW 3.5 mA or ABOVE 20.5 mA. 14) IVO DEVIATION OCCURS IF ANY CALCULATED IVO DEVIATE BY + 15% FROM THE AVERAGE IVO FOR THE VALVE SERIES. 15) REMOTE SHUTDOWN SHOULD INCLUDE TRIP OF UPSTREAM UNIT, GENERAL PLANT EMERGENCY TRIP, HIGH HIGH LIQUID ' LEVEL IN FEED KO DRUM. HIGH HIGH FEED TEMPERATURE IS HANDLED AS A SEPARATE SIGNAL BY THE PSA SHUTDOWN LOGIC. 16) BYPASS CAN ONLY BE (DE)ACTIVATED BY OPERATOR. 17) PARTIAL SWITCHOVER BYPASS IS SET MANUALLY BY THE OPERATOR OR AUTOMATICALLY BY THE LOGIC AT EVERY START-UP, SWITCHOVER OR SWITCHBACK BUT CAN ONLY BE DE-ACTIVATED BY THE OPERATOR. 18) ALARM LIMIT IS DYNAMICALLY CALCULATED AS FUNCTION OF THE CAPACITY FACTOR AND THE NUMBER OF ADSORBERS IN SERVICE; IT IS USED AS MAXIMUM FLOW LIMIT AND COMMUNICATED AS A REMOTE FLOW SET-POINT TO THE PSA VENT VALVE CONTROLLER. 19) ALARM LIMIT VALUES : 213 754 Nm3/hr IN MAIN MODE 162 024 Nm3/hr IN FIRST SWITCHOVER MODE 131 781 Nm3/hr IN SECOND SWITCHOVER MODE 20) PSA SHUTDOWN OCCURS WHEN THERE IS NO STANDBY PLC CPU ON-LINE. 21) FULL I/O REDUNDANCY : I/O FAILURE WILL RESULT IN A SHUTDOWN ONLY IF BOTH CARDS FAIL SIMULTANEOUSLY. 22) PLC HARDWARE FAILURE ALARM IS A COMMON ALARM GROUPING ALL PLC FAILURES : PLC SWITCHOVER, CPU NON-STANDBY STATUS, CARD FAILURES, POWER SUPPLY FAILURE, COMMUNICATION FAILURE, I/O COMMUNICATION FAILURE, OTHER POWER SUPPLIES, RELAY FAILURES. SHUTDOWN LIMIT VALUES: N/A N/A 138 717 Nm3/hr

THE SHUTDOWN WILL OCCUR IF THE FEED FLOW CANNOT BE REDUCED WITHIN A COMPLETE SUB-CYCLE.

This information is proprietary and shall not be disclosed outside your organisation, nor shall it be duplicated, used, or disclosed for any purpose other than as permitted under written agreement with UOP.